ACS Materials Letters,
Journal Year:
2022,
Volume and Issue:
4(11), P. 2058 - 2079
Published: Sept. 26, 2022
The
electrocatalytic
carbon
dioxide
reduction
reaction
(CO2RR)
holds
great
potential
in
promoting
neutral
through
effectively
converting
CO2
molecules
to
useful
chemicals
and
fuels.
high-efficiency
electrochemical
conversion
of
single-carbon
products
has
been
well
realized,
while
more
efforts
are
needed
for
the
generation
high-value
multicarbon
products.
Metal–organic
frameworks
(MOFs),
featuring
porous
structures,
high
chemical
tunability,
ultralarge
surface
area,
have
attracted
increasing
attention
CO2RR.
Herein,
we
review
recent
progress
CO2RR
on
MOF-based
materials
toward
First,
structure
MOFs
is
briefly
introduced.
Then,
performance
corresponding
catalytic
mechanism
pristine
(classified
according
kind
organic
ligands/linkers)
MOF-derived
(including
metal
nanomaterials,
single-atom
catalysts
nanocomposites)
product
systematically
discussed.
Finally,
critical
challenges
opportunities
highlighted
inspire
rational
design
targeted
synthesis
advanced
high-performance
eScience,
Journal Year:
2023,
Volume and Issue:
3(2), P. 100092 - 100092
Published: Jan. 10, 2023
Micro/nano
metal–organic
frameworks
(MOFs)
have
attracted
significant
attention
in
recent
years
due
to
their
numerous
unique
properties,
with
many
synthetic
methods
and
strategies
being
reported
for
constructing
MOFs
specific
micro/nano
structures.
In
addition,
the
design
of
energy
storage
conversion
applications
study
structure–activity
relationship
also
become
research
hotspots.
Herein,
a
comprehensive
overview
progress
on
is
presented.
We
begin
brief
introduction
various
synthesis
controlling
morphology
MOFs.
Subsequently,
structure-dependent
properties
as
electrode
materials
or
catalysts
terms
batteries,
supercapacitors,
catalysis
are
discussed.
Finally,
remaining
challenges
future
perspectives
this
field
Overall,
review
expected
inspire
advanced
efficient
technologies.
Catalysts,
Journal Year:
2021,
Volume and Issue:
11(10), P. 1222 - 1222
Published: Oct. 11, 2021
The
market
for
industrial
enzymes
has
witnessed
constant
growth,
which
is
currently
around
7%
a
year,
projected
to
reach
$10.5
billion
in
2024.
Lipases
are
hydrolase
naturally
responsible
triglyceride
hydrolysis.
They
the
most
expansively
used
biocatalysts,
with
wide
application
broad
range
of
industries.
However,
these
biocatalytic
processes
usually
limited
by
low
stability
enzyme,
half-life
time,
and
required
solve
problems
complex
lack
feasibility
at
scale.
Emerging
technologies
create
new
materials
enzyme
carriers
sophisticate
well-known
immobilization
principles
produce
more
robust,
eco-friendlier,
cheaper
biocatalysts.
Therefore,
this
review
discusses
trending
studies
applications
protocols
lipase
immobilization,
analyzing
their
advantages
disadvantages.
Finally,
it
summarizes
current
challenges
potential
alternatives
lipases
level.
Small,
Journal Year:
2023,
Volume and Issue:
19(15)
Published: Jan. 5, 2023
Hydrogen,
a
clean
and
flexible
energy
carrier,
can
be
efficiently
produced
by
electrocatalytic
water
splitting.
To
accelerate
the
sluggish
hydrogen
evolution
reaction
oxygen
kinetics
in
splitting
process,
highly
active
electrocatalysts
are
essential
for
lowering
barriers,
thereby
improving
efficiency
of
overall
Combining
distinctive
advantages
metal-organic
frameworks
(MOFs)
with
physicochemical
properties
2D
materials
such
as
large
surface
area,
tunable
structure,
accessible
sites,
enhanced
conductivity,
MOFs
have
attracted
intensive
attention
field
electrocatalysis.
Different
strategies,
conductivities
MOFs,
reducing
thicknesses
MOF
nanosheets,
integrating
conductive
particles
or
substrates,
developed
to
promote
catalytic
performances
pristine
MOFs.
This
review
summarizes
recent
advances
MOF-based
electrolysis.
In
particular,
their
intrinsic
detailly
analyzed
reveal
important
roles
inherent
centers,
other
situ
generated
phases
from
responsible
reactions.
Finally,
challenges
development
prospects
future
applications
discussed.
Carbon Energy,
Journal Year:
2022,
Volume and Issue:
4(2), P. 246 - 281
Published: March 1, 2022
Abstract
Because
of
features,
such
as
adjustable
structures,
high
porosity,
and
crystallinity,
metal–organic
frameworks
(MOFs)
deservedly
have
received
considerable
attention.
Nevertheless,
there
is
still
room
for
improvements
in
the
electrical
conductivity
chemical
stability
some
MOFs,
because
which
they
cannot
be
utilized
electrode
materials.
Fortunately,
MOF
derivatives
widespread
attention
recent
years,
especially
phosphide
materials,
are
widely
used
practical
applications
their
outstanding
conductivity,
excellent
specific
surface
area,
standout
charge
mobility.
In
this
review,
latest
developments
MOF‐derived
phosphides
electrocatalysis
related
to
energy,
including
performance
terms
electrochemical
energy
storage
ingenious
strategies,
diversified
synthetic
approaches
been
emphasized
summarized.
Additionally,
arduous
task
feasible
proposals
also
discussed.
