Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 31, 2024
The photocatalytic conversion of carbon dioxide (CO
Language: Английский
Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 31, 2024
The photocatalytic conversion of carbon dioxide (CO
Language: Английский
International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 79, P. 1357 - 1364
Published: July 14, 2024
Language: Английский
Citations
5ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: April 23, 2025
The electrocatalytic urea oxidation reaction (UOR) is a promising approach to lowering the energy barrier of anode half-reaction in water splitting for energy-efficient hydrogen production and remove excess from blood or dialysis fluid. However, sluggish kinetics large overpotential caused by scaling relationships significantly limit development UOR technology. Herein, bifunctional amorphous M-CoS (M = Zr, Cu, Mn, Fe) nanosheets were synthesized via one-step electrodeposition process. Among them, Zr-CoS exhibited exceptional performance, achieving 10 mA cm-2 at an 1.26 V, outperforming recently reported catalysts, while CoS demonstrated evolution impressively low -175 mV. Density functional theory calculations revealed that doped Cu Zr ions migrated adsorption sites N atoms before after C-N cleavage, breaking limitation relationships. Meanwhile, cleavage step showed good linear relationship with variation integrated crystal orbital Hamilton population (ΔICOHP), indicating ΔICOHP was descriptor evaluate performances. This work not only emphasized outstanding performances but also offered innovative insights into role metal sulfides UOR.
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 179865 - 179865
Published: March 1, 2025
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 683, P. 546 - 554
Published: Dec. 26, 2024
Language: Английский
Citations
0Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 31, 2024
The photocatalytic conversion of carbon dioxide (CO
Language: Английский
Citations
0