Functional electrospun nanofibers: fabrication, properties, and applications in wound-healing process

RSC Advances, Journal Year: 2024, Volume and Issue: 14(5), P. 3359 - 3378

Published: Jan. 1, 2024

Electrostatic spinning as a technique for producing nanoscale fibers has recently attracted increasing attention due to its simplicity, versatility, and loadability.

Language: Английский

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Two 2D Metal–Organic Frameworks Based on Purine Carboxylic Acid Ligands for Photocatalytic Oxidation of Sulfides and CO₂ Chemical Fixation

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(20), P. 9109 - 9118

Published: May 7, 2024

Two two-dimensional (2D) layered metal-organic frameworks (MOFs), namely, {[Yb(

Language: Английский

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Electrochemical deposition for metal organic Frameworks: Advanced Energy, Catalysis, sensing and separation applications

Journal of Electroanalytical Chemistry, Journal Year: 2023, Volume and Issue: 937, P. 117417 - 117417

Published: April 5, 2023

Language: Английский

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Electrocatalytic Reactions for Converting CO2 to Value-Added Products: Recent Progress and Emerging Trends

International Journal of Molecular Sciences, Journal Year: 2023, Volume and Issue: 24(12), P. 9952 - 9952

Published: June 9, 2023

Carbon dioxide (CO2) emissions are an important environmental issue that causes greenhouse and climate change effects on the earth. Nowadays, CO2 has various conversion methods to be a potential carbon resource, such as photocatalytic, electrocatalytic, photo-electrocatalytic. into value-added products many advantages, including facile control of reaction rate by adjusting applied voltage minimal pollution. The development efficient electrocatalysts improving their viability with appropriate reactor designs is essential for commercialization this environmentally friendly method. In addition, microbial electrosynthesis which utilizes electroactive bio-film electrode catalyst can considered another option reduce CO2. This review highlights contribute increase in efficiency reduction (CO2R) processes through structure introduction electrolytes ionic liquid, sulfate, bicarbonate electrolytes, pH operating pressure temperature electrolyzer. It also presents research status, fundamental understanding (CO2RR) mechanisms, electrochemical CO2R technologies, challenges opportunities future research.

Language: Английский

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Ionic liquid post-modified carboxylate-rich MOFs for efficient catalytic CO₂ cycloaddition under solvent-free conditions

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(14), P. 6215 - 6223

Published: Jan. 1, 2024

Ionic liquid post-modified carboxylate-rich MOFs, which were synthesized and characterized, are highly efficient for catalytic epoxides CO 2 cycloaddition under solvent-free conditions.

Language: Английский

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Research on biomass energy and CO2 conversion to methanol: a combination of conventional and bibliometric review analysis

Carbon Research, Journal Year: 2025, Volume and Issue: 4(1)

Published: Jan. 8, 2025

Abstract The use of methanol as a chemical precursor and fuel additive has increased recently on global scale. Hence, this study combined bibliometric traditional review methods to assess the recent trends evolution production, well its use. According study, producing large scale from renewable sources is still hampered by immature technologies used in production. For instance, production via process biochemical conversion remains at laboratory level even though it proven be promising option. Cu-based catalysts, especially Cu-Zn-based were found most frequently catalysts for hydrogenation CO 2 due their superior activity. shows an annual growth rate 3.63% research within last decade, with 867 authors involved. China leads globally consumption research. highest collaboration occurred between United States America frequency six. proposed future directions, including evaluation environmental impact methanol, focusing entire life cycle, comparing approaches, streamlining procedures. It also recommended conduct flow chemistry novel reactor designs that enhance mass heat transfer catalytic reactors. Graphical

Language: Английский

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Doping and defect engineering in carbon-based electrocatalysts for enhanced electrochemical CO2 reduction: From 0D to 3D materials

Advances in Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 339, P. 103429 - 103429

Published: Feb. 6, 2025

Language: Английский

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Regulation Strategy of Nanostructured Engineering on Indium‐Based Materials for Electrocatalytic Conversion of CO₂

Small, Journal Year: 2023, Volume and Issue: 20(9)

Published: Oct. 16, 2023

Abstract Electrochemical carbon dioxide reduction (CO 2 RR), as an emerging technology, can combine with sustainable energies to convert CO into high value‐added products, providing effective pathway realize neutrality. However, the activation energy of , low mass transfer, and competitive hydrogen evolution reaction (HER) leads unsatisfied catalytic activity. Recently, Indium (In)‐based materials have attracted significant attention in RR a series regulation strategies nanostructured engineering are exploited rationally design various advanced In‐based electrocatalysts, which forces necessary comprehensive fundamental summary, but there is still scarcity. Herein, this review provides systematic discussion nanostructure for efficient electrocatalytic conversion fuels. These including morphology, size, composition, defects, surface modification, interfacial structure, alloying, single‐atom summarized exploring internal relationship between performance physicochemical properties catalysts. The correlation electronic structure adsorption behavior intermediates highlighted gain in‐depth understanding kinetics RR. Moreover, challenges opportunities proposed, expected inspire development other catalysts

Language: Английский

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Reaction Mechanisms and Applications of Single Atom Catalysts for Thermal-Catalytic Carbon Dioxide Hydrogenation Toward Oxygenates

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(21), P. 16434 - 16458

Published: Oct. 23, 2024

Thermo-catalytic CO2 hydrogenation to high-value oxygenates has been regarded as one of the most powerful strategies that can potentially alleviate excessive emissions. However, due high chemical stability and variability pathways, it is still challenging achieve highly active selective hydrogenation. Single atom catalysts (SACs) with ultrahigh metal utilization efficiency extraordinary electronic features have displayed growing importance for thermo-catalytic multiple developed improve performances. Here, we review breakthroughs in developing SACs efficient toward common (CO, HCOOH, CH3OH, CH3CH2OH) following order: first, an analysis reaction mechanisms thermodynamics challenges reactions; second, a summary SAs designed by dividing them into two categories single- dual-sites; third, discussion support effects focus on approaches regulating strong metal–support interaction (MSI). Summarily, current future perspectives develop higher-performance are presented. We expect this bring more design inspiration trigger innovation catalytic evolution materials eventually benefit achievement carbon-neutrality goal.

Language: Английский

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Role of the cathode chamber in microbial electrosynthesis: A comprehensive review of key factors

Engineering Microbiology, Journal Year: 2024, Volume and Issue: 4(3), P. 100141 - 100141

Published: Feb. 17, 2024

The consumption of non-renewable fossil fuels has directly contributed to a dramatic rise in global carbon dioxide (CO2) emissions, posing an ongoing threat the ecological security Earth. Microbial electrosynthesis (MES) is innovative energy regeneration strategy that offers gentle and efficient approach converting CO2 into high-value products. cathode chamber vital component MES system its internal factors play crucial roles improving performance system. Therefore, this review aimed provide detailed analysis key related topics covered include inward extracellular electron transfer pathways, materials, applied potentials, catholyte pH, reactor configuration. In addition, analyzes discusses challenges promising avenues for conversion products via MES.

Language: Английский

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