Silica Nanoparticle/TPU Coating Imparts Aramid with Puncture Resistance and Anti-corrosion for Personal Protection DOI

Ting‐Ting Li,

Sheng Chu, Xianjin Hu

et al.

ACS Applied Nano Materials, Journal Year: 2023, Volume and Issue: 6(18), P. 16986 - 16999

Published: Aug. 31, 2023

In extreme environments, the simultaneous requirements of puncture resistance, acid and alkali chemical corrosion resistance are crucial for design safety protection materials. To address these requirements, this study employed a "scratch coating" technique, combining modified silica nanoparticles (nano F–SiO2) thermoplastic polyurethane elastomers (TPU) with aramid fabrics. This approach ensured that composites were both soft resistant. Additionally, simple cost-effective spraying method was utilized to create multifunctional coating comprising nanosilica, micron-polytetrafluoroethylene (PTFE), fluorinated alkyl silane. Furthermore, investigated effect different lamination angles fabric on resistance. The results demonstrated composite exhibited outstanding strong acids bases, super-double sparsity. Notably, maximum reached 515.50 N, which 33.02 times higher than pure (15.61 N). Similarly, knife 247.42 representing 10.77-fold increase compared (22.97 obtained superhydrophobicity water contact angle 163.8° sliding 3.2°. It remarkable durability when immersed in acidic or basic solutions 120 h exposed outdoor conditions more 30 days. Importantly, micronano displayed exceptional stability even subjected highly corrosive chemicals such as concentrated sulfuric (98%) sodium hydroxide (40%) up 12 h. summary, introduces novel designing flexible puncture-resistant properties. offers valuable insights contributes advancements field protective materials..

Language: Английский

Flexible, Reliable, and Lightweight Multiwalled Carbon Nanotube/Polytetrafluoroethylene Membranes with Dual‐Nanofibrous Structure for Outstanding EMI Shielding and Multifunctional Applications DOI

Runze Shao,

Guilong Wang, Jialong Chai

et al.

Small, Journal Year: 2024, Volume and Issue: 20(24)

Published: Jan. 4, 2024

In this study, lightweight, flexible, and environmentally robust dual-nanofibrous membranes made of carbon nanotube (CNT) polytetrafluoroethylene (PTFE) are fabricated using a novel shear-induced in situ fibrillation method for electromagnetic interference (EMI) shielding. The unique spiderweb-like network, constructed from fine CNTs PTFE fibrils, integrates the inherent characteristics these two materials to achieve high conductivity, superhydrophobicity, extraordinary chemical resistance. demonstrate EMI shielding effectiveness (SE) 25.7–42.2 dB at thickness range 100–520 µm normalized surface-specific SE can reach up 9931.1 dB·cm2·g−1, while maintaining reliability even under extremely harsh conditions. addition, distinct electrothermal photothermal conversion properties be achieved easily. Under stimulation modest electrical voltage (5 V) light power density (400 mW·cm−2), surface temperatures CNT/PTFE 135.1 147.8 °C, respectively. Moreover, exhibit swift, stable, highly efficient thermal capabilities, endowing them with self-heating de-icing performance. These versatile, breathable membranes, coupled their facile fabrication process, showcase tremendous application potential aerospace, Internet Things, wearable electronic equipment extreme environments.

Language: Английский

Citations

22

Super high flux oil/water separation and efficient separation of water-in-oil emulsions by a versatile superhydrophobic multi-walled carbon nanotubes coating DOI
Yu Guo, Haibin Zhao,

Cunsheng Zhang

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 348, P. 127759 - 127759

Published: April 30, 2024

Language: Английский

Citations

21

Development of a feasible and scalable manufacturing method for PTFE-based solvent-free lithium-ion battery electrodes DOI Creative Commons
Hyeseong Oh,

Gyu-Sang Kim,

Byung Un Hwang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 491, P. 151957 - 151957

Published: May 6, 2024

Conventional wet-electrode manufacturing encounters challenges in producing thicker electrodes due to issues related solvent evaporation. This study introduces a novel method for fabricating solvent-free dry using polytetrafluoroethylene (PTFE) as binder, representing significant advancement electrode processes. By eliminating the use of solvents, this not only addresses these but also offers scalable and practical solution mass production. The process is meticulously structured into sequential unit operations, each specifically tailored distinct function, utilizing distinctive fibrillation properties PTFE. Intermediate product specifications phase are clearly defined, accompanied by comprehensive analysis both physical electrochemical performances. highlights influence varying PTFE contents on microstructure electrode. Notably, achieves breakthrough with an formulation NCM811/PTFE/carbon black (CB)/carbon nanotube (CNT) = 96/2.0/1.8/0.2, which demonstrates exceptional discharge rate capability 80 % at 0.5 C-rate (5 mA/cm2) under demanding parameters 10 mAh/cm2 3.8 g/cc. approach enhances microstructural paves way environmentally friendly efficient future energy storage applications.

Language: Английский

Citations

21

Multifunctional Janus-Structured Polytetrafluoroethylene-Carbon Nanotube-Fe3O4/MXene Membranes for Enhanced EMI Shielding and Thermal Management DOI Creative Commons

Runze Shao,

Guilong Wang, Jialong Chai

et al.

Nano-Micro Letters, Journal Year: 2025, Volume and Issue: 17(1)

Published: Feb. 6, 2025

Abstract Herein, a novel Janus-structured multifunctional membrane with integrated electromagnetic interference (EMI) shielding and personalized thermal management is fabricated using shear-induced in situ fibrillation vacuum-assisted filtration. Interestingly, within the polytetrafluoroethylene (PTFE)-carbon nanotube (CNT)-Fe 3 O 4 layer (FCFe), CNT nanofibers interweave PTFE fibers to form stable “silk-like” structure that effectively captures Fe particles. By incorporating highly conductive MXene layer, FCFe/MXene (FCFe/M) exhibits excellent electrical/thermal conductivity, mechanical properties, flame retardancy. Impressively, benefiting from rational regulation of component proportions design Janus structure, FCFe/M thickness only 84.9 µm delivers outstanding EMI effectiveness 44.56 dB X-band, normalized specific SE reaching 10,421.3 cm 2 g −1 , which attributed “absorption-reflection-reabsorption” mechanism. Furthermore, demonstrates low-voltage-driven Joule heating fast-response photothermal performance. Under stimulation V voltage an optical power density 320 mW −2 surface temperatures membranes can reach up 140.4 145.7 °C, respectively. In brief, anti-electromagnetic radiation temperature attractive candidate for next generation wearable electronics, compatibility, visual heating, thermotherapy, military aerospace applications.

Language: Английский

Citations

3

Low-pressure driving Co3O4/PAN nanofiber membrane with peroxymonosulfate activation self-cleaning for efficient wastewater purification DOI

Hengchao Liang,

Atian Xie,

Shihao Nie

et al.

Journal of Membrane Science, Journal Year: 2023, Volume and Issue: 693, P. 122380 - 122380

Published: Dec. 21, 2023

Language: Английский

Citations

35

A versatile MOF liquids-based Janus fibrous membrane towards complex oil/water separation and heavy metal ions removal DOI

Bingbing Cheng,

Xinming Fu, Yiheng Song

et al.

Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 331, P. 125701 - 125701

Published: Nov. 10, 2023

Language: Английский

Citations

31

High hydrophobic ZIF-8@cellulose nanofibers/chitosan double network aerogel for oil adsorbent and oil/water separation DOI

Rongrong Si,

Honggang Luo,

Tao Zhang

et al.

International Journal of Biological Macromolecules, Journal Year: 2023, Volume and Issue: 238, P. 124008 - 124008

Published: March 17, 2023

Language: Английский

Citations

30

Bio-inspired surface engineering of hydrophobic membranes with nano-structured hydrogel toward viscous oil-in-water emulsion separation DOI Open Access

Jinxuan Meng,

Jin Zhang, Xiang Shen

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 473, P. 145519 - 145519

Published: Aug. 18, 2023

Language: Английский

Citations

27

Superhydrophobic nanofibrous polytetrafluoroethylene and composite membranes with tunable adhesion for micro-droplet manipulation, self-cleaning and oil/water separation DOI
Jialong Chai, Guilong Wang, Aimin Zhang

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(2), P. 112355 - 112355

Published: March 4, 2024

Language: Английский

Citations

15

Engineering “fishnet-like” structure to boost the monovalent anion selectivity of anion exchange membranes for electrodialysis applied in organic solvent systems DOI
Junbin Liao, Yuanyuan Tang, Tongtong Wang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 485, P. 150076 - 150076

Published: Feb. 29, 2024

Language: Английский

Citations

11