Metal–Organic Frameworks for the Removal of Emerging Organic Contaminants in Water

Chemical Reviews, Journal Year: 2020, Volume and Issue: 120(16), P. 8378 - 8415

Published: Feb. 5, 2020

Water is essential in all aspects of life, being the defining characteristic our planet and even body. Regrettably, water pollution increasingly becoming a challenge due to novel anthropogenic pollutants. Of particular concern are emerging organic contaminants (EOCs), term used not only cover newly developed compounds but also discovered as environment. Aside from contamination, higher temperature more extreme less predictable weather conditions projected affect availability distribution. Therefore, wastewater treatment has become valuable resource its reuse an important issue that must be carried out efficiently. Among technologies considered remediation processes, metal–organic frameworks (MOFs) regarded promising materials for elimination EOCs since they present many properties commend them treatment: large surface area, easy functionalizable cavities, some stable water, synthesized at scale, etc. This review highlights advances use MOFs (adsorption and/or degradation) classifying by nature contaminant.

Language: Английский

---

Power of Infrared and Raman Spectroscopies to Characterize Metal-Organic Frameworks and Investigate Their Interaction with Guest Molecules

Chemical Reviews, Journal Year: 2020, Volume and Issue: 121(3), P. 1286 - 1424

Published: Dec. 14, 2020

The variety of functionalities and porous structures inherent to metal-organic frameworks (MOFs) together with the facile tunability their properties makes these materials suitable for a wide range existing emerging applications. Many applications are based on processes involving interaction MOFs guest molecules. To optimize certain process or successfully design new one, thorough knowledge is required about physicochemical characteristics mechanisms obtain such important information, various complementary analytical techniques applied, among which vibrational spectroscopy (IR Raman) plays an role indispensable in many cases. In this review, we critically examine reported IR Raman spectroscopies as powerful tools initial characterization MOF studying gases. Both advantages limitations technique considered, cases where preferable highlighted. Peculiarities specific gases some inconsistent band assignments also emphasized. Summarizing broad possibilities spectroscopies, conclude that it can be applied combinations other explicitly establish structure, properties, reactivity MOFs.

Language: Английский

---

Photocatalysis-activated SR-AOP over PDINH/MIL-88A(Fe) composites for boosted chloroquine phosphate degradation: Performance, mechanism, pathway and DFT calculations

Applied Catalysis B Environment and Energy, Journal Year: 2021, Volume and Issue: 293, P. 120229 - 120229

Published: April 16, 2021

Language: Английский

---

A review of metal organic framework (MOFs)-based materials for antibiotics removal via adsorption and photocatalysis

Chemosphere, Journal Year: 2021, Volume and Issue: 272, P. 129501 - 129501

Published: Jan. 7, 2021

Language: Английский

---

Fe-based metal-organic frameworks as Fenton-like catalysts for highly efficient degradation of tetracycline hydrochloride over a wide pH range: Acceleration of Fe(II)/ Fe(III) cycle under visible light irradiation

Applied Catalysis B Environment and Energy, Journal Year: 2019, Volume and Issue: 263, P. 118282 - 118282

Published: Oct. 23, 2019

Language: Английский

---

Remediation of antibiotic wastewater by coupled photocatalytic and persulfate oxidation system: A critical review

Journal of Hazardous Materials, Journal Year: 2020, Volume and Issue: 408, P. 124461 - 124461

Published: Nov. 4, 2020

Language: Английский

---

Application of MOFs and COFs for photocatalysis in CO2 reduction, H2 generation, and environmental treatment

EnergyChem, Journal Year: 2022, Volume and Issue: 4(4), P. 100078 - 100078

Published: June 25, 2022

Language: Английский

---

Treatment of industrial dye wastewater and pharmaceutical residue wastewater by advanced oxidation processes and its combination with nanocatalysts: A review

Journal of Water Process Engineering, Journal Year: 2021, Volume and Issue: 42, P. 102122 - 102122

Published: May 6, 2021

Language: Английский

---

Dual-channel charges transfer strategy with synergistic effect of Z-scheme heterojunction and LSPR effect for enhanced quasi-full-spectrum photocatalytic bacterial inactivation: new insight into interfacial charge transfer and molecular oxygen activation

Applied Catalysis B Environment and Energy, Journal Year: 2019, Volume and Issue: 264, P. 118465 - 118465

Published: Nov. 27, 2019

Language: Английский

---

Degradation of acetaminophen by activated peroxymonosulfate using Co(OH)2 hollow microsphere supported titanate nanotubes: Insights into sulfate radical production pathway through CoOH+ activation

Chemical Engineering Journal, Journal Year: 2020, Volume and Issue: 406, P. 126877 - 126877

Published: Sept. 3, 2020

Language: Английский

---