The Journal of Organic Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 25, 2025
Among
all
compounds
constructed
by
intramolecular
integration,
4
(Td
=
321
°C,
D
8799
m
s-1,
IS
35
J)
that
integrates
ortho
amino
nitro
group
and
tetrazole
framework
possesses
a
much
better
comprehensive
performance
than
most
widely
used
heat-resistant
explosive
HNS
318
7612
5
J),
which
suggest
it
might
be
candidate
for
advanced
explosive.
Compared
with
8,
isomer
shows
significant
improvement
in
density,
thermal
stability
sensitivity,
may
caused
the
relatively
strong
structural
aromaticity,
hydrogen
bond
large
face-to-face
π-π
interaction
surfaces
strength.
ACS Applied Materials & Interfaces,
Journal Year:
2022,
Volume and Issue:
14(44), P. 49898 - 49908
Published: Oct. 26, 2022
Thermally
stable
energetic
materials
have
broad
applications
in
the
deep
mining,
oil
and
natural
exploration,
aerospace
industries.
The
quest
for
thermally
(heat-resistant)
with
high
energy
output
low
sensitivity
has
fascinated
many
researchers
worldwide.
In
this
study,
two
different
series
of
salts
based
on
pyrazole–oxadiazole
pyrazole–triazole
(3–23)
explosophoric
groups
been
synthesized
a
simple
straightforward
manner.
All
newly
compounds
were
fully
characterized
by
IR,
ESI-MS,
multinuclear
NMR
spectroscopy,
elemental
analysis,
thermogravimetric
analysis–differential
scanning
calorimetry
measurements.
structures
3,
7,
22
supported
single-crystal
X-ray
diffraction
studies.
density,
heat
formation,
properties
(detonation
velocity
detonation
pressure)
all
range
between
1.75
1.94
g
cm–3,
0.73
to
2.44
kJ
g–1,
7689
9139
m
s–1,
23.3
31.5
GPa,
respectively.
are
insensitive
impact
(>30
J)
friction
(>360
N).
addition,
4,
6,
10,
14,
17,
21,
22,
23
show
onset
decomposition
temperature
(Td
238
397
°C)
than
benchmark
RDX
=
210
°C),
HMX
(279
HNS
(318
°C).
It
is
noteworthy
that
backbones
greatly
influence
their
physicochemical
properties.
Overall,
study
offers
perspective
nitrogen-rich
explores
relationship
structure
performance.
ACS Applied Materials & Interfaces,
Journal Year:
2022,
Volume and Issue:
14(8), P. 10594 - 10604
Published: Feb. 22, 2022
The
development
of
energetic
materials
is
still
facing
a
huge
challenge
because
the
relationship
between
energy
and
sensitivity
usually
contradictory:
high
always
accompanied
with
low
sensitivity.
Here,
high-energy,
low-sensitivity
polynitro-functionalized
azopyrazole
(TNAP)
its
salts
have
been
synthesized.
structural
characterization
these
compounds
was
analyzed
by
elemental
analysis,
1H
13C
NMR
spectroscopies,
infrared
spectroscopy.
single-crystal
structure
K2TNAP,
TNAP,
5,
6
obtained
X-ray
diffraction,
K2TNAP
novel
metal-organic
framework.
calculated
detonation
properties
TNAP
(9040
m
s-1
36.0
GPa)
are
superior
to
that
RDX
(8796
33.6
GPa).
In
addition,
also
has
lower
mechanical
(IS
>
40
J,
FS
=
244
N)
higher
decomposition
temperature
(Td
221
°C)
than
7.4
120
N,
Td
204
°C).
These
experimental
results
suggest
may
become
new
candidate
for
secondary
explosives.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(22), P. 13231 - 13239
Published: Jan. 1, 2024
Two
high-performance
heat-resistant
energetic
materials
were
developed
via
a
synergistic
strategy
of
designing
hydrogen
bonding
networks
and
expanding
the
π-conjugation
system.
Inorganic Chemistry,
Journal Year:
2022,
Volume and Issue:
61(9), P. 4143 - 4149
Published: Feb. 22, 2022
In
recent
years,
molecular
perovskite
energetic
materials
have
attracted
more
attention
because
of
their
simple
synthesis
processes,
high
thermal
stabilities,
excellent
performances,
and
great
significance
as
a
design
platform
for
materials.
To
explore
the
possibility
application
in
heat-resistant
explosives,
four
silver(I)-based
compounds,
(H2A)[Ag(ClO4)3],
where
H2A
=
piperazine-1,4-diium
(H2pz2+)
PAP-5,
1-methyl-piperazine-1,4-diium
(H2mpz2+)
PAP-M5,
homopiperazine-1,4-diium
(H2hpz2+)
PAP-H5,
1,4-diazabicyclo[2.2.2]octane-1,4-diium
(H2dabco2+)
DAP-5,
were
synthesized
by
one-pot
self-assembly
strategy
structurally
characterized.
The
single-crystal
structures
indicated
that
DAP-5
possess
cubic
while
PAP-H5
possesses
hexagonal
structure.
Differential
analyses
showed
onset
decomposition
temperatures
are
>308.3
°C.
For
PAP-5
they
not
only
exceptional
calculated
detonation
parameters
(D
values
8.961
8.534
km
s-1
P
42.4
37.9
GPa,
respectively)
but
also
proper
mechanical
sensitivity
(impact
sensitivities
≤10
J
3
friction
≤5N
both
DAP-5)
thus
interest
potential
primary
explosive
components.
Organic & Biomolecular Chemistry,
Journal Year:
2023,
Volume and Issue:
21(32), P. 6604 - 6616
Published: Jan. 1, 2023
This
work
demonstrates
the
synthesis,
characterization,
and
energetic
properties’
evaluation
of
polynitro-functionalized
4-phenyl-1
H
-pyrazole-based
heat-resistant
explosives.
Physical Chemistry Chemical Physics,
Journal Year:
2023,
Volume and Issue:
25(28), P. 18523 - 18544
Published: Jan. 1, 2023
Increasing
the
strength
and
number
of
hydrogen
bonds
azoles
expanding
π–π
stacking
area
are
key
factors
to
improve
thermal
stability,
which
provides
a
valuable
way
for
developing
energetic
materials
with
higher
energy
stability.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(36), P. 24188 - 24194
Published: Jan. 1, 2024
H4
(
T
d
=
365
°C,
D
8844
m
s
−1
)
synthesized
in
this
work
possesses
both
super
heat
resistance
and
high
explosive
properties,
strongly
supporting
it
as
a
candidate
for
advanced
ultra
heat-resistant
explosives.
