Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1006, P. 176342 - 176342
Published: Sept. 4, 2024
Language: Английский
Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1006, P. 176342 - 176342
Published: Sept. 4, 2024
Language: Английский
International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 64, P. 1030 - 1039
Published: April 1, 2024
Language: Английский
Citations
3ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(12), P. 14609 - 14620
Published: June 7, 2024
Language: Английский
Citations
3ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(28), P. 10466 - 10474
Published: July 1, 2024
α-Ni(OH)2 is an efficient candidate for urea oxidation reaction (UOR) but its instability and high energy barriers restrict application. The introduction of transition metals a strategy to solve these problems, systematic investigations mechanisms are limited. Herein, range isoelectronic (ITMs) (M = Co, Fe, Cu) doped Ni(OH)2 catalysts on UOR studied simultaneously in theory experiment. By introducing Co Fe into the lattice Ni(OH)2, electronic structure transfer facilitated, resulting effective promotion absorption CO2 desorption, intrinsic activity can be increased. Among catalysts, Co–Ni(OH)2 with lowest barrier (1.76 eV) rate-determining steps might exhibit excellent activity. To verify theoretical prediction, samples synthesized via one-step hydrothermal method. ITMs incorporation stabilize α phase confirmed by chronopotentiometry X-ray diffraction results. Agreeing calculation, manifests superior properties than other providing smallest onset potential (1.304 V vs RHE) Tafel slope (24 mV dec–1). This study provide comprehensive understanding ITMs-Ni(OH)2 catalytic mechanism, which could instructive designing higher
Language: Английский
Citations
3Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 674, P. 39 - 48
Published: June 20, 2024
Language: Английский
Citations
2Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1006, P. 176342 - 176342
Published: Sept. 4, 2024
Language: Английский
Citations
2