Multicolor Mechanoluminescence From Lu3Al2Ga3O12: Tb, Eu for Stress and Temperature Visual Sensing DOI Creative Commons

Zhiyao Zhou,

Sheng Wu,

Binli Xiao

et al.

Advanced Optical Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 14, 2024

Abstract Mechanoluminescence (ML) refers to the luminescence phenomenon that occurs when a material is under external mechanical stimuli. However, relying solely on stress information obtain ML signals prone test errors in complex conditions. In this work, Tb 3+ /Eu ‐doped Lu 3 Al 2 Ga O 12 multicolor reported, which color can be adjusted from white red (CIE coordinates: (x = 0.313, y 0.3293) 0.6183, 0.379)) by changing Eu concentration. addition, LAGO: 0.25% and 1.5% are physically mixed at different mass ratios, varied stimuli‐responsed emission characteristics of ions used develop temperature dual sensing device. Stress further reflected simultaneously through blue/red ratio I R (I /I ). As increases, changes 0.3259, 0.306) 0.4707, 0.3625)), relative sensitivity (Sr) as high 1.209% K −1 298 K. This device provides new idea for potential structural safety monitoring, multi‐modal anti‐counterfeiting technology, etc.

Language: Английский

A Novel Near‐Infrared Emitting Sr2LuSbO6:Fe3+ Phosphor with Persistent Luminescence Performance DOI

Jiangyue Su,

Ran Pang,

Tao Tan

et al.

Advanced Optical Materials, Journal Year: 2024, Volume and Issue: 12(17)

Published: March 2, 2024

Abstract The near‐infrared (NIR) persistent luminescence (PersL) materials have attracted widespread attention owing to the unique self‐sustained light with good penetrability. Currently, most of reported NIR PersL are activated by Cr 3+ . Considering potential toxicity chromium ions, there is an urgent requirement explore ‐free phosphors. Herein, a novel phosphor Sr 2 LuSbO 6 :Fe (SLSO:Fe ) prepared and its properties systematically studied. Fe ‐activated exhibits long‐wavelength emission band centered at 890 nm 110 full‐width half maximum (FWHM), can last over 18 h. shows excellent stability even after being dispersed in solutions different environments for 7 days. Furthermore, emitted penetrate cm thickness beef, evidencing penetration property. This work provides based on technological applications also contributes accelerate development new‐generation ‐doped toward versatile applications.

Language: Английский

Citations

20
Realizing Near Infrared Mechanoluminescence Switch in LAGO:Cr Based on Oxygen Vacancy DOI
Sheng Wu,

Binli Xiao,

Dongliang Jiang

et al.

Small, Journal Year: 2024, Volume and Issue: 20(31)

Published: March 7, 2024

Abstract Mechanoluminescence (ML) materials are featured with the characteristic of “force to light” in response external stimuli, which have made great progress artificial intelligence and optical sensing. However, how effectively enable ML material is a daunting challenge. Here, Lu 3 Al 2 Ga O 12 :Cr 3+ (LAGO: Cr ) near infrared (NIR) peaked at 706 nm reported, successfully realizes key unlock by lattice‐engineering strategy substitution for “grow” oxygen vacancy (O v defects. Combined thermoluminescence measurements, observed due formation defect levels intensity proportional it. It confirmed X‐ray photoelectron spectroscopy electron paramagnetic resonance that such process dominated , plays crucial role turning on this compound. In addition, potential emissions from 4 T E level transitions discussed both experimental theoretical aspects. This study reveals mechanism change behavior after cation substitution, it may important implications practical application defect‐regulated turn‐on ML.

Language: Английский

Citations

16
Multiple Defect‐Induced High‐Resolution Near‐Infrared Mechanoluminescent Materials for Non‐Destructive Detection of Blood Glucose and Lipids DOI Open Access
Sheng Wu, Guangyu Zhou,

Yafen Wu

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(50)

Published: Nov. 6, 2024

Mechanoluminescence (ML) materials, known for their ability to convert mechanical energy into light, are increasingly recognized potential applications, such as in intelligent stress sensing, vivo bioimaging, and non-destructive monitoring. However, the low signal-to-noise ratio (SNR) narrow-band emission of single-defect-induced ML materials usually limit biological-related practical applications. Here, these limitations will be addressed by modulating microstructure evolution Y

Language: Английский

Citations

16
Near-infrared mechanoluminescence from Sr3Sn2O7:Nd3+ for potential bioimaging and non-destructive detection DOI Creative Commons

Yafen Wu,

Sheng Wu, Puxian Xiong

et al.

Journal of Rare Earths, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Language: Английский

Citations

2
Tunable Spinel Structure Phosphors: Dynamic Change in Near‐Infrared Windows and Their Applications DOI
Wen‐Tse Huang, Kuan‐Chun Chen,

Ming‐Hsuan Huang

et al.

Advanced Optical Materials, Journal Year: 2023, Volume and Issue: 11(23)

Published: July 26, 2023

Abstract Applications in near‐infrared (NIR) have been explored significantly many fields, including bioimaging, night vision, plant growth, and chemical analysis. Different emission profiles are required within the same industry. Developing luminescent materials with different tuning methods is reliable for controlling NIR regions (NIR‐I, 700–1000 nm; NIR‐II, 1000–1700 nm). Spinel phosphors promising candidates due to their ability modulate crystal field. Understanding parameters that influence degree of inversion spinel compounds crucial harness variability structure. Cr 3+ Ni 2+ ideal activators NIR‐I NIR‐II emissions, respectively. However, there a need emit region when excited by visible light. Although energy transfer method combining two considered, this review focuses on types structures, discussing common strategies tune host The goal achieve desired shift broadness entire spectrum, highlighting importance spectrum practical applications.

Language: Английский

Citations

41
Cation-defect-induced self-reduction towards efficient mechanoluminescence in Mn2+-activated perovskites DOI
Yao Xiao, Puxian Xiong, Shuai Zhang

et al.

Materials Horizons, Journal Year: 2023, Volume and Issue: 10(9), P. 3476 - 3487

Published: Jan. 1, 2023

A deep-red to NIR ML phosphor of MgGeO 3 : Mn 2+ is reported, and defect believed influence the properties by comparing phosphor’s luminescent before after 4+ –Mn self-reduction.

Language: Английский

Citations

39
Cr3+-activated broadband near-infrared mechanoluminescence in garnet compound DOI
Sheng Wu,

Binli Xiao,

Yao Xiao

et al.

Nano Energy, Journal Year: 2023, Volume and Issue: 116, P. 108811 - 108811

Published: Aug. 21, 2023

Language: Английский

Citations

36
Single Tb3+ ion doped ratiometric mechanoluminescence for tunable stress visualization DOI
Sheng Wu, Puxian Xiong,

Dongliang Jiang

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 469, P. 143961 - 143961

Published: June 7, 2023

Language: Английский

Citations

31
Self-recoverable NIR mechanoluminescence from Cr3+ doped perovskite type aluminate DOI Creative Commons

Peishan Shao,

Puxian Xiong, Yao Xiao

et al.

Advanced Powder Materials, Journal Year: 2023, Volume and Issue: 3(2), P. 100165 - 100165

Published: Nov. 8, 2023

Mechanoluminescent (ML) materials, which have the ability to convert mechanical energy optical energy, found huge promising applications such as in stress imaging and anti-counterfeiting. However, main reported ML phosphors are based on trap-related ones, thus hindering practical due requirement of complex light pre-irradiation process. Here, a self-recoverable near infrared (NIR) material LaAl1-xO3: xCr3+ (x = 0.2 %, 0.4 0.6 0.8 1.0 % 1.2 %) has been developed. Based preheating method corresponding performance analysis, influences residual carriers eliminated detailed dynamic luminescence process analysis is realized. Systematic experiments conducted reveal origin emissions, demonstrating that dictated more by non-centrosymmetric piezoelectric crystal characteristic. In general, this work provided significant references for exploring efficient NIR may provide potential anti-counterfeiting bio-stress sensing.

Language: Английский

Citations

29
Multicolor Mechanoluminescence in Sr2Ga2GeO7: Pr3+ for Stress Sensing and Anticounterfeiting DOI

Binli Xiao,

Puxian Xiong, Sheng Wu

et al.

Advanced Optical Materials, Journal Year: 2023, Volume and Issue: 11(22)

Published: July 14, 2023

Abstract Mechanical luminescence (ML) is the conversion of mechanical energy into light when a material subjected to force. It challenging develop ML materials with tunable luminescent properties by single ion doping, which have broad application prospects in fields stress sensing and dynamic signature anticounterfeiting. In this study, Pr 3+ doped Sr 2 Ga GeO 7 reported. Due traps resulting from unequal substitution –Sr 2+ [SrO 6 ] heptahedra, deep/shallow redistribution occurs towards multicolor red green. addition, even after continuous friction sliding force (15 N), intensities can be recovered ultraviolet pre‐irradiation, indicating that : has excellent emission stability. Based on thermoluminescence analysis, potential PersL mechanisms are further elaborated lattice engineering (trap regulation) strategy. all, development single‐ion may crucial research value show variety applications anticounterfeiting information encryption.

Language: Английский

Citations

28