Metal Cluster-based Crystalline Materials for the Electrocatalytic Reduction of Carbon Dioxide DOI
Fanfei Meng, Man Dong, Jingting He

et al.

ACS Materials Letters, Journal Year: 2024, Volume and Issue: 7(1), P. 229 - 249

Published: Dec. 16, 2024

Given the increasingly severe global climate change and energy crisis, conversion of carbon dioxide (CO2) into very valuable chemicals has been proposed as an attractive solution. The electrocatalytic CO2 reduction reaction (eCO2RR) represents a remarkably efficient pathway for reducing under mild conditions. Metal cluster-based crystalline materials (MCMs) have garnered significant interest in area CO2RR because their elevated concentration active sites, tunable backbone structures, excellent stability. These enable precise control metal valence states charge transfer pathways, offering variety pathways CO2RR. Herein, we examine utilization MCMs eCO2RR recent years. We cover fundamental principles reduction, synthesis approaches these materials, connection between structural characteristics catalytic performance. Additionally, paper delves challenges opportunities presented by enhancing efficiency selectivity. aim to provide researchers with new perspective on field eCO2RR, thereby improving understanding relationship structure Ultimately, this work seeks advance technology contributing significantly sustainable production mitigation greenhouse gas emissions.

Language: Английский

MOF-Based Electrocatalysts: An Overview from the Perspective of Structural Design DOI

Nana Sun,

Syed Shoaib Ahmad Shah, Zhongyuan Lin

et al.

Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 18, 2025

The electrocatalytic technique, as an efficient energy storage and conversion technology, has attracted significant attention to address exhaustion environmental pollution. Usually, the activity selectivity of reactions are largely dominated by dynamic process occurring on electrocatalysts. Therefore, high-performance electrocatalysts, which can dominate pathway barrier reactions, great significance for advancement technique. Metal-organic frameworks (MOFs), emerging crystalline porous materials, present structural component advantages including well-defined structure, high surface area, large porosity, diverse components, easy tailorability, demonstrating fantastic potential precise fabrication In this Review, strategies in electrocatalysts based MOF-related materials specifically introduced from aspects catalytic site design microenvironment modulation around sites. Furthermore, representative progress achieved various applications employing MOF-based is systematically summarized, with special emphasis MOFs performance optimization. Finally, remaining challenges future perspectives further highlighted.

Language: Английский

Citations

3
A novel LA@Cu-MOF film with dual response to pH and humidity: Preparation, antibacterial activity, and fruit preservation DOI

Chuanlong Men,

Chenchen Wu, Lei Wang

et al.

Food Chemistry, Journal Year: 2025, Volume and Issue: 475, P. 143304 - 143304

Published: Feb. 8, 2025

Language: Английский

Citations

1
A Review on Single Site Catalysts for Electrochemical CO2 Reduction DOI
Fan Yang, Haoyu Han,

Hailong Duan

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

Abstract Single site catalysts (SSCs), characterized by high atomic utilization and well‐defined active sites, exhibit significant potential in the field of CO 2 electroreduction (CO RR). Typically, SSCs tend to a 2‐electron transfer reaction RR, there remain challenges achieving efficient conversion above 2‐electrons (methane (CH 4 ) multicarbon products(C 2+ ). Therefore, systematic review is crucial summarize recent advancements single electrocatalysts their structure‐activity relationship. The discussion begins with state‐of‐the‐art characterization techniques SSCs. Then influence central atoms, coordination environments, support metal‐support interactions on catalytic performance discussed detail. Subsequently, regulation strategies improve activity selectivity CH C products are discussed. Furthermore, dynamic evolution metal sites true nature during RR also addressed. Finally, associated for product formation analyzed.

Language: Английский

Citations

0
Achievements and Challenges in Carbon‐Free Dual‐Atom Catalysts for Electrocatalysis DOI
Luoluo Qi, Jingqi Guan

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 25, 2025

Abstract Carbon‐free dual‐atom catalysts (CFDACs) are beginning to make their presence in the field of electrocatalysis due unique properties and structures that different from those carbon‐based DACs, which endowed with activity, selectivity, stability. Currently, some advances made study CFDACs, including structure‐performance relationships metal‐support interaction, theoretical combined experiments, electrocatalytic applications potential catalytic mechanisms, design strategies achieve highly active performance. Herein, perception CFDACs is first elaborated terms carbon‐free substrates sites, then briefly summarizes advanced characterization techniques, study, energy storage conversion applications, highlights realize high‐performance vacancy anchoring, strain regulation, alloying, finally put forward personal viewpoints on current challenges future development CFDACs.

Language: Английский

Citations

0
Ligand-induced surface modification of cuprous oxide improves C2+ product selectivity in electrochemical CO2 reduction DOI

Vishesh Kumar,

Yining Li, Abhishek Dutta Chowdhury

et al.

Materials Today Chemistry, Journal Year: 2024, Volume and Issue: 41, P. 102319 - 102319

Published: Sept. 23, 2024

Language: Английский

Citations

2
Enhancement of electrocatalytic CO2 performance by different components of Cu-based bimetallic MOFs DOI

Jvwei Liu,

Qiang Zhang, Jianlin Wang

et al.

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Cu-based catalysts have been promising materials for electrocatalytic reduction of carbon dioxide into C 2+ products.

Language: Английский

Citations

0
Metal Cluster-based Crystalline Materials for the Electrocatalytic Reduction of Carbon Dioxide DOI
Fanfei Meng, Man Dong, Jingting He

et al.

ACS Materials Letters, Journal Year: 2024, Volume and Issue: 7(1), P. 229 - 249

Published: Dec. 16, 2024

Given the increasingly severe global climate change and energy crisis, conversion of carbon dioxide (CO2) into very valuable chemicals has been proposed as an attractive solution. The electrocatalytic CO2 reduction reaction (eCO2RR) represents a remarkably efficient pathway for reducing under mild conditions. Metal cluster-based crystalline materials (MCMs) have garnered significant interest in area CO2RR because their elevated concentration active sites, tunable backbone structures, excellent stability. These enable precise control metal valence states charge transfer pathways, offering variety pathways CO2RR. Herein, we examine utilization MCMs eCO2RR recent years. We cover fundamental principles reduction, synthesis approaches these materials, connection between structural characteristics catalytic performance. Additionally, paper delves challenges opportunities presented by enhancing efficiency selectivity. aim to provide researchers with new perspective on field eCO2RR, thereby improving understanding relationship structure Ultimately, this work seeks advance technology contributing significantly sustainable production mitigation greenhouse gas emissions.

Language: Английский

Citations

0