Cited by Multi-descriptors guided constructing the microenvironment of frustrated Lewis pair bi-active sites in functionalized MOFs toward Sabatier optimal for catalytic hydrogenation

Defect Engineering in Ce-Based Metal–Organic Frameworks toward Enhanced Catalytic Performance for Hydrogenation of Dicyclopentadiene DOI

Shenglan Zhou,

Tao Ban, Li Tian

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(29), P. 38177 - 38187

Published: July 16, 2024

Defective metal–organic frameworks (MOFs) have shown great potential for catalysis due to abundant active sites and adjustable physical chemical properties. A series of Ce-based MOFs with different defect contents were synthesized via a modulator-induced engineering strategy the aid cell pulverization technique. The effects modulators on pore structure, morphology, valence distribution Ce, Lewis acidity Ce-MOF-801 systematically investigated. Among samples studied, optimal Ce-MOF-801-50eq sample exhibited remarkable catalytic activity DCPD hydrogenation, achieving conversion rate 100%, which is significantly higher compared other Ce-MOF-801-neq as well Zr-MOF-801-50eq Hf-MOF-801-50eq samples. enhanced performance can be attributed advantages provided by engineering, such high specific surface area, proper size distribution, unsaturated metal sites, Ce3+/Ce4+ atom ratio, been supported various characterizations. This study provides important insights into rational design Ce-MOFs in field hydrogenation.

Language: Английский

Citations

Advancements in Nanoscale MOFs-Based Catalytic Materials: Synthesis Strategies and Applications DOI

Wen Meng,

Weiyao Yang,

Zhi-Ping Zhao

et al.

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 115613 - 115613

Published: Jan. 1, 2025

Language: Английский

Citations

Linker engineering regulating the electron transfer between Ni nanoparticles and RE-MOFs for enhanced DCPD hydrogenation performance DOI

Li Tian, Juan Chen, Dandan Jia

et al.

Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 43, P. 102521 - 102521

Published: Jan. 1, 2025

Language: Английский

Citations

Reverse modulation of defect density of Ce-MOF-808 by solvent-assisted ligand exchange for dicyclopentadiene hydrogenation DOI

Danfeng Zhao,

Feinan Hu, Rushuo Li

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 3, 2025

Language: Английский

Citations

Mechanism of coordinated anions regulating the photocatalytic performance of Cu(I) metal–organic frameworks DOI

Shixiong Li,

Xiu Wu,

Yuzheng Cao

et al.

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114321 - 114321

Published: March 1, 2025

Language: Английский

Citations

Promoted synergistic interactions between Ce and Ni in hierarchical porous Ce-UiO-66 supported Ni NPs for dicyclopentadiene hydrogenation to tetrahydrodicyclopentadiene DOI

Feinan Hu, Rushuo Li,

Danfeng Zhao

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 163022 - 163022

Published: March 1, 2025

Language: Английский

Citations

Regulating electron transfer between valence-variable cuprum and cerium sites within bimetallic metal–organic framework towards enhanced catalytic hydrogenation performance DOI

Xinmeng Xu,

Zuoshuai Xi,

Danfeng Zhao

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 679, P. 1159 - 1170

Published: Oct. 12, 2024

Language: Английский

Citations

Multi-descriptors guided constructing the microenvironment of frustrated Lewis pair bi-active sites in functionalized MOFs toward Sabatier optimal for catalytic hydrogenation DOI

Linmeng Wang,

Shihao Feng,

Hongyi Gao

et al.

Journal of Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 116165 - 116165

Published: April 1, 2025

Language: Английский

Citations