Chemistry - An Asian Journal,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 31, 2024
The
reusable
and
separable
surface
frustrated
Lewis
pairs
(SFLPs)
open
up
a
novel
approach
to
efficient
small-molecule
activation
conversion
in
heterogeneous
catalysis.
However,
SFLPs
have
only
been
reported
on
limited
systems
due
the
difficulty
design
synthesis
process.
inherent
various
solid
materials
offer
promising
opportunities
for
finding
natural
SFLPs,
providing
straightforward
strategy
overcome
current
limitations.
In
this
concept,
we
retrospect
concept
of
proposed
wurtzite
crystal
surfaces
identify
other
that
probably
exist
materials,
including
reduced
oxide
surfaces,
corrugated
graphene,
perovskite
quantum
dots.
Having
focused
reactivity
activation,
discuss
challenges,
propose
possible
research
directions,
highlight
potential
applications
Nature Communications,
Journal Year:
2025,
Volume and Issue:
16(1)
Published: Jan. 3, 2025
High-entropy
metal-organic
frameworks
(HE-MOFs)
hold
promise
as
versatile
materials,
yet
current
rare
examples
are
confined
to
low-valence
elements
in
the
fourth
period,
constraining
their
design
and
optimization
for
diverse
applications.
Here,
a
novel
high-entropy,
defect-rich
small-sized
(32
nm)
UiO-66
(ZrHfCeSnTi
HE-UiO-66)
has
been
synthesized
first
time,
leveraging
increased
configurational
entropy
achieve
high
tolerance
doping
with
metal
ions.
The
lattice
distortion
of
HE-UiO-66
induces
exposure
nodes
create
coordination
unsaturated
sites
concentration
322.4
μmol/g,
which
increases
abundance
Lewis
acid-base
sites,
thereby
achieving
significant
improvement
performance
catalytic
transfer
hydrogenation
(CTH)
reaction.
Systematic
investigation
manifests
that
special
electronic
structure
enhances
interaction
bonding
substrate
molecules
reduces
energy
barrier
hydrogen
process.
Our
approach
offers
new
strategy
constructing
MOFs.
offer
potential
but
existing
largely
limited
restricting
various
defect-rich,
framework
enhance
hydrogenation.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(13), P. 7470 - 7507
Published: Jan. 1, 2024
Various
types
of
catalysts
for
the
catalytic
combustion
light
hydrocarbon
VOCs
and
their
superiority
deficiency
are
described
in
detail.
Meanwhile,
reaction
mechanisms
structure–activity
relationships
illustrated
intensively.
Chemical Communications,
Journal Year:
2023,
Volume and Issue:
59(91), P. 13535 - 13550
Published: Jan. 1, 2023
This
review
focuses
on
emerging
high-entropy-oxide-based
anodes
for
LIBs,
summarizing
synthesis
routes,
discussing
the
structural
evolution
and
lithium
storage
mechanism,
detailing
strategies
improving
electrochemical
performance.
The Journal of Physical Chemistry Letters,
Journal Year:
2024,
Volume and Issue:
15(20), P. 5436 - 5444
Published: May 14, 2024
The
excellent
reactivity
of
frustrated
Lewis
pairs
(FLP)
to
activate
small
molecules
has
gained
increasing
attention
in
recent
decades.
Though
the
development
surface
FLP
(SFLP)
is
prompting
application
chemical
industry,
design
SFLP
with
superior
activity,
high
density,
and
stability
for
small-molecule
activation
still
challenging.
Herein,
we
review
progress
designing
by
engineering,
screening
natural
SFLP,
dynamic
formation
from
theoretical
perspectives.
We
highlight
breakthrough
fine-tuning
designed
studied
using
computational
methods.
also
discuss
future
challenges
directions
outstanding
capabilities
activation.
