One step upcycling CO2 from flue gas into CO using natural stone in an integrated CO2 capture and utilisation system DOI Creative Commons
Shuzhuang Sun, Yuanyuan Wang, Xiaotong Zhao

et al.

Carbon Capture Science & Technology, Journal Year: 2022, Volume and Issue: 5, P. 100078 - 100078

Published: Nov. 6, 2022

Natural marble was successfully applied in integrated CO2 capture and utilisation for selectively producing valuable CO. The cheap easy-accessible dust is proven to have a high capacity of (9.4 mmol g−1) be active converting the captured into CO (> 85% conversion at 650 °C) with almost 100% selectivity. Furthermore, stone material exhibits impressive cycle stability (0.036 g−1 decrease per cycle). This report demonstrates that carbon emission control can realised over straightforward process using robust materials, representing an attractive technology cost-effective low-carbon development.

Language: Английский

Graphene Oxide‐Arginine Composites: Efficient Dual Function Materials for Integrated CO2 Capture and Conversion DOI Creative Commons
Sebastiano Mantovani,

Angela Pintus,

Alessandro Kovtun

et al.

ChemSusChem, Journal Year: 2024, Volume and Issue: 17(5)

Published: Jan. 16, 2024

Abstract The “on‐demand” capture and utilization of CO 2 is effectively realized with a readily accessible dual function organic composite. covalent controlled derivatization graphene oxide (GO) surface naturally occurring arginine led to “smart” material capable capturing (chemisorption) from high‐purity flue‐gas as well low‐concentration streams ( i. e . direct air capture) concomitant chemical activation toward the incorporation into cyclic carbonates. overall integrated conversion (ICCC) strategy has been fully elucidated mechanistically via dedicated computational, spectroscopic thermal analyses.

Language: Английский

Citations

9
Mid-temperature CO2 Adsorption over Different Alkaline Sorbents Dispersed over Mesoporous Al2O3 DOI Creative Commons
Anastasios I. Tsiotsias, Amvrosios G. Georgiadis, Nikolaos D. Charisiou

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: 9(10), P. 11305 - 11320

Published: Feb. 28, 2024

CO2 adsorbents comprising various alkaline sorption active phases supported on mesoporous Al2O3 were prepared. The materials tested regarding their adsorption behavior in the mid-temperature range, i.e., around 300 °C, as well characterized via XRD, N2 physisorption, CO2-TPD and TEM. It was found that Na2O phase (originated following NaNO3 impregnation) led to highest capacity due presence of CO2-philic interfacial Al–O––Na+ sites, optimum load shown be 12 wt % (0.22 Na/Al molar ratio). Additional prepared by dispersing over different metal oxide supports (ZrO2, TiO2, CeO2 SiO2), showing an inferior performance than Na2O/Al2O3. kinetics thermodynamics also investigated at temperatures, best-performing Na2O/Al2O3 material is exothermic follows Avrami model, while tests under varying partial pressures revealed Langmuir isotherm best fits data. Lastly, multiple adsorption–desorption cycles 500 respectively. maintain its with no detrimental effects nanostructure, porosity surface basic thereby rendering it suitable a reversible chemisorbent or support for preparation dual-function materials.

Language: Английский

Citations

9
Cutting-edge innovations in bio-alcohol reforming: Pioneering pathways to high-purity hydrogen: A review DOI

Wei Man Liew,

N. Ainirazali

Energy Conversion and Management, Journal Year: 2025, Volume and Issue: 326, P. 119463 - 119463

Published: Jan. 6, 2025

Language: Английский

Citations

1
Integrated direct air CO2 capture and utilization via in-situ catalytic conversion to fuels and chemicals using dual functional materials: Recent progresses and perspectives DOI
Yiran Zhang, Jiaqi Feng,

Linjia Li

et al.

Frontiers in Energy, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 10, 2025

Language: Английский

Citations

1
One step upcycling CO2 from flue gas into CO using natural stone in an integrated CO2 capture and utilisation system DOI Creative Commons
Shuzhuang Sun, Yuanyuan Wang, Xiaotong Zhao

et al.

Carbon Capture Science & Technology, Journal Year: 2022, Volume and Issue: 5, P. 100078 - 100078

Published: Nov. 6, 2022

Natural marble was successfully applied in integrated CO2 capture and utilisation for selectively producing valuable CO. The cheap easy-accessible dust is proven to have a high capacity of (9.4 mmol g−1) be active converting the captured into CO (> 85% conversion at 650 °C) with almost 100% selectivity. Furthermore, stone material exhibits impressive cycle stability (0.036 g−1 decrease per cycle). This report demonstrates that carbon emission control can realised over straightforward process using robust materials, representing an attractive technology cost-effective low-carbon development.

Language: Английский

Citations

36