ACS Materials Letters,
Journal Year:
2022,
Volume and Issue:
4(11), P. 2058 - 2079
Published: Sept. 26, 2022
The
electrocatalytic
carbon
dioxide
reduction
reaction
(CO2RR)
holds
great
potential
in
promoting
neutral
through
effectively
converting
CO2
molecules
to
useful
chemicals
and
fuels.
high-efficiency
electrochemical
conversion
of
single-carbon
products
has
been
well
realized,
while
more
efforts
are
needed
for
the
generation
high-value
multicarbon
products.
Metal–organic
frameworks
(MOFs),
featuring
porous
structures,
high
chemical
tunability,
ultralarge
surface
area,
have
attracted
increasing
attention
CO2RR.
Herein,
we
review
recent
progress
CO2RR
on
MOF-based
materials
toward
First,
structure
MOFs
is
briefly
introduced.
Then,
performance
corresponding
catalytic
mechanism
pristine
(classified
according
kind
organic
ligands/linkers)
MOF-derived
(including
metal
nanomaterials,
single-atom
catalysts
nanocomposites)
product
systematically
discussed.
Finally,
critical
challenges
opportunities
highlighted
inspire
rational
design
targeted
synthesis
advanced
high-performance
Nature Communications,
Journal Year:
2025,
Volume and Issue:
16(1)
Published: April 10, 2025
Current
strategies
to
tailor
the
formation
of
nanoparticle
clusters
require
specificity
and
directionality
built
into
surface
functionalization
nanoparticles
by
involved
chemistries
that
can
alter
their
properties.
Here,
we
describe
a
non-disruptive
approach
place
nanomaterials
different
shapes
between
nanosheets,
i.e.,
nano-sandwiches,
absent
any
pre-modification
components.
We
demonstrate
this
with
metal-organic
frameworks
(MOFs)
silicon
oxide
(SiO2)
sandwiched
graphene
(GO)
MOF-GO
SiO2-GO,
respectively.
For
MOF-GO,
MOF
shows
significantly
enhanced
conductivity
retains
its
original
crystallinity,
even
after
one-year
exposure
aqueous
acid/base
solutions,
where
GO
effectively
encapsulates
MOF,
shielding
it
from
polar
molecules
ions.
The
MOF-GOs
are
shown
capture
CO2
high-humidity
flue
gas
while
fully
maintaining
crystallinities
porosities.
Similar
behavior
is
found
for
other
MOFs,
including
water-sensitive
HKUST-1
MOF-5,
promoting
use
MOFs
in
practical
applications.
sandwich
strategy
provides
opportunities
materials
science
design
consisting
predetermined
spatial
arrangements.
Inorganic Chemistry,
Journal Year:
2021,
Volume and Issue:
60(17), P. 13168 - 13176
Published: Aug. 19, 2021
Controlling
the
growth
of
metal–organic
frameworks
(MOFs)
at
micro-/nanoscopic
scale
will
result
in
new
physical
properties
and
novel
functions
into
materials
without
changing
chemical
identities
characteristic
features
MOFs
themselves.
Herein,
we
report
a
facile
approach
to
synthesize
series
[Co-MOF,
CoxNiy-MOFs
(x
y
represent
molar
ratio
Co2+
Ni2+
x/y
=
1:1,
1:5,
1:10,
1:15,
1:20),
Ni-MOF]
with
one-dimensional
micro-/nanoscaled
rod-like
architecture.
From
Co-MOF
Ni-MOF,
diameters
rods
turn
be
spindly
increase
content
which
facilitate
supercapacitor
performances.
Interestingly,
Co1Ni20-MOF
exhibits
highest
specific
capacity
597
F
g–1
0.5
A
excellent
cycle
performance
(retained
93.59%
after
4000
cycles)
among
these
MOF
owing
its
micro-/nanorod
structure
smaller
diameter
synergy
effect
between
optimum
Ni2+.
RSC Advances,
Journal Year:
2021,
Volume and Issue:
11(47), P. 29247 - 29266
Published: Jan. 1, 2021
Metal-organic
frameworks
(MOFs)
with
efficient
surface
and
structural
properties
have
risen
as
a
distinctive
class
of
porous
materials
through
the
last
few
decades,
which
has
enabled
MOFs
to
gain
attention
in
wide
range
applications
like
drug
delivery,
gas
separation
storage,
catalysis
sensors.
Likewise,
they
also
emerged
active
energy
storage
devices
owing
their
remarkable
conducting
properties.
garnered
great
interest
high-energy-density
rechargeable
batteries
super-capacitors.
Herein
study
presents
expanding
diversity,
structures
chemical
compositions
can
be
tuned
at
molecular
level.
It
aims
evaluate
inherently
framework
how
it
facilitates
electronic
ionic
transportation
charging
discharging
cycles
lithium-ion
batteries.
In
this
review
we
summarized
various
synthesis
paths
achieve
particular
metal-organic
framework.
This
focuses
mainly
on
implementation
anode
cathode
for
(LIBs)
an
evaluation
influence
cyclic
stability
discharge
capacity.
For
purpose,
brief
assessment
is
made
recent
developments
or
would
provide
enlightenment
optimizing
reaction
conditions
designing
MOF
structure
battery
community
electrochemical
applications.
ACS Materials Letters,
Journal Year:
2022,
Volume and Issue:
4(11), P. 2058 - 2079
Published: Sept. 26, 2022
The
electrocatalytic
carbon
dioxide
reduction
reaction
(CO2RR)
holds
great
potential
in
promoting
neutral
through
effectively
converting
CO2
molecules
to
useful
chemicals
and
fuels.
high-efficiency
electrochemical
conversion
of
single-carbon
products
has
been
well
realized,
while
more
efforts
are
needed
for
the
generation
high-value
multicarbon
products.
Metal–organic
frameworks
(MOFs),
featuring
porous
structures,
high
chemical
tunability,
ultralarge
surface
area,
have
attracted
increasing
attention
CO2RR.
Herein,
we
review
recent
progress
CO2RR
on
MOF-based
materials
toward
First,
structure
MOFs
is
briefly
introduced.
Then,
performance
corresponding
catalytic
mechanism
pristine
(classified
according
kind
organic
ligands/linkers)
MOF-derived
(including
metal
nanomaterials,
single-atom
catalysts
nanocomposites)
product
systematically
discussed.
Finally,
critical
challenges
opportunities
highlighted
inspire
rational
design
targeted
synthesis
advanced
high-performance
