Advances and prospects of low temperature Li S batteries DOI

Kaijie Miao,

Chengwei Ma, Jiangqi Zhou

et al.

Applied Energy, Journal Year: 2025, Volume and Issue: 388, P. 125720 - 125720

Published: March 15, 2025

Language: Английский

Kinetically Favorable Li–S Battery Electrolytes DOI

Zixiong Shi,

Zhengnan Tian, Dong Guo

et al.

ACS Energy Letters, Journal Year: 2023, Volume and Issue: 8(7), P. 3054 - 3080

Published: June 20, 2023

Lithium–sulfur (Li–S) batteries suffer from rampant polysulfide shuttling and sluggish reaction kinetics, which have curtailed sulfur utilization deteriorated their actual performance. To circumvent these detrimental issues, electrolyte engineering is a reliable strategy to control behavior facilitate kinetics. However, the electrolyte–polysulfide nexus remains elusive, design principle far clear, especially for pragmatic application. In this Review, key approaches obtain kinetically favorable Li–S battery electrolytes are elucidated three perspectives: (i) high-donor-number components, (ii) homogeneous catalysts, (iii) endogenous co-mediators. Particular attention paid probing underlying working mechanism. addition, kinetics electrochemical performances systematically studied, highlighting strategic effectiveness of in lean-electrolyte conditions. This Review aims offer meaningful guidance rational enhance performance advance commercialization batteries.

Language: Английский

Citations

59
Emerging medium- and high-entropy materials as catalysts for lithium-sulfur batteries DOI
Josué M. Gonçalves, Érick A. Santos, Paulo Roberto Martins

et al.

Energy storage materials, Journal Year: 2023, Volume and Issue: 63, P. 102999 - 102999

Published: Sept. 26, 2023

Language: Английский

Citations

30
Supramolecular channels via crown ether functionalized covalent organic frameworks for boosting polysulfides conversion in Li−S batteries DOI

Diandian Han,

Linhai Sun,

Ziqiu Li

et al.

Energy storage materials, Journal Year: 2023, Volume and Issue: 65, P. 103143 - 103143

Published: Dec. 17, 2023

Language: Английский

Citations

27
Progress in the advancement of atomically dispersed catalysts for enhanced performance lithium-sulfur batteries DOI
Jiangqi Zhou, Aiyue Sun

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 488, P. 150719 - 150719

Published: March 29, 2024

Language: Английский

Citations

15
Redox mediators for high performance lithium-sulfur batteries: Progress and outlook DOI
Jiangqi Zhou, Aiyue Sun

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 495, P. 153648 - 153648

Published: July 1, 2024

Language: Английский

Citations

15
Progress on Critical Cell-fabrication Parameters and Designs for Advanced Lithium–Sulfur Batteries DOI

Cheng‐Che Wu,

Tzu-Ching Chan,

Sheng‐Heng Chung

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(79), P. 11017 - 11033

Published: Jan. 1, 2024

Since 1990, commercial lithium-ion batteries have made significant strides, approaching their theoretical performance limits, albeit with escalating costs. To address these challenges, attention has shifted toward lithium-sulfur batteries, which offer higher energy densities and cost-effectiveness. However, cells face challenges such as active-material loss, excessive electrolyte usage, rapid degradation of lithium-metal anodes. overcome issues, research focused on optimizing cell configurations fabrication parameters while exploring novel electrolytes electrode materials. This feature article delves into the intrinsic material extrinsic engineering issues in current explores development advanced crucial progress high-loading sulfur cathodes, lean-electrolyte cells, solid-state electrolytes. Moreover, it outlines fundamental principles, structures, performances, developmental trajectories indicated articles published after 2020, highlighting future directions aimed at resolving key for practical application cells.

Language: Английский

Citations

12
Dual-stage polyporate framework with redox mediator for high loading lithium sulfur batteries DOI
Yifan Zhang, Wenqiang Wang, Zhichao Jia

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 67, P. 103320 - 103320

Published: March 1, 2024

Language: Английский

Citations

11
In-situ chemical state transition of Ni nano-metal catalytic site promotes the reaction kinetics of lithium-sulfur battery DOI

Chunman Yang,

Fei Wang,

Dan You

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 153812 - 153812

Published: July 7, 2024

Language: Английский

Citations

11
Electrocatalysts work better in lean-electrolyte lithium–sulfur batteries DOI
Jiajia Zhao, Zixian Chen, Qian Cheng

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(33), P. 21845 - 21852

Published: Jan. 1, 2024

The cathode kinetics promotion effectiveness of electrocatalysts is evaluated in lean-electrolyte lithium–sulfur batteries. improvement polysulfide conversion and battery performance more significant at higher sulfur concentration.

Language: Английский

Citations

10
Transition Metals@MXenes electrocatalysts for high-performance Lithium–Sulfur batteries under lean electrolyte: A comprehensive review DOI
Jinwu Bai, Kai Li, Zihang Zhang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160285 - 160285

Published: Feb. 1, 2025

Language: Английский

Citations

1