Energy storage materials, Journal Year: 2024, Volume and Issue: unknown, P. 103996 - 103996
Published: Dec. 1, 2024
Language: Английский
Energy storage materials, Journal Year: 2024, Volume and Issue: unknown, P. 103996 - 103996
Published: Dec. 1, 2024
Language: Английский
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(45)
Published: Aug. 1, 2024
Abstract Prussian blue analogues (PBAs) have been widely studied in aqueous zinc‐ion batteries (AZIBs) due to the characteristics of large specific surface area, open aperture, and straightforward synthesis. In this work, vanadium‐based PBA nanocubes were firstly prepared using a mild situ conversion strategy at room temperature without protection noble gas. Benefiting from multiple‐redox active sites V 3+ /V 4+ , 5+ Fe 2+ /Fe cathode exhibited an excellent discharge capacity 200 mAh g −1 AZIBs, which is much higher than those other metal‐based PBAs nanocubes. To further improve long‐term cycling stability V‐PBA cathode, high concentration water‐in‐salt electrolyte (4.5 M ZnSO 4 +3 Zn(OTf) 2 ), water‐based eutectic (5.55 glucose+3 ) designed successfully inhibit dissolution vanadium deposition Zn onto zinc anode. More importantly, assembled AZIBs maintained 55 % their highest even after 10000 cycles 10 A with superior rate capability. This study provides new for preparation pure nanostructures direction enhancing PBA‐based current densities industrialization prospects.
Language: Английский
Citations
27Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 530, P. 216475 - 216475
Published: Feb. 5, 2025
Language: Английский
Citations
2Talanta, Journal Year: 2024, Volume and Issue: 281, P. 126918 - 126918
Published: Sept. 20, 2024
Language: Английский
Citations
12Small, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 2, 2025
Intrinsic low conductivity, poor structural stability, and narrow interlayer spacing limit the development of MnO
Language: Английский
Citations
1Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 684, P. 635 - 646
Published: Jan. 11, 2025
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161124 - 161124
Published: Feb. 1, 2025
Language: Английский
Citations
1Materials Science in Semiconductor Processing, Journal Year: 2025, Volume and Issue: 192, P. 109396 - 109396
Published: Feb. 19, 2025
Language: Английский
Citations
0Inorganics, Journal Year: 2025, Volume and Issue: 13(3), P. 85 - 85
Published: March 15, 2025
This study presents the synthesis, electrochemical characterization, and sensor application of Na3[Fe(CN)5(PZT)], a novel pentacyanidoferrate-based coordination compound incorporating 2-pyrazinylethanethiol (PZT) as ligand. Unlike conventional Prussian blue analogues, this system exhibits enhanced electrocatalytic properties due to its unique ligand framework, which contributes increased charge transfer efficiency stability. The complex was synthesized via controlled substitution reaction, followed by UV-Vis IR spectroscopy confirmation successful formation. Na3[Fe(CN)5(PZT)] were investigated using cyclic voltammetry (CV), differential pulse (DPV), square-wave (SWV), impedance (EIS). Notably, modified electrodes exhibited improved kinetics catalytic activity, making them promising candidates for sensing applications. Na3[Fe(CN)5(PZT)]-modified electrode demonstrated outstanding performance towards hydrazine oxidation, exhibiting low detection limit 7.38 × 10−6 M, wide linear response range from 5 64 µmol L−1, high sensitivity. proposed enables precise quantification with selectivity, positioning an effective mediator advanced platforms. These findings provide new insights into design next-generation analogue-based sensors superior analytical performance.
Language: Английский
Citations
0Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Language: Английский
Citations
0Materials Today Chemistry, Journal Year: 2024, Volume and Issue: 42, P. 102350 - 102350
Published: Oct. 13, 2024
Language: Английский
Citations
3