Photofluorochromic Organic Supramolecular Compounds for Multiple Dynamic Anticounterfeiting DOI
Hua Yang,

Li Huang,

Yu-An Shen

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(23), P. 8350 - 8358

Published: Jan. 1, 2024

Photofluorochromic materials with highly efficient luminescence and color-changing behaviour displaying multiple dynamic anticounterfeiting secure information encryption.

Language: Английский

Aminobenzoic Acid Covalently Modified Polyoxotungstates Based on {XW6} Clusters with Proton Conductivity Property DOI
Yunfan Zhang,

Yizhen Song,

Lihua Liu

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 14, 2025

Three cases of aminobenzoic acid hybrid polyoxotungstates, Na3(H3O)2[(HPW6O21) (O2CC6H4NH2)3]·7H2O (1), K2(H3O)4[(AsW6O21)(O2CC6H4NH2)3]·4H2O (2), and [(H2N(CH3)2]3Na2(H3O)[(SbW6O21) (3), were successfully synthesized. This is the first report successful assembly hexanuclear {XW6} (X = HPIII, AsIII, or SbIII) clusters organic carboxylic (para acid) ligands. All three hybrids feature a common unit composed six-membered {WO6} octahedral ring capped by one {XO3} trigonal pyramid. Furthermore, these possess an extensive three-dimensional network hydrogen bonds, which not only provide high thermal stability but also contribute to excellent proton conductive performances. Simultaneously, based on Hirshfeld partition analysis, combined with interaction between POMs water molecules, transport mechanisms highlighted.

Language: Английский

Citations

2
Temperature‐Responsive Polyoxometalates‐Based Materials: From Underlying Mechanism to Promising Applications DOI
Yuanyu Wang, Zhihao Yu, Jian Xiong

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(40)

Published: July 7, 2024

Abstract Polyoxometalates (POMs) are multifunctional anionic metal‐oxygen complexes with structural and electronic diversity, as well tunable acid‐base redox properties, resulting in their potential building blocks for constructing temperature‐responsive polyoxometalates‐based materials (TRPMs). TRPMs represent a class of intelligent exhibiting property changes response to temperature fluctuations, offering distinctive applications various fields such catalysis, medicine, sensors, imaging, so on. Though many reported, systematic review including recent advances is still absent. This provides insights into advancements mechanisms, nanostructure design strategies, the characterization TRPMs. Special emphasis placed on enhancing properties by incorporating POMs suitable organic ligands, ionic liquid cations, deep eutectic solvent cationic surfactants, polymers. The incorporation ligands not only enables phase transitions but also enhances other catalyst selectivity drug loading capacity, expanding applications. Consequently, this summarizes delivery release, chemical sensing, discusses future technological challenges. in‐depth understanding may help from nanoscale, guiding inspiring development.

Language: Английский

Citations

8
Photochromic ionogel with a wide temperature range and fatigue resistance for high-resolution rewritable information record DOI
Jingyue Zhang,

Mengru Guo,

Yuanteng Su

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 495, P. 153263 - 153263

Published: June 18, 2024

Language: Английский

Citations

7
Two multifunctional Eu-MOFs with dual photochromic and luminous centers for multiple optical switches and anti-counterfeiting properties DOI
Xiaonan Li, Hui Han, Tingting Guo

et al.

Dyes and Pigments, Journal Year: 2024, Volume and Issue: 230, P. 112358 - 112358

Published: Nov. 1, 2024

Language: Английский

Citations

6
Polyoxometalate/s-triazine hybrid heterostructures with ultrafast photochromic properties DOI

Yue-Chen Chen,

Yi‐Ming Di,

Shuquan Zhang

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(7), P. 3215 - 3223

Published: Jan. 1, 2024

Benefitting from the strong anion–π interactions and matching energy levels between donors acceptors, four hybrid heterostructures protonated tri(4-pyridyl)- s -triazines POM anions exhibited ultrafast photochromic behaviours.

Language: Английский

Citations

5
Synthesis of bridged dinaphthoviologen derivatives for enhanced electrochromic performance and picric acid detection DOI

Chaoyu Bao,

Ni Yan,

Tianle Cao

et al.

Dyes and Pigments, Journal Year: 2024, Volume and Issue: 227, P. 112136 - 112136

Published: April 9, 2024

Language: Английский

Citations

5
Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate DOI Creative Commons
Natalia S. Soldatova, Amirbek D. Radzhabov, Daniil M. Ivanov

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(31), P. 12459 - 12472

Published: Jan. 1, 2024

The structure-directing "key-to-lock" interaction of double σ-(I

Language: Английский

Citations

4
Highly efficient NIR-II photothermal conversion from a 2,2′-biquinoline-4,4′-dicarboxylate-based photochromic complex DOI
Ning-Ning Zhang,

Ya-Tong Liu,

Li Li

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(15), P. 4867 - 4875

Published: Jan. 1, 2024

A novel electron-transfer photochromic complex based on BCA exhibits efficient NIR-II photothermal conversion with a high PCE (84.5%).

Language: Английский

Citations

4
Hybrid polysaccharide film infused with polyoxometalates for inkless printing and solar ultraviolet sensing DOI
Tanveer Hussain, Zaheer Ahmad, Onome Ejeromedoghene

et al.

International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: unknown, P. 139308 - 139308

Published: Jan. 1, 2025

Language: Английский

Citations

0
Transparent insulating photochromic PU/PTA films for Wide-Spectrum modulated smart windows DOI
Tuodong Xiong, Wanxiong Yong, Na Chen

et al.

Journal of Photochemistry and Photobiology A Chemistry, Journal Year: 2024, Volume and Issue: 456, P. 115853 - 115853

Published: June 22, 2024

Language: Английский

Citations

3