CrystEngComm,
Journal Year:
2022,
Volume and Issue:
24(31), P. 5557 - 5561
Published: Jan. 1, 2022
A
Co-MOF
with
a
2D
morphology
(BUC-92)
was
prepared,
which
exhibited
outstanding
rhodamine
B
(RhB)
degradation
performance
via
peroxymonosulfate
(PMS)
activation.
Chemical Engineering Journal,
Journal Year:
2022,
Volume and Issue:
452, P. 139202 - 139202
Published: Sept. 16, 2022
Per-
and
polyfluoroalkyl
substances
(PFAS)
are
a
class
of
toxic
bioaccumulative
compounds
affecting
environmental
human
health.
Conventional
wastewater
treatment
processes
ineffective
at
remediating
these
persistent
chemicals.
While
functional
framework
materials
have
been
shown
to
remove
PFAS
via
adsorption
catalytic
degradation,
there
is
an
on-going
debate
about
their
practical
use
in
water
purification.
Inspired
by
recent
research
on
typical
materials,
including
zeolites,
metal-organic
frameworks
(MOFs),
covalent
organic
(COFs),
our
review
summarizes
the
principles
design,
properties,
applications
with
special
emphasis
removal.
The
potential
material
for
degradation
constructively
discussed,
based
limited
studies
thus
far.
Finally,
challenges
using
degrade
presented
along
sustainable
design
prospects
improve
technology.
current
provides
new
insights
advancing
elimination
from
contaminated
waters.
Molecules,
Journal Year:
2023,
Volume and Issue:
28(8), P. 3622 - 3622
Published: April 21, 2023
Metal–organic
framework
(MOF)
materials
possess
a
large
specific
surface
area,
high
porosity,
and
atomically
dispersed
metal
active
sites,
which
confer
excellent
catalytic
performance
as
peroxide
(peroxodisulfate
(PDS),
peroxomonosulfate
(PMS),
hydrogen
(H2O2))
activation
catalysts.
However,
the
limited
electron
transfer
characteristics
chemical
stability
of
traditional
monometallic
MOFs
restrict
their
large-scale
application
in
advanced
oxidation
reactions.
Furthermore,
single-metal
site
uniform
charge
density
distribution
result
fixed
reaction
path
Fenton-like
process.
To
address
these
limitations,
bimetallic
have
been
developed
to
improve
activity,
stability,
controllability
Compared
with
MOFs,
enhance
material,
promote
internal
transfer,
even
alter
through
synergistic
effect
bimetals.
In
this
review,
we
systematically
summarize
preparation
methods
mechanism
activating
different
systems.
Moreover,
discuss
factors
that
affect
process
activation.
This
report
aims
expand
understanding
MOF
synthesis
mechanisms
processes.