Optimization of Paper-Based Alveolar-Mimicking SERS Sensor for High-Sensitivity Detection of Antifungal Agent DOI Creative Commons
Hyunjun Park,

Kyunghwan Chai,

Eugene Park

et al.

Biosensors, Journal Year: 2024, Volume and Issue: 14(12), P. 566 - 566

Published: Nov. 22, 2024

Crystal violet (CV) is a disinfectant and antifungal agent used in aquaculture that plays vital role treating aquatic diseases sterilizing water. However, its potential for strong toxicity, including carcinogenicity mutagenicity, upon accumulation the body raises concerns regarding safe use. Therefore, there growing need quantitative detection of CV early application stages to ensure human safety. Recently, Raman spectroscopy-based surface-enhanced scattering (SERS) research has been actively conducted; consequently, an alveolar-mimicking SERS paper (AMSP) inspired by structure lungs was developed. The AMSP optimized through various factors, type, reducing agent, concentration, reaction time. This optimization enhanced surface area interaction with target substances promoted hotspot formation, resulting performance. substrate exhibited exceptional uniformity, reproducibility, reliability. successfully detected at concentration 1 nM laboratory settings. Furthermore, real-world environmental samples, fish farm water serum, confirming as practical monitoring platform samples.

Language: Английский

Waste Cooking Oils as a Sustainable Feedstock for Bio-based Application: A Systematic Review DOI Creative Commons
Antonio Caporusso, Matteo Radice, Antonino Biundo

et al.

Journal of Biotechnology, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 1, 2025

Waste cooking oils (WCOs) are common wastes and promising green, eco-friendly sustainable feedstocks for bio-based applications. While the primary valorisation strategy revolves around concept of waste-to energy, new research trends have emerged in last decade. This systematic review provides a comprehensive analysis current state art conversion WCOs into molecules. Based on PRISMA methodology, 64 papers were selected using different databases sources, such as: PubMed, ScienceDirect, Scopus MDPI. The data extraction process focused studies reporting biological chemical value-added bioproducts. Many publications deal with development bioactive molecules, including biosurfactants, application pharmaceuticals, food, cosmetics, bioremediation. Bioconversion processes mainly featured engineered Yarrowia lipolytica Escherichia coli strains, even if additional microorganisms also employed. In same way, been thoroughly studied. A smaller segment is directed to production feed supplements soaps. Regulatory constraints limit further due potential contaminants, while soap needs stability studies. present shows outcomes through molecules products. Despite wide range applications, these findings identify that scalability economic sustainability require investigation. study seeks summarize gaps advance industrialization valorisation.

Language: Английский

Citations

2

Machine Learning-Based Interfacial Tension Equations for (H2 + CO2)-Water/Brine Systems over a Wide Range of Temperature and Pressure DOI
Minjunshi Xie, Mingshan Zhang, Zhehui Jin

et al.

Langmuir, Journal Year: 2024, Volume and Issue: 40(10), P. 5369 - 5377

Published: Feb. 28, 2024

Large-scale underground hydrogen storage (UHS) plays a vital role in energy transition. H2-brine interfacial tension (IFT) is crucial parameter structural trapping geological locations and gas–water two-phase flow subsurface porous media. On the other hand, cushion gas, such as CO2, often co-injected with H2 to retain reservoir pressure. Therefore, it imperative accurately predict (H2 + CO2)-water/brine IFT under UHS conditions. While there have been number of experimental measurements on H2-water/brine IFT, an accurate efficient model conditions still lacking. In this work, we use molecular dynamics (MD) simulations generate extensive databank (840 data points) over wide range temperature (from 298 373 K), pressure 50 400 bar), gas composition, brine salinity (up 3.15 mol/kg) for typical conditions, which used develop machine learning (ML)-based equation. Our ML-based equation validated by comparing available equations various systems (H2-brine/water, CO2-brine/water, CO2)-brine/water), rendering generally good performance (with R2 = 0.902 against 601 points). The developed can be readily applied implemented applications.

Language: Английский

Citations

8

Phylogenomics, Classification, and Lifestyle Evolution in Raft- and Nursery web- Spiders (Araneae: Dolomedidae and Pisauridae) DOI Creative Commons
Kuang‐Ping Yu, Ren‐Chung Cheng, Charles R. Haddad

et al.

bioRxiv (Cold Spring Harbor Laboratory), Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 24, 2024

Abstract Pisauridae Simon, 1890 or “nursery web spiders” are a global and heterogenous assemblage of spider genera with diverse lifestyles, containing builders webless species, as well terrestrial semi-aquatic notably “fishing spiders”, genus Dolomedes Latreille, 1804. Incomplete, unresolved, conflicting phylogenies have so far hampered testing for pisaurid monophyly evolution. Here, we broadly address these questions within phylogenomic comparative framework. Our goals i) reconstruction robust phylogeny to test the amend classification; ii) estimation evolutionary shifts trends in lifestyles capture webs; iii) evaluation hypotheses morphological trait association lifestyle. To this end generate subgenomic data (ultraconserved elements UCE) 53 species 28 genera. We analyze using maximum likelihood, Bayesian, multi-species coalescence approaches, two different phylogenetic time calibration methods, RelTime MCMCtree. Consistent across analytical our reject both . “Pisaurid” fall into three clades: 1) Focal Clade I groups majority, including Pisaura 1886, hence representing true pisaurids; 2) II = Blandinia Tonini et al., 2016 is sister Trechaleidae Lycosidae Sundevall, 1833; 3) III fishing raft spiders , Megadolomedes Davies Raven, 1980, Ornodolomedes Raven Hebron, 2018 II, Trechaleidae, Lycosidae. taxonomy, based on complementary taxa evidence, resurrects Dolomedidae 1876 include Oceanic Bradystichus 1884, Caledomedes 2018, Mangromedes Tasmomedes 2018. Both MCMCtree analyses yield comparable divergence estimations: origin estimated between 29 40 Ma; 21 34 10 17 9 16 Ma. In order avoid misleading significant correlations and/or over-resolved ancestral states, performed taxon sampling bias correction all analyses. Evolutionary reconstruct lifestyle large clade pisaurids, lycosids, trechaleids, dolomedids, several reversals Capture webs evolved at least times, reversals. Counter expectation, evolution independent. Although leg tarsus lengths do not indicate significantly larger than ones. explain pattern biomechanical threshold over which surface tension can be broken while forage under water. time-calibrated that web-building from ancestors coincided cooling drying climates mid-Miocene. therefore hypothesize climatic changes acted strong selection pressures toward diversification.

Language: Английский

Citations

3

Natural Mucilage From Phoenix dactylifera L. as an Alternative for Artificial Saliva DOI Creative Commons
Jirapornchai Suksaeree, Pattwat Maneewattanapinyo

Scientifica, Journal Year: 2024, Volume and Issue: 2024(1)

Published: Jan. 1, 2024

The sensation of dry mouth is a clinical illness known as xerostomia. Treatment necessary for alleviating symptoms in patients who experience either transient or persistent mouth. It essential to develop artificial saliva this purpose. fruit the Phoenix dactylifera edible and has been used food. Its mucilage from dried fruits was extracted by soaking distilled water precipitated with 90% v/v ethanol. P. producing combined other components including proteins electrolytes. translucent light brown gel solution seen using mucilage. measured relative density ranged 1.02 1.15 g/mL. Artificial had become more viscous addition its concentration. Their pH values between 6.98 7.15. produced wetting time ranging 7.53 9.70 min, which similar typical human saliva. could form film after certain periods. found that exhibited many adsorption bands corresponding various biomolecules, such protein, carbohydrate, lipid, unique peak at 275 nm. results investigation suggest formulation may be utilized treat xerostomia temporarily lubricating hydrating their mouths when they

Language: Английский

Citations

0

Optimization of Paper-Based Alveolar-Mimicking SERS Sensor for High-Sensitivity Detection of Antifungal Agent DOI Creative Commons
Hyunjun Park,

Kyunghwan Chai,

Eugene Park

et al.

Biosensors, Journal Year: 2024, Volume and Issue: 14(12), P. 566 - 566

Published: Nov. 22, 2024

Crystal violet (CV) is a disinfectant and antifungal agent used in aquaculture that plays vital role treating aquatic diseases sterilizing water. However, its potential for strong toxicity, including carcinogenicity mutagenicity, upon accumulation the body raises concerns regarding safe use. Therefore, there growing need quantitative detection of CV early application stages to ensure human safety. Recently, Raman spectroscopy-based surface-enhanced scattering (SERS) research has been actively conducted; consequently, an alveolar-mimicking SERS paper (AMSP) inspired by structure lungs was developed. The AMSP optimized through various factors, type, reducing agent, concentration, reaction time. This optimization enhanced surface area interaction with target substances promoted hotspot formation, resulting performance. substrate exhibited exceptional uniformity, reproducibility, reliability. successfully detected at concentration 1 nM laboratory settings. Furthermore, real-world environmental samples, fish farm water serum, confirming as practical monitoring platform samples.

Language: Английский

Citations

0