ACS Materials Letters,
Journal Year:
2022,
Volume and Issue:
4(11), P. 2058 - 2079
Published: Sept. 26, 2022
The
electrocatalytic
carbon
dioxide
reduction
reaction
(CO2RR)
holds
great
potential
in
promoting
neutral
through
effectively
converting
CO2
molecules
to
useful
chemicals
and
fuels.
high-efficiency
electrochemical
conversion
of
single-carbon
products
has
been
well
realized,
while
more
efforts
are
needed
for
the
generation
high-value
multicarbon
products.
Metal–organic
frameworks
(MOFs),
featuring
porous
structures,
high
chemical
tunability,
ultralarge
surface
area,
have
attracted
increasing
attention
CO2RR.
Herein,
we
review
recent
progress
CO2RR
on
MOF-based
materials
toward
First,
structure
MOFs
is
briefly
introduced.
Then,
performance
corresponding
catalytic
mechanism
pristine
(classified
according
kind
organic
ligands/linkers)
MOF-derived
(including
metal
nanomaterials,
single-atom
catalysts
nanocomposites)
product
systematically
discussed.
Finally,
critical
challenges
opportunities
highlighted
inspire
rational
design
targeted
synthesis
advanced
high-performance
Cell Reports Physical Science,
Journal Year:
2023,
Volume and Issue:
4(3), P. 101301 - 101301
Published: Feb. 22, 2023
Metal-organic
framework
(MOF)
backbone
materials,
as
nanoporous
have
outstanding
performance
in
studies
on
adsorption
and
catalysis
by
virtue
of
their
high
porosity,
large
specific
surface
area,
unsaturated
metal
coordination
sites,
diverse
structures
functions.
However,
it
is
difficult
to
synthesize
truly
perfect
MOFs
practical
experiments
because
any
slight
change
reaction
conditions
may
lead
defects
the
material.
This
suggests
that
be
prevalent
a
systematic
understanding
would
beneficial
controlling
material
properties.
Meanwhile,
detection
synthesis
defective
MOF
materials
are
still
development
stage.
In
this
paper,
methods,
characterization
techniques,
optimization
strategies
reviewed.
paper
discusses
current
difficulties
makes
suggestions
for
future
work.
Advanced Science,
Journal Year:
2023,
Volume and Issue:
10(10)
Published: Jan. 22, 2023
The
use
of
metal-organic
frameworks
(MOFs)
in
solid-state
electrolytes
(SSEs)
has
been
a
very
attractive
research
area
that
received
widespread
attention
the
modern
world.
SSEs
can
be
divided
into
different
types,
some
which
combined
with
MOFs
to
improve
electrochemical
performance
batteries
by
taking
advantage
high
surface
and
porosity
MOFs.
However,
it
also
faces
many
serious
problems
challenges.
In
this
review,
types
are
classified
changes
these
after
addition
described.
Afterward,
attached
introduced
for
battery
applications
effects
on
cells
Finally,
challenges
faced
materials
presented,
then
solutions
development
expectations
given.
Advanced Materials,
Journal Year:
2023,
Volume and Issue:
35(48)
Published: June 29, 2023
The
use
of
conductive
MOFs
(c-MOFs)
in
zinc-based
batteries
has
been
a
popular
research
direction.
Zinc-based
are
widely
used
with
the
advantages
high
specific
capacity
and
safety
stability,
but
they
also
face
many
problems.
c-MOFs
have
excellent
conductivity
compared
other
primitive
MOFs,
therefore
better
applications
batteries.
In
this
paper,
transfer
mechanisms
unique
charges
c-MOFs:
hop
transport
band
transport,
respectively,
discussed
way
electron
is
further
addressed.
Then,
various
ways
to
prepare
introduced,
among
which
solvothermal,
interfacial
synthesis,
postprocessing
methods
used.
addition,
terms
their
role
performance
different
types
Finally,
current
problems
prospects
for
future
development
presented.
Crystal Growth & Design,
Journal Year:
2024,
Volume and Issue:
24(5), P. 2235 - 2265
Published: Feb. 26, 2024
Metal-organic
frameworks
(MOFs),
formed
by
the
combination
of
both
inorganic
and
organic
components,
have
attracted
special
attention
for
their
tunable
porous
structures,
chemical
functional
diversities,
enormous
applications
in
gas
storage,
catalysis,
sensing,
etc.
Recently,
electronic
MOFs
like
electrocatalysis,
supercapacitors,
batteries,
electrochemical
etc.,
become
a
major
research
topic
MOF
chemistry.
However,
low
electrical
conductivity
most
represents
handicap
development
these
emerging
applications.
To
overcome
limitations,
different
strategies
been
developed
to
enhance
implementation
devices.
In
this
review,
we
outline
all
employed
increase
conduction
intrinsically
(framework-modulated)
extrinsically
(guests-modulated)
conducting
MOFs.
Energy Material Advances,
Journal Year:
2023,
Volume and Issue:
4
Published: Jan. 1, 2023
Over
the
past
few
decades,
metal–organic
frameworks
(MOFs)
have
been
recognized
as
most
attractive
energy-involved
materials
due
to
their
unique
features,
including
ultrahigh
specific
surface
area,
superior
porous
structure,
and
excellent
customizability.
Nevertheless,
pristine
MOFs
suffer
from
low
electronic
conductivity
chemical
instability,
which
severely
hindered
large-scale
applications.
Recently,
MXene
with
abundant
terminations
high
metallic
suggested
a
valid
substrate
improve
stability
of
MOFs.
Importantly,
MXene/MOF
composites
enhanced
conductivity,
rich
chemistry,
hierarchical
structure
facilitate
rapid
electron/ion
transfer
deliver
better
electrochemical
properties
than
that
original
through
synergistic
effects.
Moreover,
can
be
designed
into
various
derivatives
desired
architecture
performance.
Therefore,
elaborate
synthesis
hybrids
for
devices
are
great
interest.
Herein,
we
provided
state-of-the-art
review
on
progress
in
terms
strategies
Furthermore,
put
forward
current
challenges
feasible
research
directions
future
development.
Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 15, 2024
Metal-organic
frameworks
(MOFs)
are
composed
of
metal
nodes
and
organic
linkers
that
can
self-assemble
into
an
infinite
network.
The
high
porosity
large
surface
area
MOFs
facilitate
the
effective
enrichment
mass
transfer
analytes,
which
enhance
signal
response
improve
sensitivity
electrochemical
sensors.
Additionally,
their
derivatives
possess
properties
unsaturated
sites
tunable
structures,
collectively
demonstrating
potential
for
sensing.
This
paper
summarizes
preparation
methods,
structural
properties,
applications
in
sensing,
emphasizing
sensors'
selectivity
from
perspectives
direct
indirect
detection.
it
also
explores
future
directions
prospects
with
aim
overcoming
current
limitations
through
innovative
approaches.
Nanoscale,
Journal Year:
2024,
Volume and Issue:
16(9), P. 4434 - 4483
Published: Jan. 1, 2024
Metal-organic
frameworks
have
become
promising
stimuli-responsive
agents
to
release
the
loaded
therapeutic
in
target
site
achieve
more
precise
drug
delivery
due
their
high
loading,
excellent
biocompatibility,
and
stimuli-responsiveness.
Nanoscale,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Schematic
of
functional
materials
for
electrochemical
sensors,
showcasing
MWCNTs,
CNFs,
GO,
Pd,
Pt,
Ni,
Fe,
Co,
COFs,
MOFs
detecting
heavy
metal
ions
(Pb,
Cd,
Hg,
Cu,
Cr,
As)
in
complex
environments
with
high
sensitivity
and
reliability.
