Chemical Physics Letters, Journal Year: 2023, Volume and Issue: 832, P. 140862 - 140862
Published: Oct. 12, 2023
Language: Английский
Chemical Physics Letters, Journal Year: 2023, Volume and Issue: 832, P. 140862 - 140862
Published: Oct. 12, 2023
Language: Английский
Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 313, P. 123447 - 123447
Published: Feb. 22, 2023
Language: Английский
Citations
59Vacuum, Journal Year: 2024, Volume and Issue: 228, P. 113528 - 113528
Published: Aug. 3, 2024
Language: Английский
Citations
9Optical Materials, Journal Year: 2024, Volume and Issue: 150, P. 115158 - 115158
Published: March 5, 2024
Language: Английский
Citations
6Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 492, P. 152306 - 152306
Published: May 16, 2024
Language: Английский
Citations
6Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 644, P. 285 - 294
Published: April 25, 2023
Language: Английский
Citations
15Chemosphere, Journal Year: 2023, Volume and Issue: 343, P. 140285 - 140285
Published: Sept. 25, 2023
Language: Английский
Citations
14Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(26), P. 15893 - 15901
Published: Jan. 1, 2024
The scheme of M (M = Fe, Co, Ni, Cu, and Zn) doped-La 2 (MoO 4 ) 3 are performed NRR.
Language: Английский
Citations
5Journal of Physics and Chemistry of Solids, Journal Year: 2023, Volume and Issue: 185, P. 111781 - 111781
Published: Nov. 17, 2023
Language: Английский
Citations
11Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)
Published: March 26, 2025
Reductive-coupling of nitro compounds and alcohols is a sustainable route for constructing C = N bonds in organonitrogen chemicals, yet challenging due to the inertness α-Csp3-H bond vulnerability towards hydrogenation. Here, we report surprising catalytic activity ultrafine alkaline-earth metal oxide MgO nanoclusters (0.9 ± 0.3 nm) that efficiently activate bonds, facilitating transfer hydrogenation synthesis value-added chemicals bearing with high excellent yields (86–99%). Controlled experiments characterizations showed crucial role oxygen vacancies (Ov) local Mg environment (Mg-O bond) substrate adsorption activation via electronic interactions between substrate's negatively charged atoms Ov sites nanoclusters. Theoretical calculation further confirmed significantly lowered energy barrier hydrogen atom from ethanol group nitrobenzene (29.3 vs. 52.9 kcal/mol), which rate-determining step highest reductive-coupling reactions. Our method not only provides an efficient pathway synthesizing but also inspires exploration main element catalysts as alternatives transition noble organic transformations. The reductive coupling typically amine products. Here authors show catalyse this reaction, giving unsaturated containing
Language: Английский
Citations
0Nanomaterials, Journal Year: 2024, Volume and Issue: 14(13), P. 1071 - 1071
Published: June 22, 2024
The efficient separation of photogenerated charge carriers and strong oxidizing properties can improve photocatalytic performance. Here, we combine the construction a tightly connected S-scheme heterojunction with exposure an active crystal plane to prepare
Language: Английский
Citations
2