Photofunctionalized Europium(III) Complexes with Circularly Polarized Luminescence DOI Creative Commons
Md. Jahidul Islam, Nazmun Sharmin

Chemical Physics Impact, Journal Year: 2024, Volume and Issue: unknown, P. 100806 - 100806

Published: Dec. 1, 2024

Language: Английский

Endowing single-crystal polymers with circularly polarized luminescence DOI Creative Commons
Zhong‐Qiu Li, Meng Li,

Zili Chen

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: Jan. 2, 2025

The preparation of single-crystal polymers with circularly polarized luminesce (CPL) remains a challenging task in chemistry and materials science. Herein, we present the single-crystal-to-single-crystal topochemical photopolymerization chiral organic salt to achieve this goal. in-situ reaction 1,4-bis((E)-2-(pyridin-4-yl)vinyl)benzene (1) (+)- or (−)-camphorsulfonic acid (CSA) gives monomer crystal 1[( + )/( − )-CSA]2 showing yellow CPL high luminescent dissymmetry factor |glum| 0.035 emission quantum yield Φ 49.7%. Upon photo-induced [2 2] polymerization, polyionic poly-1[( are obtained. (SCSC) is revealed by situ powder X-ray diffraction, X-ray, optical microscopy, infrared, circular dichroism, spectroscopic analyzes. Interestingly, photopolymer crystals show blue handedness-inverted 0.011 (Φ = 14.2%), respect crystal. Furthermore, patterned circularly-polarized photonic heterojunctions alternate sub-blocks prepared mask-assisted method. Our findings provide vision for fabricating high-performance CPL-active crystalline polymer materials, paving way further development photo-response systems. Single-crystal luminescence interesting but prepare. Here, authors report photopolymerisation form luminescence.

Language: Английский

Citations

1
Perspectives and challenges in circularly polarized luminescence of lanthanide(III) complexes: From solution-based systems to solid-state applications DOI
Airton G. Bispo‐Jr,

Nagyla A. Oliveira,

Isabela M.S. Diogenis

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216279 - 216279

Published: Oct. 16, 2024

Language: Английский

Citations

7
Two chiral lanthanide PrIII and HoIII complexes: NIR luminescent and nonlinear optical properties DOI

Yanhong Peng,

Taoyu Wang,

Congli Gao

et al.

CrystEngComm, Journal Year: 2024, Volume and Issue: 26(28), P. 3867 - 3873

Published: Jan. 1, 2024

The first examples of NIR-emissive lanthanide complexes displaying simultaneous SHG and THG responses were discovered.

Language: Английский

Citations

5
The application of chiral groups in circularly polarized luminescent lanthanide complexes DOI

Yanxin Zha,

Zuqiang Bian,

Zhiwei Liu

et al.

Polyhedron, Journal Year: 2025, Volume and Issue: 272, P. 117452 - 117452

Published: Feb. 25, 2025

Language: Английский

Citations

0
Controlled Assembly of Chiral One-Dimensional Helical Coordination Polymers for Circularly Polarized Luminescence and Polydimethylsiloxane-Assisted Signal Inversion and Amplification DOI
Hongyu Dong,

Ziwen Song,

Liping Wang

et al.

ACS Materials Letters, Journal Year: 2025, Volume and Issue: unknown, P. 1786 - 1794

Published: April 9, 2025

Language: Английский

Citations

0
Magnetic circularly polarized luminescence from spin–flip transitions in a molecular ruby DOI Creative Commons
Alessio Gabbani, Maxime Poncet, Gennaro Pescitelli

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Magnetic circularly polarized luminescence (MCPL),

Language: Английский

Citations

3
Interplay of Circularly Polarized Light with Molecular and Structural Chirality: Chiral Lanthanide Complexes and Cellulose Nanocrystals DOI Creative Commons

Matteo Cei,

Alessandra Operamolla, Francesco Zinna

et al.

Advanced Optical Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 17, 2024

Abstract The interaction of circularly polarized (CP) light with chiral matter at different scales opens several possibilities manipulation in photonic and electronic devices. Here it is shown that a multilayer architecture, possible to take advantage the polarization‐selective reflection nematic arrangement cellulose nanocrystals strong intrinsic CP luminescence (CPL) various bands Eu complexes. In this way, both CPL total emission complex are modified depending on enantiomer applied detection geometry. This concept may apply for polarization control devices optical cavities.

Language: Английский

Citations

2
Dinuclear enantiopure Ln3+ complexes with (S-) and (R-) 2-phenylbutyrate ligands. Luminescence, CPL and magnetic properties DOI Creative Commons
Ànnia Tubau, Francesco Zinna, Lorenzo Di Bari

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(32), P. 13566 - 13582

Published: Jan. 1, 2024

The reaction of Ln(NO

Language: Английский

Citations

1
Fluorescent Dye‐Based Chiral Crystalline Organic Salt Networks for Circularly Polarized Luminescence DOI Open Access
Haitao Li, Shu‐Yu Zhang, Qi‐Long Zhu

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 24, 2024

Abstract A facile and general strategy is developed herein for the construction of circularly polarized luminescence (CPL) materials with simultaneously high fluorescence quantum efficiency (Φ) large dissymmetry factor (g lum ). The self‐assembly fluorescent dye, disodium 4,4′‐bis(2‐sulfonatostyryl)biphenyl (CBS), chiral diamines such as (R,R)/(S,S)‐1,2‐diaminocyclohexane (R/S‐DACH) R/S‐1,2‐diaminopropane (R/S‐DAP), produces four crystalline organic salt networks (COSNs). These as‐synthesized salts emit strong blue‐color CPL upon excitation, both Φ g values up to 79% 0.022. well‐defined molecular structures arrangements CBS are directly observed through single crystal X‐ray analysis, offering crucial information regarding origins high‐efficiency performance. chirality amine effectively transferred further amplified supramolecular structure by multiple hydrogen bonding π–π stacking interactions, giving rise factors; meanwhile, fixation ordered arrangement these interactions empower efficient suppression motions, facilitating fluorescence. This work can inspire assembly via charge‐assisted bonds between dyes inducers. It also offers important insight into structural

Language: Английский

Citations

1
Photofunctionalized Europium(III) Complexes with Circularly Polarized Luminescence DOI Creative Commons
Md. Jahidul Islam, Nazmun Sharmin

Chemical Physics Impact, Journal Year: 2024, Volume and Issue: unknown, P. 100806 - 100806

Published: Dec. 1, 2024

Language: Английский

Citations

1