Analytical Methods,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
A
portable
paper-based
enzyme
sensor
utilizing
a
Zr-doped
Fe-MOF
enables
sensitive
glyphosate
detection
through
coordination
interactions
and
automated
colorimetric
signal
output.
Journal of Agricultural and Food Chemistry,
Journal Year:
2021,
Volume and Issue:
69(43), P. 12661 - 12673
Published: Oct. 21, 2021
In
this
paper,
a
dual-functional
probe,
2-(benzothiazol)-4-(3-hydroxy-4-methylphenyl)
imino
phenol
(BHMH),
was
synthesized
and
characterized
for
the
simultaneous
detection
of
Cu2+
Fe3+
in
dimethyl
sulfoxide/4-(2-hydroxyethyl)-1-piperazineethanesulfonic
acid
(DMSO/HEPES)
(1:4,
v/v,
pH
=
6.0).
The
limits
detections
(LODs)
were
9.05
48
nM,
respectively.
Based
on
competitive
coordination,
complex
BHMH-Cu2+/Fe3+
exhibited
good
sensitivity
selectivity
glyphosate.
LODs
BHMH-Cu2+
BHMH-Fe3+
glyphosate
0.41
0.63
μM,
probe
quantitatively
detected
tap
water,
Songhua
River
local
water
soil,
food
samples.
colorimetric
on-site
sensing
through
also
studied
based
smartphones.
BHMH
outstanding
imaging
capabilities
Cu2+,
Fe3+,
living
cells
with
low
cytotoxicity,
especially
first
time
Journal of Agricultural and Food Chemistry,
Journal Year:
2022,
Volume and Issue:
70(4), P. 1003 - 1018
Published: Jan. 18, 2022
Protoporphyrinogen
oxidase
(PPO,
EC
1.3.3.4)
is
an
important
target
for
discovering
novel
herbicides,
and
it
causes
bleaching
symptoms
by
inhibiting
the
synthesis
of
chlorophyll
heme.
In
this
study,
active
fragments
several
commercial
herbicides
were
joined
substructure
splicing
bioisosterism,
a
series
diphenyl
ether
derivatives
containing
five-membered
heterocycles
synthesized.
The
greenhouse
herbicidal
activity
PPO
inhibitory
in
vitro
discussed
detail.
results
showed
that
most
compounds
had
good
activity,
trifluoromethyl
groups
tended
to
have
higher
activity.
Among
them,
compound
G4
best
with
half-maximal
concentration
(IC50)
0.0468
μmol/L,
which
was
approximately
3
times
better
than
oxyfluorfen
(IC50
=
0.150
μmol/L).
addition,
molecular
docking
indicated
formed
obvious
π-π
stacking
interactions
hydrogen
bond
PHE-392
ARG-98,
respectively.
Remarkably,
safety
corn,
wheat,
rice,
soybean,
cumulative
crops
lower
oxyfluorfen.
Therefore,
can
be
used
develop
potential
lead
inhibitors.
Journal of Agricultural and Food Chemistry,
Journal Year:
2022,
Volume and Issue:
70(26), P. 7911 - 7920
Published: June 24, 2022
Pyrimethanil
(PMT)
is
an
anilinopyrimidine
bactericide
with
poor
water
solubility,
which
limits
its
applications.
To
improve
the
physical
and
chemical
properties
of
PMT,
hydroxypropyl-β-cyclodextrin/pyrimethanil
inclusion
compound
nanofibers
(HPβCD/PMT-IC-NFs)
were
fabricated
via
electrospinning.
A
variety
analytical
techniques
used
to
confirm
formation
compound.
Scanning
electron
microscopy
image
displayed
that
HPβCD/PMT-IC-NF
was
homogeneous
without
particles.
Thermogravimetric
analysis
indicated
improved
thermostability
PMT.
In
addition,
phase
solubility
test
illustrated
formed
by
PMT
HPβCD
had
a
stronger
solubility.
The
antifungal
effect
exhibited
better
properties.
release
experiment
confirmed
sustained-release
effect,
curve
conformed
first-order
kinetic
model
equation.
short,
fabrication
inhibited
thus
promoting
development
pesticide
dosage
form
water-based
low-pollution
direction.