Solid State Ionics, Journal Year: 2024, Volume and Issue: 417, P. 116715 - 116715
Published: Oct. 11, 2024
Language: Английский
Solid State Ionics, Journal Year: 2024, Volume and Issue: 417, P. 116715 - 116715
Published: Oct. 11, 2024
Language: Английский
Carbon Neutralization, Journal Year: 2025, Volume and Issue: 4(2)
Published: Feb. 21, 2025
ABSTRACT Lithium iron phosphate (LiFePO 4 ) serves as a commonly used cathode material in lithium‐ion batteries and is an essential power source for consumer electronics electric vehicles. Nevertheless, significant degradation its electrochemical performance occurs at low temperatures, leading to energy losses, challenges charging, reduced lifespan, heightened safety concerns—critical factors LiFePO applications. This review outlines recent progress aimed enhancing the low‐temperature of batteries, concentrating on mechanisms involved various modification strategies. The primary contributing subzero temperatures are first examined. A variety strategies designed improve interfacial internal reaction kinetics cathodes under cold conditions emphasized, feasible approaches also presented. These include optimizing cell design enhance inherent reactivity employing heating techniques raise external temperatures. In conclusion, this discusses limitations associated with settings examines advancements from system level. insights provided intended motivate further developments other technologies tailored
Language: Английский
Citations
2International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 125, P. 37 - 47
Published: April 10, 2025
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160148 - 160148
Published: Feb. 1, 2025
Language: Английский
Citations
0ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: March 3, 2025
Language: Английский
Citations
0ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: March 14, 2025
Economical and high-safety LiMn0.85Fe0.15PO4/C cathode materials have gained significant attention recently due to their theoretical specific energy advantage of 18% compared LiFePO4. However, low electronic conductivity sluggish diffusion kinetics limit the practical applications LiMn0.85Fe0.15PO4/C. This paper presents a simple solid-state synthesis porous LMFM0.01P-2C4P, which is doped with Mg coated composite carbon. substitution for Mn shortens transport path lithium ions while increasing intrinsic structural stability. Additionally, 3D conductive network structure generated by carbon source (citric acid polyethylene glycol 400) improves effectively minimizes internal resistance battery. LMFM0.01P-2C4P consists secondary particles aggregated from primary smaller than 100 nm, each uniform layer. The lithium-ion coefficient greatly exceed those unmodified LMFP-4C, measuring 7.22 × 10-3 S cm-1 ∼10-12 cm2 s-1, respectively. Electrochemical studies demonstrate that delivers superior capacity 152.1 m Ah g-1 124.9 at 0.1C 1C, respectively, along retention 80.8% after 500 cycles 1C. initial LMFP-4C merely 104.1 mAh only 65.7% cycles. work useful way enhance phosphate lithium/sodium-ion batteries.
Language: Английский
Citations
0Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
The dual coatings with different functional roles synergistically improve electronic conductivity and lithium-ion diffusion coefficient, while effectively inhibiting manganese dissolution.
Language: Английский
Citations
0ChemElectroChem, Journal Year: 2024, Volume and Issue: 11(21)
Published: Oct. 21, 2024
Abstract The practical application of LiMn 1−x Fe x PO 4 as a cathode material is hindered considerably by its poor electronic conductivity and slow lithium‐ion diffusion. In the present study, uniform nitrogen‐doped carbon coating on 0.7 0.3 (LiMn @NC) was achieved using ethylene diamine tetraacetic acid (EDTA) chelating agent source. layer enhanced ionic diffusion cathode. Furthermore, prevented metal ion dissolution stabilized crystal structure. resulting @NC‐2 sample demonstrated superior performance with specific capacity 152.5 mAh g −1 at 0.1 C preserved 93.7 % this over 200 cycles 1 C. Meanwhile, high Li + coefficient (3.98×10 −11 cm 2 s ) electrical (1.47×10 −2 S ). This study presents novel approach to designing high‐performance materials cost‐effective straightforward process.
Language: Английский
Citations
1Solid State Ionics, Journal Year: 2024, Volume and Issue: 417, P. 116715 - 116715
Published: Oct. 11, 2024
Language: Английский
Citations
0