Theoretical Insights into the Vibrational Spectra and Chemical Bonding of Ln(III) Complexes with a Tripodal N4O3 Ligand Along the Lanthanide Series DOI
Francielle C. Machado, Mateus Quintano, Carlos V. Santos‐Jr

et al.

Physical Chemistry Chemical Physics, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This study provides new theoretical insights into the vibrational spectra of Ln( iii ) complexes, along lanthanide series by utilizing LModeAGen protocol and integrating cutting-edge topological ideas.

Language: Английский

Perspectives and challenges in circularly polarized luminescence of lanthanide(III) complexes: From solution-based systems to solid-state applications DOI
Airton G. Bispo‐Jr,

Nagyla A. Oliveira,

Isabela M.S. Diogenis

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216279 - 216279

Published: Oct. 16, 2024

Language: Английский

Citations

8
Intramolecular energy transfer and its influence on the overall quantum yields of Eu3+ and Tb3+ chelates with dimethyl(phenylsulfonyl)amidophosphate ligands DOI
Albano N. Carneiro Neto,

Justyna Nasalska,

Paula Gawryszewska

et al.

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Journal Year: 2024, Volume and Issue: 324, P. 124875 - 124875

Published: July 31, 2024

Language: Английский

Citations

6
Assessment of DFT Functionals for Structural Determination of Lanthanide(III) Complexes Using Ligand Field Splitting DOI Open Access
Lucca Blois, Renaldo T. Moura, Ricardo L. Longo

et al.

Journal of Computational Chemistry, Journal Year: 2025, Volume and Issue: 46(2)

Published: Jan. 13, 2025

ABSTRACT Lanthanide (Ln 3+ ) tetrakis complexes, C[Ln(L) 4 ], are important for applications due to their high quantum yields, solubility, and stability. Their luminescent properties depend on the structure, particularly coordination polyhedron, assessment of computational methods calculating structures is paramount. Usually, this uses RMSD distances in [Ln(L) ] − complex or {LnO 8 } polyhedron between crystallographic calculated structures. However, since ligand field (LF) splitting highly geometry‐dependent, experimental LF Stark levels (RMSD‐LF) offers a more accurate measure evaluating methods. energy eigenvalues were using simple overlap model (SOM), with geometries optimized by various density functionals. M06 M06‐L functionals, def2‐SVP/MWB52(Eu)/CPCM, demonstrate best balance accuracy low cost, making them suitable modeling C[Eu(L) complexes.

Language: Английский

Citations

0
Biological Activity and Imaging Potential of Tb3+-Activated Silico-Gallate Mesoporous Bioactive Glasses Analyzed via Photoluminescence Spectroscopy DOI

A. Maha Lakshmi,

Kusum Kumari,

P. Venkateswara Rao

et al.

Ceramics International, Journal Year: 2025, Volume and Issue: unknown

Published: March 1, 2025

Language: Английский

Citations

0
Europium- β diketonate based blended thin films with tunable emission: Formulation and assessment for optoelectronic devices DOI
N. Thejo Kalyani, Akhilesh Ugale, S.J. Dhoble

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142380 - 142380

Published: April 1, 2025

Language: Английский

Citations

0
Multifunctional lanthanide(III) single-molecule magnets displaying luminescence thermometry: Progress, challenges, and future directions DOI
Airton G. Bispo‐Jr

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 537, P. 216685 - 216685

Published: April 15, 2025

Language: Английский

Citations

0
Developing halloysite-based X-ray scintillating nanocomposite enables red to green tunable emission behavior in epoxy resin DOI

Jiaying Zhong,

Weihua Song, Yu Wang

et al.

Applied Clay Science, Journal Year: 2025, Volume and Issue: 267, P. 107726 - 107726

Published: Jan. 31, 2025

Language: Английский

Citations

0
Ionic Radius-Dependent Self-Assembly of Lanthanide Organic Polyhedra: Structural Diversities and Luminescent Properties DOI
Jing Su, Fan Yin,

Xiao‐Fang Duan

et al.

Inorganic Chemistry Frontiers, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This article presents the influence of lanthanide size and ligands conformational flexibility on assemblies their corresponding luminescent properties.

Language: Английский

Citations

0
Unraveling the Role of Ligand Structure in Modulating Chiral Europium Complex Luminescence DOI Creative Commons

Didarul Islam,

Md. Hafizul Islam

Chemical Physics Impact, Journal Year: 2025, Volume and Issue: unknown, P. 100859 - 100859

Published: March 1, 2025

Language: Английский

Citations

0
Bifunctional Lanthanide MOFs with Phosphorus Ligands: Selective Luminescent Detection of Borides and CO2 Conversion DOI
Lifeng Shi,

Mixiang Qi,

Lei Han

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 6, 2025

There is an increasing demand for the development of lanthanide metal-organic frameworks and derived multifunctional materials. The functional properties such compounds are influenced by arrangement various Lewis basic sites or structural configurations ligands. In this study, a series isostructural Ln-MOFs containing phosphine-dicarboxylate ligand, [Ln(HL)(L)(DMF)]·DMF (where H2L = 5-(diphenylphosphanyl)isophthalic acid, Ln Tb3+ (1), Eu3+ (2), Gd3+ (3), Ce3+ (4), Nd3+ (5)), was synthesized under solvothermal conditions characterized in detail. Among obtained compounds, Tb-MOF 1 demonstrated excellent luminescent with high quantum yield (90.45%) considerable lifetime (1266 μs). Furthermore, acts as unique sensor 4-formylphenylboronic acid 9-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]carbazole, exhibiting low detection limits 1.38 3.62 mM, respectively. Additionally, Nd-MOF 5 efficient catalyst coupling carbon dioxide to epoxy resulting conversion rates (up 96%). This study further extends growing family provides insights preparing materials through modification organic ligands specific groups.

Language: Английский

Citations

0