The
structural
modification
of
metal-organic
frameworks
(MOFs)
is
vital
importance
in
many
fields,
especially
sensing
with
enhanced
performance,
while
the
efficient
synthesis
functionalized
MOF
nanoparticles
toward
small
molecule
detection
remains
challenging.
Here,
a
general
cellulose
nanofibril
(CNF)-induced
situ
one-step
strategy
was
proposed
for
dual-ligand-functionalized
europium-based
(EuMOF@CNF)
under
an
effective
regulation
crystallization
kinetics
hydrothermal
synthesis.
Based
on
unique
dual-ligand
structure,
obtained
EuMOF
featured
tunable
antenna
effect
and
laid
good
foundation
fluorescence-sensing
materials.
Benefiting
from
superior
self-assembly
properties
CNFs
EuMOF@CNF,
flexible
films
were
constructed,
showing
excellent
mechanical
(72
MPa
stress
3.8%
strain)
luminescence
achieving
instant
(1
s)
sensitive
fluorescence
sarin
analogue
vapor
significantly
low
limit
(LOD,
2.8
ppb)
robust
selectivity
against
wide
range
common
interferents
(>14
types),
independent
acids.
We
believe
that
this
pioneering
design
effects
would
positively
advance
development
high-performance
MOF-based
fluorescent
materials
devices.
The Chemical Record,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 1, 2025
Abstract
Metal‐Organic
Frameworks
(MOFs)
have
emerged
as
versatile
materials
bridging
inorganic
and
organic
chemistry
to
address
critical
environmental
challenges.
Composed
of
metal
nodes
linkers,
these
crystalline
structures
offer
unique
properties
such
high
surface
area,
tunable
pore
sizes,
structural
diversity.
Recent
advancements
in
MOFs
synthesis,
particularly
innovative
approaches
like
mechanochemical,
microwave‐assisted,
ultrasonic
significantly
enhanced
sustainability
by
utilizing
non‐toxic
solvents,
renewable
feedstocks,
energy‐efficient
processes,
offering
promising
solutions
reduce
impact.
This
review
highlights
novel
methods
their
contributions
improving
functionality
for
applications
remediation,
gas
capture,
energy
storage.
We
examine
the
potential
catalysis
pollutant
degradation,
water
purification,
hazardous
waste
removal,
well
role
next‐generation
storage
technologies,
supercapacitors,
batteries,
hydrogen
production.
Furthermore,
we
challenges
including
scalability,
stability,
long‐term
performance,
underscoring
need
continued
innovation
synthesis
techniques
enable
large‐scale
applications.
Overall,
hold
transformative
multifunctional
materials,
are
successful
integration
into
practical
solutions.
Journal of Materials Chemistry C,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
DOCK5
acts
at
focal
adhesions
in
breast
cells
to
establish
positive
feedback
loops
via
CDC42
and
RAC.
The
stabilisation
of
polarity
during
migration
promotes
persistent
YAP/TAZ
activation
which
we
propose
drives
cancer
phenotypes.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 16, 2025
Abstract
Metal‐organic
frameworks
(MOFs)
have
gained
prominence
through
reticular
chemistry,
connecting
building
blocks
to
create
specific
structures.
MOFs
offer
high
surface
areas,
porosity,
stability,
and
diverse
functionalities.
This
makes
them
easily
modifiable
for
various
applications,
evolving
into
complex
architectures.
Recent
advancements
in
MOF‐derived
multi‐shelled
nanostructures
are
summarized
herein.
The
advantages
disadvantages
of
these
over
bare
single‐shelled
structures
discussed.
recent
progress
potential
energy
storage
applications
comprehensively
explored.
Challenges
prospects
this
area
also
outlined.
The
structural
modification
of
metal-organic
frameworks
(MOFs)
is
vital
importance
in
many
fields,
especially
sensing
with
enhanced
performance,
while
the
efficient
synthesis
functionalized
MOF
nanoparticles
toward
small
molecule
detection
remains
challenging.
Here,
a
general
cellulose
nanofibril
(CNF)-induced
situ
one-step
strategy
was
proposed
for
dual-ligand-functionalized
europium-based
(EuMOF@CNF)
under
an
effective
regulation
crystallization
kinetics
hydrothermal
synthesis.
Based
on
unique
dual-ligand
structure,
obtained
EuMOF
featured
tunable
antenna
effect
and
laid
good
foundation
fluorescence-sensing
materials.
Benefiting
from
superior
self-assembly
properties
CNFs
EuMOF@CNF,
flexible
films
were
constructed,
showing
excellent
mechanical
(72
MPa
stress
3.8%
strain)
luminescence
achieving
instant
(1
s)
sensitive
fluorescence
sarin
analogue
vapor
significantly
low
limit
(LOD,
2.8
ppb)
robust
selectivity
against
wide
range
common
interferents
(>14
types),
independent
acids.
We
believe
that
this
pioneering
design
effects
would
positively
advance
development
high-performance
MOF-based
fluorescent
materials
devices.
