ACS Applied Materials & Interfaces,
Journal Year:
2023,
Volume and Issue:
15(3), P. 3713 - 3730
Published: Jan. 12, 2023
Ultrathin
MoS2-MoO3-x
heterojunction
nanosheets
with
unique
features
were
introduced
as
biocompatible,
non-cytotoxic,
and
visible
light-sensitive
stimulator
layers
for
the
controlled
differentiation
of
human
neural
progenitor
cells
(hNPCs)
into
nervous
lineages.
hNPC
was
also
investigated
on
reduced
graphene
oxide
(rGO)-containing
scaffolds,
that
is,
rGO
rGO/MoS2-MoO3-x
nanosheets.
In
darkness,
neurons
increased
by
a
factor
2.7
due
to
excellent
biophysical
cues
further
4.4
synergistic
effect
induced
rGO.
The
MoO3-x
domains
antioxidant
activity
LSPR
absorption
p-type
doping
in
MoS2-MoO3-x.
Under
photostimulation,
hNPCs
exhibited
higher
glial
1.4,
decrease
photo-electron
current
induction
more
While
increase
neuronal
1.8
ascribed
presence
an
ultrafast
electron
transferor
which
quickly
transferred
photogenerated
electrons
before
their
transfer
free
radicals,
these
results
demonstrated
promising
potential
MoS2-based
scaffolds
applying
controllable
repair
and/or
regeneration
diseases/disorders
related
system.
Molecular Physics,
Journal Year:
2023,
Volume and Issue:
121(3)
Published: Jan. 12, 2023
This
study
using
the
first-principles
theory
investigates
geometric
and
electronic
properties
of
Cu-decorated
NiS2
(Cu–NiS2)
monolayer,
adsorption
sensing
performance
Cu–NiS2
monolayer
upon
five
C5F10O
decomposed
species,
in
order
to
explore
its
potential
evaluate
operation
status
C5F10O-based
insulation
devices.
It
is
found
that
Cu
atom
prefers
be
trapped
on
H1
site
with
formation
energy
−3.09
eV
without
cluster
issue.
The
chemisorption
determined
Cu–NiS2/C2F6O3
an
−1.05
eV,
while
physisorption
identified
C3F6,
CF2O,
C2F6
CF4
systems.
analyses
property
recovery
reveal
strong
a
reusable
C3F6
or
CF2O
sensor
at
room
temperature,
high-sensitive
one-shot
C2F6O3
instead
not
suitable
for
due
low
sensitivity.
work
meaningful
terms
proposing
novel
material
application
power
system
ensure
good
devices.Research
Highlights
Cu-decorating
behaviours
pristine
are
studied.The
mechanisms
species
expounded.The
as
resistance-type
gas
explored.
ACS Sensors,
Journal Year:
2022,
Volume and Issue:
7(11), P. 3450 - 3460
Published: Nov. 7, 2022
Two-dimensional
(2D)
magnetic
materials
are
the
key
to
development
of
new
generation
in
spintronics
technology
and
engineering
multifunctional
devices.
Herein,
electronic,
spin-resolved
transmission,
gas
sensing
properties
2D
g-C4N3/MoS2
van
der
Waals
(vdW)
heterostructure
have
been
investigated
by
using
density
functional
theory
with
non-equilibrium
Green's
function
method.
First,
vdW
demonstrates
ferromagnetic
half-metallicity
superior
adsorption
capacity
for
molecules.
The
spin-dependent
electronic
transport
g-C4N3/MoS2-based
nanodevice
is
obviously
regulated
parallel
or
anti-parallel
spin
configuration
electrodes,
leading
perfect
single-spin
conduction
behavior
a
nearly
100%
filtering
efficiency,
negative
differential
resistance
effect,
other
interesting
electrical
phenomena.
Moreover,
exhibits
directional
dependency
strong
anisotropic
under
bias
windows,
indicating
that
electric
current
propagates
more
easily
through
vertical
direction
than
horizontal
direction.
physical
mechanisms
revealed
analyzed
presenting
bias-dependent
transmission
spectra
combination
projected
local
device
states.
Finally,
sensor
sensitive
CO,
NO,
NO2,
NH3
molecules
chemisorption
type.
chemical
leads
formation
electrons
on
scattering
center
ultimately
affects
properties,
resulting
maximum
sensitivity
reaching
6.45
NO
at
0.8
V.
This
work
not
only
reveals
high
anisotropy,
filtering,
outstanding
promising
material
but
also
provides
an
insight
into
further
application
futuristic
nanodevices.
ACS Applied Nano Materials,
Journal Year:
2023,
Volume and Issue:
6(7), P. 5517 - 5526
Published: March 23, 2023
Dissolved
gas
detection
is
very
important
for
an
oil-immersed
transformer
fault.
We
examined
the
adsorption
characteristics
and
sensitivity
processes
of
monolayer
NbSe2
doped
with
Ag,
Pd,
Pt
on
five
typical
gases
(H2,
CO,
CO2,
CH4,
C2H2)
in
using
first-principles
calculations.
While
Pd–NbSe2
system
only
has
great
desorption
properties
H2
at
high
temperature,
Ag/Pt–NbSe2
outstanding
possessions
ambient
temperature.
Therefore,
micro-nanomaterials
prepared
by
Ag/Pd/Pt–NbSe2
are
expected
to
be
used
as
sensors
detecting
H2.
The
systems
can
C2H2
temperature
temperatures,
but
effect
not
excellent.
Micro-nanomaterials
Pd/Pt–NbSe2
have
excellent
performance
CH4
CO2
candidates
sensors.
This
paper
systematically
studies
potential
application
a
metal-doped
oil
dissolution
provides
theoretical
guidance
detection.
It
theoretically
proven
that
scheme
dissolved
oil.
ACS Applied Nano Materials,
Journal Year:
2023,
Volume and Issue:
6(4), P. 2527 - 2537
Published: Feb. 8, 2023
The
increasing
demand
of
hydrogen
(H2)
as
an
alternative
clean
fuel
emboldened
the
parallel
development
extremely
sensitive
room-temperature
H2
sensors
for
safety
purposes.
Molybdenum
disulfide
(MoS2)
is
intriguing
material,
exhibiting
a
high
chemical
sensing
ability.
However,
usage
MoS2
in
has
been
limited
and
usually
suffers
from
low
sensitivity
selectivity,
especially
at
room
temperature.
In
this
work,
we
report
highly
selective
sensor
based
on
Pt
nanoparticle-functionalized
vertically
aligned
large-area
flakes.
fabricated
Pt@MoS2
exhibits
value
23%,
excellent
reproducibility,
fast
response,
complete
recovery
superior
response
attributed
to
spillover
effect
adsorption
sites
distributed
surface
MoS2–Pt
interface.
influence
operating
temperature
performance
also
investigated.
Density
functional
theory
calculations
validate
our
experimental
results
demonstrate
higher
leading
improved
response.
This
study
offers
nanoparticle-sensitized
potential
candidate
low-power
near
future
vehicles
related
technologies.