Inorganic Chemistry Frontiers,
Journal Year:
2023,
Volume and Issue:
10(7), P. 2067 - 2074
Published: Jan. 1, 2023
A
sunflower-like
Ir,
Fe-codoped
Co(OH)
2
catalyst
assembled
by
nanosheets
is
designed
for
boosting
electrocatalytic
OER,
where
dual-cation
doping
can
significantly
decrease
the
energy
barrier
of
rate-determining
step
OER.
Inorganic Chemistry,
Journal Year:
2023,
Volume and Issue:
62(4), P. 1659 - 1666
Published: Jan. 17, 2023
Rational
design
of
fast
and
sensitive
determination
nitrite
(NO2-)
from
a
complicated
actual
sample
overtakes
crucial
role
in
constructing
high-efficiency
sensing
platform.
Herein,
visual
NO2-
platform
with
outstanding
selectivity,
sensitivity,
stability
based
on
surface
plasmon
resonance
(SPR)-enhanced
oxidase-like
activity
has
been
proposed.
Benefiting
the
intrinsic
photocatalytic
limited
light
penetration
ZnS,
ZnS
decorated
Ag
nanowires
(Ag@ZnS)
is
determined.
It
demonstrated
that
electrons
are
generated
efficiently
then
transferred
into
hot
help
localized
SPR
excitation,
thus
greatly
oxidating
colorless
3,3',5,5'-tetramethylbenzidine
(TMB)
to
produce
dark
blue
oxidized
TMB
(oxTMB).
When
added
reaction
system,
oxTMB
will
selectively
react
generate
diazotized
oxTMB,
leading
color
change
green
subsequently
yellow.
Owing
specific
recognition
between
recovery
catalytic
induced
an
enhanced
colorimetric
test
wider
linear
range
for
determination,
ultralow
detection
limit
0.1
μM,
excellent
practicability
application
real
samples.
This
plasmon-enhanced
not
only
provides
smart
approach
realize
assay
high
sensitivity
simplicity
but
also
modulates
activities.
Inorganic Chemistry Frontiers,
Journal Year:
2023,
Volume and Issue:
10(7), P. 2067 - 2074
Published: Jan. 1, 2023
A
sunflower-like
Ir,
Fe-codoped
Co(OH)
2
catalyst
assembled
by
nanosheets
is
designed
for
boosting
electrocatalytic
OER,
where
dual-cation
doping
can
significantly
decrease
the
energy
barrier
of
rate-determining
step
OER.