Elemental Charge Engineering in Cobalt and Cobalt–Phosphide Interface for Enhanced Oxygen Evolution and Urea Oxidation Reactions DOI
Xiang Ding, Jun Xiang, Yangyang Wan

et al.

ACS Applied Energy Materials, Journal Year: 2024, Volume and Issue: 7(9), P. 4260 - 4267

Published: April 16, 2024

The development of cost-effective electrocatalysts with high performance for oxygen evolution and urea oxidation reaction (OER/UOR) is desirable but remains a great challenge. Here, we report facile strategy boron-doping cobalt cobalt–phosphide interfacial (B–Co/Co2P) bifunctional OER/UOR. By virtue B doping, the abundant exposed active sites as well enhanced electrical conductivity can efficiently improve charge migration heterogeneous sites. Therefore, obtained B–Co/Co2P exhibit OER/UOR activities an outstanding overpotential 284 107 mV at industrial current density 100 mA cm–2, respectively. Such excellent catalytic attributed to fact that dopant adjusts electron distribution optimizes adsorption/desorption intermediate species, reduces energy barriers water oxidation. Furthermore, setup two-electrode cell requires merely overpotentials 280.7 56.9 drive 10 cm–2 robust stability in splitting electrolysis, Overall, this provides construct catalysts efficiency hydrogen generation.

Language: Английский

Crafting amorphous VO2–crystalline NiS2 heterostructures as bifunctional electrocatalysts for efficient water splitting: The different cocatalytic function of VO2 DOI

Weiliang Zhou,

Xiaojie Li, Xuan Li

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 470, P. 144146 - 144146

Published: June 19, 2023

Language: Английский

Citations

26
Breakthroughs and prospects in ruthenium-based electrocatalyst for hydrogen evolution reaction DOI
Thanh-Binh Nguyen,

Kamakshi Sherpa,

Chiu‐Wen Chen

et al.

Journal of Alloys and Compounds, Journal Year: 2023, Volume and Issue: 968, P. 172020 - 172020

Published: Sept. 9, 2023

Language: Английский

Citations

23
Activating Fe activity and improving Ni activity via C3N4 substrate in alkaline oxygen evolution catalyzed by Ni-Fe phosphide DOI
Hongyan Zhang, Tao Yang, Hao Zhou

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 342, P. 123391 - 123391

Published: Oct. 11, 2023

Language: Английский

Citations

23
Integrated MXene and metal oxide electrocatalysts for the oxygen evolution reaction: synthesis, mechanisms, and advances DOI Creative Commons
Muhammad Nazim Lakhan, Abdul Hanan, Yuan Wang

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(38), P. 15540 - 15564

Published: Jan. 1, 2024

This review summarizes recent advances in MXene and transition metal oxide (TMO) electrocatalysts for enhancing oxygen evolution reaction (OER), concluding with key findings future research directions further improvements.

Language: Английский

Citations

11
Enhancing d-band center modulation in Carbon-Supported CoP via exogenous nitrogen Dopants: A strategy for boosting Ampere-Level hydrogen evolution reaction DOI
Qichang Wang, Zhanghong Wang, Jing Zhao

et al.

Journal of Catalysis, Journal Year: 2024, Volume and Issue: 430, P. 115310 - 115310

Published: Jan. 24, 2024

Language: Английский

Citations

9
Built-in electric field drives n-n heterojunction toward enhanced electrochemical freshwater and seawater oxidation DOI
Lei Jin, Hui Xu, Kun Wang

et al.

Applied Surface Science, Journal Year: 2024, Volume and Issue: 657, P. 159777 - 159777

Published: Feb. 24, 2024

Language: Английский

Citations

9
Dual-strategy engineered nickel phosphide for achieving efficient hydrazine-assisted hydrogen production in seawater DOI Creative Commons
Ruiqing Li,

Songyun Guo,

Xiaojun Wang

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(26), P. 10084 - 10091

Published: Jan. 1, 2024

We developed a dual-strategy of Fe doping and CeO 2 decoration to optimize the electronic structure reaction energy barrier Ni P achieve energy-efficient chlorine-free hydrogen production by coupling HER with HzOR in seawater.

Language: Английский

Citations

9
Step-by-step enhancing oxygen evolution ability of CoFe2O4 by hybrid structure engineering and fluorine doping DOI

Yi‐Gang Ji,

Jiawei Wu, Huan Wen

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 154211 - 154211

Published: July 22, 2024

Language: Английский

Citations

9
Iron-doped cobalt phosphide nanowires prepared via one-step solvothermal phosphidization of metal–organic frameworks for the oxygen evolution reactions DOI
Jianbo Tong,

Yichuang Xing,

Xuechun Xiao

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(9), P. 5308 - 5325

Published: Jan. 1, 2024

A solvothermal phosphidization method is adopted to construct CoFeP nanowires electrochemically catalyze oxygen evolution reaction.

Language: Английский

Citations

8
CoFePS Quaternary Alloy Sub‐Nanometric Sheets by Synchronously Phospho‐Sulfurizing CoFe‐Bimetallene for Boosting Oxygen Evolution Reaction DOI
Long Zhao,

Ming Wen,

Yibo Guo

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(50)

Published: Aug. 7, 2023

Abstract Due to the sluggish kinetics of oxygen evolution reaction (OER), electrocatalysts are urgently needed simultaneously achieve increased activity, enhanced stability, and reduced cost. Herein, CoFePS quaternary alloy sub‐nanometric sheet is synthesized via synchronously phosphor‐sulfurizing CoFe‐bimetallene. Heteroatomization results in increasing conductivity, enhancing interactions with electrolyte, improving chemical structural stability exhibit a current density 10 mA cm −2 at 211 mV large 1053 570 mV. Density functional theory calculations reveal that adjustment Fermi levels adjacent metal atoms reduces energy barrier accelerates electron transfer, resulting Tafel slope 14 dec −1 . In situ Raman monitors formation phosphor‐sulfate shell oxidized surface as active sites improved OER CoFePS, retention rate 99.7% for 78 h. This study provides promising strategy synthesis multicomponent good electrocatalyst candidates OER.

Language: Английский

Citations

21