Linker engineering regulating the electron transfer between Ni nanoparticles and RE-MOFs for enhanced DCPD hydrogenation performance DOI
Li Tian, Juan Chen, Dandan Jia

et al.

Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 43, P. 102521 - 102521

Published: Jan. 1, 2025

Language: Английский

In situ anchoring Cu nanoclusters on Cu-MOF: A new strategy for a combination of catalysis and fluorescence toward the detection of H2O2 and 2,4-DNP DOI
Huijun Li, Yingying Wu, Zhouqing Xu

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 479, P. 147508 - 147508

Published: Nov. 28, 2023

Language: Английский

Citations

79

Heteroatom‐Doped Ag25 Nanoclusters Encapsulated in Metal–Organic Frameworks for Photocatalytic Hydrogen Production DOI
He Wang, Xiyuan Zhang, Wei Zhang

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(17)

Published: Feb. 26, 2024

Atomically precise metal nanoclusters (NCs) with unique optical properties and abundant catalytic sites are promising in photocatalysis. However, their light-induced instability the difficulty of utilizing photogenerated carriers for photocatalysis pose significant challenges. Here, MAg

Language: Английский

Citations

54

Size and charge effects of metal nanoclusters on antibacterial mechanisms DOI Creative Commons

Hanny Tika Draviana,

Istikhori Fitriannisa,

Muhamad Khafid

et al.

Journal of Nanobiotechnology, Journal Year: 2023, Volume and Issue: 21(1)

Published: Nov. 15, 2023

Abstract Nanomaterials, specifically metal nanoclusters (NCs), are gaining attention as a promising class of antibacterial agents. Metal NCs exhibit properties due to their ultrasmall size, extensive surface area, and well-controlled ligands. The mechanisms influenced by two primary factors: size charge. In this review, we summarize the impacts charge on mechanisms, interactions with bacteria, factors that influence effects against both gram-negative gram-positive bacteria. Additionally, highlight occur when negatively or positively charged, provide examples applications A better understanding relationships between activity will aid in design synthesis nanomaterials for development effective agents bacterial infections. Based remarkable achievements NCs, review also presents conclusions current challenges future perspectives fundamental investigations practical applications. Graphical

Language: Английский

Citations

47

Enhanced biochemical sensing using metallic nanoclusters integrated with metal–organic frameworks (NCs@MOFs): a comprehensive review DOI
Sameera Sh. Mohammed Ameen, Khalid M. Omer,

Farzaneh Shalileh

et al.

Materials Horizons, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Significant advancements have been made in biochemical sensing, particularly the design, development, and utilization of metallic nanoclusters metal–organic frameworks as separate functional materials.

Language: Английский

Citations

3

Synthesis of a new complex of lanthanum on MCM-41 as an efficient and reusable heterogeneous catalyst for the chemoselective synthesis of sulfoxides and tetrahydrobenzo[b]pyrans DOI
Mohsen Nikoorazm, Bahman Tahmasbi,

Mitra Darabi

et al.

Journal of Porous Materials, Journal Year: 2023, Volume and Issue: 31(2), P. 511 - 526

Published: Nov. 6, 2023

Language: Английский

Citations

30

Towards bridging thermo/electrocatalytic CO oxidation: from nanoparticles to single atoms DOI
Kai Wei, Xian Wang,

Junjie Ge

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(17), P. 8903 - 8948

Published: Jan. 1, 2024

Proton exchange membrane fuel cells (PEMFCs), as a feasible alternative to replace the traditional fossil fuel-based energy converter, contribute significantly global sustainability agenda. At PEMFC anode, given high current density, Pt/C is deemed catalyst-of-choice ensure that hydrogen oxidation reaction (HOR) occurs at sufficiently fast pace. The performance of Pt/C, however, can only be achieved under premise purity used. For instance, in presence trace level carbon monoxide, typical contaminant during H

Language: Английский

Citations

13

Recent progress in atomically precise metal nanoclusters for photocatalytic application DOI

Yuanxin Du,

Chengqi Li,

Yali Dai

et al.

Nanoscale Horizons, Journal Year: 2024, Volume and Issue: 9(8), P. 1262 - 1278

Published: Jan. 1, 2024

This review summarizes the recent progress in atomically precise metal nanoclusters various photocatalytic applications and highlights strategy for constructing nanocluster-based heterostructures to improve stability catalytic activity.

Language: Английский

Citations

11

Phase and chemical state tuning of FeNi oxides for oxygen evolution reaction DOI
Jiawei Wu,

Zhouyang Ma,

Lice Yu

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: 67(8), P. 2755 - 2766

Published: June 24, 2024

Language: Английский

Citations

11

Regulating interaction with surface ligands on Au25 nanoclusters by multivariate metal–organic framework hosts for boosting catalysis DOI Creative Commons
He Wang, Xiaokang Liu,

Yulong Zhao

et al.

National Science Review, Journal Year: 2024, Volume and Issue: 11(10)

Published: July 23, 2024

ABSTRACT While atomically precise metal nanoclusters (NCs) with unique structures and reactivity are very promising in catalysis, the spatial resistance caused by surface ligands structural instability poses significant challenges. In this work, Au25(Cys)18 NCs encapsulated multivariate metal–organic frameworks (MOFs) to afford Au25@M-MOF-74 (M = Zn, Ni, Co, Mg). By MOF confinement, Au25 showcase highly enhanced activity stability intramolecular cascade reaction of 2-nitrobenzonitrile. Notably, interaction between nodes M-MOF-74 is able suppress free vibration on thereby improve accessibility Au sites; meanwhile, stronger interactions lead higher electron density core expansion within Au25(Cys)18. As a result, exhibits trend Au25@Ni-MOF-74 > Au25@Co-MOF-74 Au25@Zn-MOF-74 Au25@Mg-MOF-74, highlighting crucial roles microenvironment modulation around hosts.

Language: Английский

Citations

11

Recent progress on organic metal compound/MOF hybrids: From controllable synthesis to potential catalytic applications DOI
Yahya Absalan,

Mostafa Gholizadeh,

Eun‐Bi Kim

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 515, P. 215972 - 215972

Published: May 27, 2024

Language: Английский

Citations

10