Electrochemical generation of unconventional cyanide vacancies to boost the catalytic performance of Co-Prussian Blue on oxygen evolution reaction under mild conditions DOI
Rafael L. Germscheidt,

Ana Araújo,

João Carlos O. Souza

et al.

Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 146327 - 146327

Published: April 1, 2025

Language: Английский

Electronic Feature Modification of Ni and Co Free Metal–Organic Framework Nanoparticles by Vanadium Introduction for Water Oxidation DOI
Baghendra Singh, Neetu Verma,

Pragya Arora

et al.

ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 24, 2024

Language: Английский

Citations

4

Automated nanoarchitectonics for networks filling by Prussian blue single crystals through an intermittentto-flow conversion DOI

Zixuan Wan,

Wei Zhang,

Tianzi Li

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: 505, P. 159525 - 159525

Published: Jan. 11, 2025

Language: Английский

Citations

0

High-performance aqueous copper-ion batteries based on iron hexacyanoferrate cathodes for enhanced energy storage DOI

Jinshu Zhang,

Liang Liu,

Yuao Wang

et al.

Nanoscale, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The intercalation/deintercalation mechanism of copper ions in iron hexacyanoferrate (FeHCF) was explored, and an aqueous battery with a voltage range 1.6–2.5 V prepared. These findings highlight the potential FeHCF-based batteries.

Language: Английский

Citations

0

Novel MIL- 101(Fe)@ZIF- 67 catalyst: boosting OER efficiency in water electrolysis DOI
Wenjing Zhang,

Yuxi Liu,

Weimeng Chi

et al.

Ionics, Journal Year: 2025, Volume and Issue: unknown

Published: April 15, 2025

Language: Английский

Citations

0

Influence of metal–organic framework structure on the electrocatalytic activity of nickel phosphide nanoparticles synthesized from solvothermal phosphidization DOI
Chao Wang,

Yichuang Xing

Ionics, Journal Year: 2025, Volume and Issue: unknown

Published: April 30, 2025

Language: Английский

Citations

0

‘Everything’ in Aqueous Zinc-ion Batteries can may be Prussian blue analogues: From cathode materials to electrolyte additives applications DOI
Lulu Zhao,

Yi-Han Zhao,

Yongfu Wu

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104299 - 104299

Published: May 1, 2025

Language: Английский

Citations

0

3d–2p–5d Orbital Synergy in Electrocatalytic Hydrazine Oxidation Assisted Water Splitting with Industrial Scale Current Density DOI

Pragya Arora,

Kiran Bhadauriya,

Labham Singh

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 2, 2025

The hydrazine oxidation reaction (HzOR) is a promising alternative to the oxygen evolution (OER) in electrolyzers due its lower potential than water, which significantly reduces energy demands and enhances hydrogen production efficiency. Incorporating high-valent 5d metals into 3d metal hydroxides has shown great for enhancing water-splitting performance through strong 3d–2p–5d orbital interactions, improving charge transfer, intermediate adsorption, reducing overpotentials. This study showcases an innovative approach enhance electrocatalytic of Co(OH)2 incorporation metal, tungsten (W6+), using straightforward electrochemical synthesis method. W6+ led significant Co3d–O2p–W5d coupling, strengthening electronic interactions between Co W. facilitated electron withdrawal from Co2+, promoting easier access Co3+ sites catalytic performance. W-Co(OH)2 achieved current density 100 mA cm–2 at 1.00 V versus RHE HzOR, notably 1.54 required OER. In two-electrode system, substituting OER with HzOR resulted reduction cell voltage by 0.50 V.

Language: Английский

Citations

0

MOF Derived Phosphide Nanocubes with Internal Heterojunction: A Study Powered by Single Entity Electrochemistry DOI
Zilong Chen, Hengyue Xu, Tingting Chen

et al.

Nano Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 17, 2025

Metal–organic frameworks (MOFs) and their derivatives have captivated immense interest due to tunable chemical composition structures. Our research introduces an elegant strategy for advancing hybrid MOF-based electrocatalysts, employing scanning electrochemical cell microscopy (SECCM) single-entity electrochemistry probing of individual particles with precisely engineered compositions We achieved controlled phosphidation Prussian blue analogues, forming hollow nanocubes Fe-doped CoP/Co2P heterojunctions, which demonstrated significantly enhanced hydrogen evolution reaction (HER) activity, emphasizing the pivotal role structural compositional tuning in transition metal phosphide catalysts. Utilizing SECCM, we probed intrinsic HER activity nanocubes, correlating behavior size composition. Computational insights revealed that heterojunctions electronic conductivity spin density, established internal electric fields, minimized Gibbs free energy barrier. This study paves way toward advanced nanostructured underscoring crucial interplay between size, structure, composition, catalytic efficacy.

Language: Английский

Citations

0

Thermally activated prussian blue analogues low-spin iron for enhanced sodium ion storage performance DOI
Wenwu Fu, Gang Wang, Kai Zhang

et al.

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 641, P. 236866 - 236866

Published: March 27, 2025

Language: Английский

Citations

0

Preparation of Nanographene-Based Copolymer Nanocomposites: Thermal Decomposition Kinetic, Optical, and Electrical Behaviors DOI Creative Commons
Esra Barım, Kadir Demirelli

Arabian Journal for Science and Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: April 18, 2025

Language: Английский

Citations

0