Metal ion and organic ligand disubstituted bimetallic metal‒organic framework nanosheets for high-performance alkaline zinc-based batteries DOI
Huayu Wang, Jie Bai, Qingqing He

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(71), P. 9590 - 9593

Published: Jan. 1, 2024

Pristine MOF nanosheets with a highly active metal–sulfur (M–S, M = Co and Ni) region as cathodes for Zn–Co/Ni batteries are successfully prepared through dual substitution strategy of metal ions organic ligands.

Language: Английский

Recent Progresses of Aqueous Zinc‐Ion Batteries and Their Prospects in the Field of Smart City DOI
Pengyi Lu, Zhanxi Fan, Cong Guo

et al.

Advanced Sustainable Systems, Journal Year: 2024, Volume and Issue: 8(6)

Published: Jan. 17, 2024

Abstract Due to their excellent reliability, low cost, and environmental friendliness, aqueous Zn‐ion batteries (AZIBs) present a promising prospect for both mobile stationary energy storage smart devices cities. However, current challenges, such as anode dendrite growth, cathode dissolution, parasitic side reactions, hinder the practical application of AZIBs. This review first provides an in‐depth explanation mechanisms anodes cathodes. A comprehensive discussion typical issues with anode, cathode, electrolyte AZIBs is then presented. Furthermore, considerations potential applications in development flexible electronics are illustrated. Finally, challenges perspectives future highlighted. expected serve guidepost clean, sustainable, efficient management new urban forms.

Language: Английский

Citations

6
Two-dimensional/three-dimensional hierarchical self-supporting potassium ammonium vanadate@MXene hybrid film for superior performance aqueous zinc ion batteries DOI

Yufen Zhang,

Rongyu Guo,

Jinjin Wen

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 665, P. 838 - 845

Published: March 29, 2024

Language: Английский

Citations

6
Supercapacitive performance of electrodes based on defective ZnO nanorods anchored on graphene nanowalls DOI Creative Commons
Yang Ma, Stefanos Chaitoglou, Ghulam Farid

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 488, P. 151135 - 151135

Published: April 8, 2024

Vertical graphene nanowalls (GNWs) have emerged as a highly promising architectural structure, offering vast surface area teeming with active sites and expediting ion diffusion. In our relentless pursuit of bolstering their specific capacitance, we unveil groundbreaking supercapacitive augmentation, incorporating defect-engineered ZnO nanorods (ZNRs) branching out from the GNWs. The realization this hierarchical structure is achieved through meticulous multi-step process, featuring inductively coupled plasma-chemical vapor deposition, magnetron sputtering, hydrothermal synthesis. presence oxygen vacancy (OV) defects within ZNRs, induced by argon annealing, has been characterized using X-ray photoelectron spectroscopy (XPS). emergence OV below conduction band ZNRs results in narrowing bandgap hybrid thereby enhancing its conductivity increasing reaction sites. capacity ZNRs/GNWs electrodes were evaluated an aqueous KOH electrolyte solution, operating voltage range 0.5 V at current density 0.1 mA cm−2. This assessment yielded capacitance 21.45 mF cm−2, signifying 1.5-fold increase compared to GNWs grown on graphite sheets. demonstrates remarkable electrochemical performance exhibits substantial potential for energy storage applications. Our work expected offer valuable insights enhancement properties various composite materials.

Language: Английский

Citations

5
Rational synthesis of 3D coral-like ZnCo2O4 nanoclusters with abundant oxygen vacancies for high-performance supercapacitors DOI Creative Commons

Yanlei Bi,

Huiqing Fan,

Chuansen Hu

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(17), P. 11734 - 11745

Published: Jan. 1, 2024

Transition metal oxides with high theoretical capacitance are regarded as desired electrode materials for supercapacitors, however, the poor conductivity and sluggish charge transfer kinetics constrain their electrochemical performance.

Language: Английский

Citations

5
Synergetic Effect of Mo‐Doped and Oxygen Vacancies Endows Vanadium Oxide with High‐Rate and Long‐Life for Aqueous Zinc Ion Battery DOI Creative Commons
Daming Chen, Ming Yang,

Yang Ming

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 5, 2024

Abstract Vanadium (V)‐based oxides have garnered significant attention as cathode materials for aqueous zinc‐ion batteries (AZIBs) due to their multiple valences and high theoretical capacity. However, sluggish kinetics low conductivity remain major obstacles practical applications. In this study, Mo‐doped V 2 O 3 with oxygen vacancies (OVs, Mo‐V 3‐x @NC) is prepared from a V‐metal organic framework. Ex situ characterizations reveal that the undergoes an irreversible phase transformation 5‐x ·nH serves active material exhibiting excellent Zn 2+ storage in subsequent charge‐discharge cycles. helps further improve cycling stability increases increasing content. More importantly, synergistic effect of OVs not only effectively reduces migration energy barrier, but also enhances reaction kinetics, electrochemical performance. Consequently, demonstrates ultrafast showing superior rate performance (190.9 mAh g −1 at 20 A ) long‐term (147.9 after 10000 cycles). Furthermore, assembled pouch cell exhibits (313.6 1 1000 cycles), indicating promising application prospects. This work presents effective strategy designing fabricating metal co‐doped cathodes high‐performance AZIBs.

Language: Английский

Citations

5
Fe2O3/Fe/Fe-N multidimensional cross-linked composite enhancing oxygen reduction reaction of al-air batteries: Oxygen vacancies and bandgap engineering DOI
Xiaoqi Zhao, Yingxiao Li, Xue Zhang

et al.

Applied Surface Science, Journal Year: 2023, Volume and Issue: 638, P. 158050 - 158050

Published: July 16, 2023

Language: Английский

Citations

11
Recent advances of vanadium-based cathodes toward aqueous Zn-ion batteries DOI Creative Commons
Yuyan Wang, Huaqing Chen,

Shujia Zhang

et al.

Next Energy, Journal Year: 2024, Volume and Issue: 4, P. 100119 - 100119

Published: May 21, 2024

Benefiting from the advantageous features of low manufacturing cost, inherent safety and resource renewability, aqueous Zn-ion batteries (AZIBs) are considered as one most promising candidates for energy storage systems. Unfortunately, problems AZIBs such cathode dissolution, Zn dendrite growth, irreversible electrochemical side reactions have restricted implementation practical applications. Vanadium-based deemed hopeful materials owing to diverse crystal structures multiple valence states. Therefore, it is necessary comprehensively summarize advance facing vanadium-based cathodes corresponding progress create roadmaps development high-stability AZIBs. This review starts with a discussion failure mechanisms their related affects. Then, enormous up-to-date achievements highlighted, including oxides metal oxides. The challenges associated application compounds in also effective strategies overcome them proposed. Finally, perspectives directions on further optimizing improve performance discussed.

Language: Английский

Citations

4
Zeolitic Imidazolate Framework-67-Derived Co3O4/α-MnO2 Composite as an Efficient Cathode for Aqueous Zinc-Ion Batteries DOI

Abhas Anand,

Ram Dixit, Anil Verma

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(14), P. 13365 - 13378

Published: July 1, 2024

Language: Английский

Citations

4
Advances in Transition Metal Oxide Cathodes for Zinc-Ion Batteries - A Review Focusing on Safety and Toxicity DOI Creative Commons

Suben Sri Shiam,

J.K. Rath, Amirkianoosh Kiani

et al.

International Journal of Electrochemical Science, Journal Year: 2024, Volume and Issue: unknown, P. 100804 - 100804

Published: Sept. 1, 2024

Language: Английский

Citations

4
Construction of high-voltage aqueous Zn-MnO2 batteries based on polar small-molecule organic acid-induced MnO2/Mn2+ reactions DOI
Ying Li, Nan Zhang,

Jingyu Wang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160415 - 160415

Published: Feb. 1, 2025

Language: Английский

Citations

0