CO2 capture over steam and KOH activated biochar: Effect of relative humidity DOI Creative Commons
Chen Zhang, Shuzhuang Sun, Shaojun Xu

et al.

Biomass and Bioenergy, Journal Year: 2022, Volume and Issue: 166, P. 106608 - 106608

Published: Sept. 25, 2022

Carbon dioxide (CO2) capture is critical for emission reduction. Biochar a promising adsorbent CO2 capture. In this work, the effect of relative humidity and biochar activation with steam or KOH treatment on was investigated. The results demonstrate that sample activated by has high capacity (50.73 mg g−1). addition, after 1.0 h showed carbon 38.84 g−1. also show ability decreased as concentration from 100% to 15%. had negative impact over biochar. capability materials treated range 31.38%–62.89% rose 8.8% 87.9%. Furthermore, lifetime samples at various shows increased adsorption due water molecules occupying active sites.

Language: Английский

The development of carbon capture and storage (CCS) in India: A critical review DOI Creative Commons
Rohit Shaw, Soumyajit Mukherjee

Carbon Capture Science & Technology, Journal Year: 2022, Volume and Issue: 2, P. 100036 - 100036

Published: Feb. 16, 2022

Carbon capture and sequestration (CCS) is a three-tier process- carbon capture, transport storage. The consists of pre-combustion, oxy-combustion post-combustion capture. Transport CO2 most viable through pipelines. biotic CO2storage occurs terrestrial or oceanic pathways can be simulated naturally artificially. abiotic/geologic storage achieved sequestering in depleting/depleted hydrocarbon reserves, deep saline aquifers mineral carbonation. At the district level, 64 out 641 districts (2013 government reports) accounted for ∼ 60% total emissions. Controlling emissions comes with challenge sustainable socio-economic growth country- demanding task economy. Indian organizations have made international collaborations. India holds substantial geological potential its basaltic rocks, coal seams, depleted oil soils, sedimentary basins. this point, no / clean development mechanism projects are operational country. next 10-15 years would very crucial to attain technological advancement deploy large-scale CCS projects.

Language: Английский

Citations

95

Combining Machine Learning and Molecular Simulations to Unlock Gas Separation Potentials of MOF Membranes and MOF/Polymer MMMs DOI Creative Commons
Hilal Daglar, Seda Keskın

ACS Applied Materials & Interfaces, Journal Year: 2022, Volume and Issue: 14(28), P. 32134 - 32148

Published: July 12, 2022

Due to the enormous increase in number of metal-organic frameworks (MOFs), combining molecular simulations with machine learning (ML) would be a very useful approach for accurate and rapid assessment separation performances thousands materials. In this work, we combined these two powerful approaches, ML, evaluate MOF membranes MOF/polymer mixed matrix (MMMs) six different gas separations: He/H2, He/N2, He/CH4, H2/N2, H2/CH4, N2/CH4. Single-component uptakes diffusivities were computed by grand canonical Monte Carlo (GCMC) dynamics (MD) simulations, respectively, simulation results used assess permeabilities selectivities membranes. Physical, chemical, energetic features MOFs as descriptors, eight ML models developed predict adsorption diffusion properties MOFs. Gas membrane 5249 31,494 MMMs predicted using models. To examine transferability models, also focused on computer-generated, hypothetical (hMOFs) permeability selectivity 1000 hMOF/polymer MMMs. The that accurately uptake He, H2, N2, CH4 gases will significantly accelerate These direct extensive experimental efforts computationally demanding fabrication analysis materials offering high performance target separation.

Language: Английский

Citations

82

Advances in Carbon Capture and Use (CCU) Technologies: A Comprehensive Review and CO2 Mitigation Potential Analysis DOI Creative Commons
Christiano Bruneli Peres, Pedro R. Resende, Leonel J. R. Nunes

et al.

Clean Technologies, Journal Year: 2022, Volume and Issue: 4(4), P. 1193 - 1207

Published: Nov. 17, 2022

One of society’s major current challenges is carbon dioxide emissions and their consequences. In this context, new technologies for (CO2) capture have attracted much attention. these utilization (CCU). This work focuses on the latest trends in a holistic approach to utilization. Absorption, adsorption, membranes, chemical looping are considered CO2 capture. Each technology described, its benefits drawbacks discussed. For use dioxide, various possible applications CCU starting with agriculture proceeding conversion into fuels (catalytic processes), chemicals (photocatalytic polymers, building supplies. decades, has been used industrial processes, such as CO2-enhanced oil recovery, food industry, organic compound production (such urea), water treatment, and, therefore, flame retardants coolants. There also several CO2-utilization at stages development exploitation, electrochemical fuels, supercritical CO2. At end review, future opportunities discussed regarding machine learning (ML) life cycle assessment (LCA).

Language: Английский

Citations

71

Membranes for CO2 capture and separation: Progress in research and development for industrial applications DOI
Zhongde Dai, Liyuan Deng

Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 335, P. 126022 - 126022

Published: Dec. 14, 2023

Language: Английский

Citations

68

The Application of Biochar for CO2 Capture: Influence of Biochar Preparation and CO2 Capture Reactors DOI Creative Commons
Chen Zhang,

Ying Ji,

Chunchun Li

et al.

Industrial & Engineering Chemistry Research, Journal Year: 2023, Volume and Issue: 62(42), P. 17168 - 17181

Published: June 29, 2023

This work investigates three types of biochar (bamboo charcoal, wood pellet, and coconut shell) for postcombustion carbon capture. Each is structurally modified through physical (H2O, CO2) chemical (ZnCl2, KOH, H3PO4) activation to improve capture performance. Three methods (CO2 adsorption isotherms, CO2 fixed-bed adsorption, thermogravimetric analysis) are used determine the capacity. The results show that a more than 2.35 mmol·g–1 (1 bar, 298 K) capacity was achieved using activated samples. It also demonstrated performance by depends on multiple surface textural properties. A high area pore volume resulted in an enhanced Furthermore, O*/C ratio width negative correlation with biochars.

Language: Английский

Citations

44

Post-synthetic modifications (PSM)-induced defects in hybrid metal-organic frameworks (MOFs) to unleash potential in gas separation membrane applications DOI
Gyeong Min Choi, Manas Kumar Mandal,

Ho Jin Jung

et al.

Journal of Material Science and Technology, Journal Year: 2024, Volume and Issue: 201, P. 95 - 118

Published: April 4, 2024

Language: Английский

Citations

18

Enhancing CO2 sequestration efficiency: A comprehensive study of nanostructured MOF-composite membrane for sustainable climate solution DOI Creative Commons
Putu Doddy Sutrisna, Sibudjing Kawi, K. Khoiruddin

et al.

Carbon Capture Science & Technology, Journal Year: 2025, Volume and Issue: unknown, P. 100366 - 100366

Published: Jan. 1, 2025

Language: Английский

Citations

2

Ultrasonically synthesized MOFs for modification of polymeric membranes: A critical review DOI Creative Commons
Amirhossein Taghipour, Ahmad Rahimpour, Masoud Rastgar

et al.

Ultrasonics Sonochemistry, Journal Year: 2022, Volume and Issue: 90, P. 106202 - 106202

Published: Oct. 14, 2022

Metal-organic framework (MOF) membranes hold the promise for energy-efficient separation processes. These nanocrystalline compounds can effectively separate materials with different sizes and shapes at a molecular level. Furthermore, MOFs are excellent candidates improving membrane permeability and/or selectivity due to their unique properties, such as high specific area special wettability. Generally, be used fillers in mixed matrix (MMMs) or incorporated onto surface modify top layer. Characteristics of MOFs, correspondingly, properties MOF-based membranes, majorly affected by production technique. This critical review discusses sonication technique MOF opportunities challenges using making membranes. Effective parameters on characteristics synthesized time power, were discussed detail. Although ultrasonically have shown great potential fabrication/modification gas liquid separation/purification, so far, no comprehensive has been published clarify accomplishments technological gaps future research direction. paper aims most recent conducted modification polymeric Recommendations provided intent identifying works explore influential parameters.

Language: Английский

Citations

47

A review of catalytically enhanced CO2-rich amine solutions regeneration DOI
Muhammad Waseem, Mohamed Al-Marzouqi, Nayef Ghasem

et al.

Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(4), P. 110188 - 110188

Published: May 23, 2023

Language: Английский

Citations

38

Membrane-Based Technologies for Post-Combustion CO2 Capture from Flue Gases: Recent Progress in Commonly Employed Membrane Materials DOI Creative Commons
Petros Gkotsis, E.N. Peleka, Anastasios Zouboulis

et al.

Membranes, Journal Year: 2023, Volume and Issue: 13(12), P. 898 - 898

Published: Dec. 2, 2023

Carbon dioxide (CO2), which results from fossil fuel combustion and industrial processes, accounts for a substantial part of the total anthropogenic greenhouse gases (GHGs). As result, several carbon capture, utilization storage (CCUS) technologies have been developed during last decade. Chemical absorption, adsorption, cryogenic separation membrane are most widely used post-combustion CO2 capture technologies. This study reviews latest progress in processes separation. More specifically, objective present work is to state art membrane-based flue focuses mainly on recent advancements commonly employed materials. These materials utilized fabrication application novel composite membranes or mixed-matrix (MMMs), improved intrinsic surface characteristics and, thus, can achieve high selectivity permeability. Recent described regarding metal–organic frameworks (MOFs), molecular sieves (CMSs), nanocomposite membranes, ionic liquid (IL)-based facilitated transport (FTMs), comprise MMMs. The significant challenges future prospects implementing also presented.

Language: Английский

Citations

33