Advanced Composites and Hybrid Materials,
Journal Year:
2024,
Volume and Issue:
7(6)
Published: Oct. 30, 2024
Abstract
Metal–organic
frameworks
(MOFs)
have
emerged
as
a
versatile
class
of
porous
materials
with
tremendous
potential
for
various
applications,
including
energy
storage
devices.
This
review
provides
comprehensive
analysis
recent
advancements
and
applications
MOFs
in
the
field
brief
overview
fundamental
aspects
MOFs,
their
synthesis,
structural
diversity,
tuneable
properties.
been
extensively
investigated
advanced
systems
supercapacitors.
can
be
employed
electrode
materials,
separators,
catalysts,
offering
enhanced
electrochemical
performance,
improved
charge/discharge
rates,
prolonged
cycling
stability.
The
unique
tunability
allows
rational
design
tailored
desired
properties,
such
high
specific
capacity,
excellent
conductivity,
superior
developments
MOF-based
capacitors,
particularly
significant
progress
reported
achieving
power
densities,
are
noteworthy.
exceptional
charge
capacity
combined
facile
synthesis
scalability,
makes
them
promising
candidates
next-generation
technologies.
sheds
light
on
challenges
opportunities
practical
implementation
devices
discusses
strategies
enhancing
stability
different
environments,
improving
electrical
developing
scalable
methods.
We
briefly
discuss
perspectives
future
directions,
particular
focus
research
development
use
applications.
Energy Strategy Reviews,
Journal Year:
2024,
Volume and Issue:
54, P. 101482 - 101482
Published: July 1, 2024
Energy
storage
is
one
of
the
hot
points
research
in
electrical
power
engineering
as
it
essential
systems.
It
can
improve
system
stability,
shorten
energy
generation
environmental
influence,
enhance
efficiency,
and
also
raise
renewable
source
penetrations.
This
paper
presents
a
comprehensive
review
most
popular
systems
including
systems,
electrochemical
mechanical
thermal
chemical
More
than
350
recognized
published
papers
are
handled
to
achieve
this
goal,
only
272
selected
introduced
work.
A
comparison
between
each
form
based
on
capacity,
lifetime,
capital
cost,
strength,
weakness,
use
presented
tabular
form.
Selected
studies
concerned
with
type
have
been
discussed
considering
challenges,
devices,
limitations,
contribution,
objective
study.
The
integration
hybrid
taking
into
account
types.
Hybrid
challenges
solutions
by
summarized
analyzed.
selection
criteria
for
support
decision-makers
selecting
appropriate
device
their
application.
For
enormous
scale
highly
energetic
applications,
such
bulk
energy,
auxiliary,
transmission
infrastructure
services,
pumped
hydro
compressed
air
currently
suitable.
Battery,
flywheel
storage,
super
capacitor,
superconducting
magnetic
technically
feasible
distribution
networks.
With
an
density
620
kWh/m3,
Li-ion
batteries
appear
be
capable
technologies
enhanced
implementation
built
environment.
Nonetheless,
lead-acid
continue
offer
finest
balance
price
performance
because
still
somewhat
costly.
applications
reviewed
last
section
general
utility
utilization,
buildings
communities,
transportation.
Finally,
recent
developments
some
associated
avenues
discussed.
Academics
engineers
interested
strategies
might
refer
review.
Coordination Chemistry Reviews,
Journal Year:
2024,
Volume and Issue:
512, P. 215876 - 215876
Published: April 26, 2024
The
utilization
of
metal–organic
frameworks
(MOFs)
in
energy
storage
applications
is
constrained
by
their
limited
electrical
conductivity
and
insufficient
chemical
robustness,
posing
various
challenges
limitations.
Nevertheless,
research
has
demonstrated
that
MOF
structures
with
exceptional
porosity
adaptable
architectures
yield
a
wide
range
composites,
presenting
promising
prospects
for
improving
electrochemical
performance
devices.
When
combined
other
advanced
materials,
MOFs
form
composite
overcoming
these
constraints
exhibiting
superior
conductivity,
activity,
stability
comparison
to
pure
MOFs.
This
article
comprehensively
overviews
the
designed
chemistry
MOF-composites
metal-ion
batteries
(MIBs)
capacitors
(MICs).
synthesis
properties
composites
involving
MOFs,
including
MOF-MXene,
MOF-carbon
nanomaterials
(CNM)/graphene/carbon,
MOF-transition
metal
oxide
(TMO),
MOF/polymers,
MOF-derived
layered
double
hydroxide
(LDH),
as
well
mitigation
strategies
have
been
discussed.
A
brief
overview
electrode
materials
MIBs,
lithium-ion
(LIBs),
sodium-ion
(SIBs),
potassium-ion
(KIBs)
presented.
recent
developments
MICs,
such
(LICs),
magnesium-ion
(MGICs),
zinc-ion
(ZICs),
(SICs),
(KICs)
also
included.
Furthermore,
assessed
using
metrics,
output
voltage,
capacity,
cycle
stability,
density
(ED),
power
(PD).
comprehensive
analysis
conducted
identify
potential
obstacles
possible
mitigations
explore
future
possibilities.
Overall,
comprehension
MOF-based
approaches
enhancing
futuristic
progression
MOF-composite
MIBs
MICs
elucidated.
Energy & Fuels,
Journal Year:
2024,
Volume and Issue:
38(12), P. 10542 - 10559
Published: June 7, 2024
Nitrogen-doped
carbon
materials
have
gained
significant
attention
for
energy
storage.
High-capacity
and
stable
electrode
are
crucial
supercapacitors.
Nitrogen
doping
within
structures
introduces
more
important
active
sites
electrochemical
reactions,
while
the
tunable
pore
structure
of
enhances
ion
transfer
during
processes.
emerged
as
an
excellent
choice
developing
electrodes
in
This
work
critically
examines
formation
nitrogen
framework,
to
provide
a
comprehensive
review
impact
on
physical-chemical
performance
materials.
Moreover,
it
summarizes
various
design
principles
preparation
methods
nitrogen-doped
specifically
tailored
supercapacitor
applications.
Lastly,
envisions
prospects
environmentally
friendly
high-performance
electrodes.
ACS Applied Energy Materials,
Journal Year:
2023,
Volume and Issue:
6(18), P. 9196 - 9206
Published: June 16, 2023
Moderated
thermal
transformation
of
metal–organic
frameworks
(MOFs)
empowers
the
synthesis
nanomaterials
with
precisely
controlled
porosities
and
morphologies,
leading
to
enhanced
performance
in
energy
storage
applications.
Herein,
we
prepared
MIL-88A-derived
Fe3C-integrated
EPCNFs
(EPCNFs
=
electrospun
porous
carbon
nanofibers)
mats
for
outside
growth
Fe-MOFs
using
a
moderated
temperature
calcination
technique.
The
applied
technique
endorsed
conversion
into
Fe2O3/NPC
(NPC
nanoporous
carbon)
without
any
destruction
morphology
nanorods.
integrated
Fe3C
reduces
intrinsic
resistance
synergizes
overall
resulting
negative
electrode
(Fe2O3/NPC@Fe3C/EPCNFs).
MOF-derived
materials
have
excellent
within
−1
0
window
potential
range.
optimized
Fe2O3/NPC-350@Fe3C/EPCNFs
exhibits
high
specific
capacitance
(531
F
g–1
at
1
A
g–1)
stable
cycling
performance,
retaining
more
than
90%
even
after
20000
cycles.
uniform,
vertical,
porous,
highly
interconnected
tetragonal
rod-like
can
also
maintain
structural
integrity
during
continuous
charge/discharge.
In
addition,
assembled
symmetric
supercapacitor
(Fe2O3/NPC-350@Fe3C/EPCNFs//Fe2O3/NPC-350@Fe3C/EPCNFs)
an
density
21.6
W
h
kg–1
power
499.05
superior
stability
(20000
cycles
20
g–1),
indicating
feasibility
practical
application
systems.
