Robust Covalent Organic Frameworks for Photosynthesis of H2O2: Advancements, Challenges and Strategies
Jiehui Hao,
No information about this author
Yanqi Tang,
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Jiafu Qu
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et al.
Small,
Journal Year:
2024,
Volume and Issue:
20(44)
Published: July 6, 2024
Abstract
Since
2020,
covalent
organic
frameworks
(COFs)
are
emerging
as
robust
catalysts
for
the
photosynthesis
of
hydrogen
peroxide
(H
2
O
),
benefiting
from
their
distinct
advantages.
However,
current
efficiency
H
production
and
solar‐to‐chemical
energy
conversion
(SCC)
remain
suboptimal
due
to
various
constraints
in
reaction
mechanism.
Therefore,
there
is
an
imperative
propose
improvement
strategies
accelerate
development
this
system.
This
comprehensive
review
delineates
recent
advances,
challenges,
utilizing
COFs
photocatalytic
production.
It
explores
fundamentals
challenges
(e.g.,
oxygen
(O
)
mass
transfer
rate,
adsorption
capacity,
response
sunlight,
electron‐hole
separation
efficiency,
charge
selectivity,
desorption)
associated
with
process,
well
advantages,
applications,
classification,
preparation
purpose.
Various
enhance
performance
highlighted.
The
aims
stimulate
further
advancements
discusses
potential
prospects,
application
areas
field.
Language: Английский
Development of a g-C3N4-based photocatalysis-self-Fenton system for efficient degradation and mineralization of organic pollutants
Minghui He,
No information about this author
Meichen Sun,
No information about this author
Handong Yu
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et al.
Separation and Purification Technology,
Journal Year:
2025,
Volume and Issue:
unknown, P. 132833 - 132833
Published: April 1, 2025
Language: Английский
Synergistic Effect of AuPd and NiOOH Cocatalysts Promoting Photoctalytic H2O2 Production of BiVO4 Photocatalyst
Wenjing Qi,
No information about this author
Haiyang Shi,
No information about this author
Ping Wang
No information about this author
et al.
Journal of Wuhan University of Technology-Mater Sci Ed,
Journal Year:
2025,
Volume and Issue:
40(2), P. 344 - 352
Published: April 1, 2025
Language: Английский
Strategic facet engineering of bismuth‐based photocatalysts for the applications in solar‐to‐chemical conversion
Joel Jie Foo,
No information about this author
Zi‐Jing Chiah,
No information about this author
Sue‐Faye Ng
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et al.
InfoScience.,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 5, 2024
Abstract
Semiconductor
photocatalysis
is
a
promising
tactic
to
simultaneously
overcome
global
warming
and
the
energy
crisis
as
it
can
directly
convert
inexhaustible
solar
into
clean
fuels
valuable
chemicals,
hence
being
employed
in
various
applications.
However,
current
performance
of
largely
impeded
by
fast
recombination
photogenerated
charge
carriers
insufficient
light
absorption.
Among
materials,
bismuth‐based
photocatalysts
have
stood
out
excellent
candidates
for
efficient
due
their
unique
controllable
crystal
structures
relatively
narrow
band
gap.
These
features
endow
selective
exposure
active
facets
(facet
engineering)
wide
absorption
range,
resulting
tunable
photocatalytic
activity,
selectivity,
stability.
Therefore,
great
potential
use
facet‐engineered
applications
(e.g.,
water
splitting,
CO
2
reduction,
N
fixation,
H
O
production)
achieve
sustainable
development.
Herein,
introduction
provides
overview
this
research,
while
synthesis,
modification
strategy,
latest
progress
application
were
summarized
highlighted
review
paper.
Lastly,
conclusion
outlooks
topic
concluded
give
some
insights
direction
focus
future
research.
Language: Английский
Hydroxyl-enriched hydrous tin dioxide-coated BiVO4 with boosted photocatalytic H2O2 production
Chinese Journal of Structural Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown, P. 100457 - 100457
Published: Oct. 1, 2024
Language: Английский
Recent Progress in Situ Application of H2O2 Produced via Catalytic Synthesis
Chemistry - A European Journal,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 5, 2024
Abstract
Industrial
production
of
H
2
O
requires
lots
energy
and
causes
environmental
pollution.
Moreover,
in
subsequent
applications,
much
economic
loss
could
be
produced
during
the
transportation
process
its
dilution
process.
Therefore,
it
is
highly
desirable
for
situ
application
.
In
recent
years,
catalytic
synthesis
,
e.
g.,
direct
synthesis,
electrocatalytic
photocatalytic
has
attracted
more
attention
because
continuous
low‐concentration
by
can
directly
used
oxidation
organic
compounds,
effectively
avoiding
shortcomings
current
industrial
route.
Here,
we
briefly
reviewed
latest
processes
via
various
routes.
On
this
basis,
summarized
discussed
typical
conversion
reactions,
including
ammoximation
ketones,
alcohols,
C−H
bonds,
olefins.
Some
coupling
reactions
have
shown
excellent
performance
with
high
selectivity,
cost
been
significantly
reduced.
Finally,
utilization
were
analyzed,
some
strategies
promoting
efficiency
proposed.
Language: Английский
Solar‐Driven Hydrogen Peroxide Production via BiVO4‐Based Photocatalysts
Advanced Science,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 8, 2024
Abstract
Solar
hydrogen
peroxide
(H
2
O
)
production
has
garnered
increased
research
interest
owing
to
its
safety,
cost‐effectiveness,
environmental
friendliness,
and
sustainability.
The
synthesis
of
H
relies
mainly
on
renewable
resources
such
as
water,
oxygen,
solar
energy,
resulting
in
minimal
waste.
Bismuth
vanadate
(BiVO
4
stands
out
among
various
oxide
semiconductors
for
selective
under
visible
light
via
direct
two‐electron
oxygen
reduction
reaction
(ORR)
water
oxidation
(WOR)
pathways.
Significant
advancements
have
been
achieved
using
BiVO
‐based
materials
over
the
last
decade.
This
review
explores
photocatalysts
production,
focusing
photocatalytic
powder
suspension
(PS)
photoelectrochemical
(PEC)
systems,
representing
main
approaches
heterogenous
artificial
photosynthesis.
An
overview
fundamental
principles,
performance
assessment
methodologies,
photocatalyst
photoelectrode
development,
optimization
conditions
is
provided.
While
diverse
strategies,
heterojunction,
doping,
crystal
facet
engineering,
cocatalyst
loading,
surface
passivation,
proven
effective
enhancing
generation,
this
offers
insights
into
their
similar
distinct
implementations
within
PS
PEC
systems.
challenges
future
prospects
field
are
also
discussed
facilitate
rational
design
high‐performing
photoelectrodes
generation
light.
Language: Английский