Linker Engineering of High-Nuclearity {V12@P8W48}-Based Metal–Organic Frameworks for Green-Light-Driven Oxidative Coupling of Amines DOI
Yang Zeng,

Qixin Zhao,

Zhiqiang Jiang

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 9, 2025

The development of long-wavelength visible-light-responsive and reusable photocatalysts for organic transformation is significant interest. Herein, we report the design synthesis high-nuclearity {V12@P8W48}-based metal-organic frameworks, POMOF1 POMOF2, as heterogeneous light-triggered oxidation. Linker engineering, by tuning from visible-light-inactive triazole (L1) to a photosensitive anthraquinone-derived ligand (L2), not only leads generation porous 1D open channels within POMOF2 but also imparts strong peak absorption centered at 500 nm. Moreover, integration {V12@P8W48} Cu2+ ions together with L2 into enables continued broad ranging ultraviolet near-infrared region. Consequently, exhibited excellent activity in green-light-driven oxidative coupling benzylamines, affording series imines high conversions up 99% under mild conditions. In contrast, could barely promote reaction same conditions, further confirming advantage linker modulation. stable can be reused three cycles little loss catalytic structural integrity. This work highlights potential engineering an efficient approach designing photocatalysts, which push forward photoredox catalysis.

Language: Английский

Enhanced photocatalytic properties of H2 production and tetracycline removal with a H5PMo10V2O40/ZnIn2S4 S-scheme heterojunction DOI
Xiang Zhou, Hongfei Shi,

Ao Rong

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162844 - 162844

Published: March 1, 2025

Language: Английский

Citations

2
Ni-substituted POM@UIO-66 catalyst for high-efficiency catalytic conversion of larch lignin DOI
Haoyu Deng, Yuting Liu, Xiangyu Li

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132688 - 132688

Published: March 1, 2025

Language: Английский

Citations

0
Linker engineering of ternary donor–acceptor photosensitizers in chem-stable metal–organic frameworks for efficient photo-catalytic aerobic oxidation DOI

Mingxue Shao,

Huadong Guo,

Runjie Bao

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 163233 - 163233

Published: April 1, 2025

Language: Английский

Citations

0
Linker Engineering of High-Nuclearity {V12@P8W48}-Based Metal–Organic Frameworks for Green-Light-Driven Oxidative Coupling of Amines DOI
Yang Zeng,

Qixin Zhao,

Zhiqiang Jiang

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 9, 2025

The development of long-wavelength visible-light-responsive and reusable photocatalysts for organic transformation is significant interest. Herein, we report the design synthesis high-nuclearity {V12@P8W48}-based metal-organic frameworks, POMOF1 POMOF2, as heterogeneous light-triggered oxidation. Linker engineering, by tuning from visible-light-inactive triazole (L1) to a photosensitive anthraquinone-derived ligand (L2), not only leads generation porous 1D open channels within POMOF2 but also imparts strong peak absorption centered at 500 nm. Moreover, integration {V12@P8W48} Cu2+ ions together with L2 into enables continued broad ranging ultraviolet near-infrared region. Consequently, exhibited excellent activity in green-light-driven oxidative coupling benzylamines, affording series imines high conversions up 99% under mild conditions. In contrast, could barely promote reaction same conditions, further confirming advantage linker modulation. stable can be reused three cycles little loss catalytic structural integrity. This work highlights potential engineering an efficient approach designing photocatalysts, which push forward photoredox catalysis.

Language: Английский

Citations

0