Research progress of high-entropy cathode materials for sodium-ion batteries DOI
Fan Wu, Shaoyang Wu, Xin Ye

et al.

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 109851 - 109851

Published: April 1, 2024

Language: Английский

The emerging high-entropy strategy: a booster to the development of cathode materials for power batteries DOI Creative Commons
Liping Huang, Jingting Zhu, Ji‐Xuan Liu

et al.

Journal of Advanced Ceramics, Journal Year: 2024, Volume and Issue: 13(8), P. 1093 - 1118

Published: May 24, 2024

The coordinated development of new energy vehicles and the storage industry has become inevitable to reduce carbon emissions. cathode material is key that determines density cost a power battery, while currently developed applied can not meet requirements high specific capacity, low cost, safety good stability. High-entropy type single-phase composed multiple principal elements in equimolar or near-equimolar ratios. interaction between play an important role improving comprehensive properties material, which expected solve limitations battery materials practical applications. Based on this, this review provides overview current status modification strategies batteries (lithium-ion sodium-ion battery), proposes high-entropy design strategy, analyzes structure-activity relationship effect performance. Finally, future research topics are proposed, including computational guide design, synthesis methods, electrochemistry high-throughput databases. This aims provide guidance for next-generation batteries.

Language: Английский

Citations

13

The emerging high-entropy cathode materials for advanced Na-ion batteries: advances and perspectives DOI
Peiyu Hou, Maosheng Gong,

Mohan Dong

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 72, P. 103750 - 103750

Published: Aug. 26, 2024

Language: Английский

Citations

12

Emerging high‐entropy material electrodes for metal‐ion batteries DOI Creative Commons

Jianyu Shen,

Zhen Zeng,

Weihua Tang

et al.

SusMat, Journal Year: 2024, Volume and Issue: 4(4)

Published: May 30, 2024

Abstract High‐entropy materials (HEMs) have recently attracted extensive research interest. Featuring unique structural characteristics and excellent mechanical/chemical properties, HEMs (especially high‐entropy alloys oxides) emerge as promising electrode for electrochemical energy storage. We herein present a critical review to update the recent progress in developing new electrodes various metal‐ion batteries. Their design principle is discussed along with preparation, characterization, performance materials. The current state‐of‐the‐art HEM presented, covering good capacity, rate long‐term cycle stability ion By addressing both success challenges associated development, this contributes efforts toward achieving higher capacity more stable

Language: Английский

Citations

11

Mn vacancy engineering design of Fe/Mn based cathodes for breaking the spell between “sodium limiting” in air-stabilization and “sodium promoting” on kinetics DOI
Rui Huang, Shaohua Luo, Qi Sun

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 499, P. 156599 - 156599

Published: Oct. 10, 2024

Language: Английский

Citations

10

Improving upon rechargeable battery technologies: On the role of high-entropy effects DOI
Zihao Zhou, Yuan Ma, Torsten Brezesinski

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

An overview of high-entropy strategies for batteries is provided, emphasizing their unique structural/compositional attributes and positive effects on stability performance, alongside a discussion key challenges future research directions.

Language: Английский

Citations

9

High entropy stabilized O3-type NaNi0.3Fe0.2Mn0.2Ti0.15Sn0.15O2 cathode material for sodium-ion batteries DOI
Liping Huang, Jingting Zhu, Ji‐Xuan Liu

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160309 - 160309

Published: Feb. 1, 2025

Language: Английский

Citations

1

Revealing Microstructure and Mechanism of Layered Oxide Cathodes for Sodium-ion Batteries by Advanced TEM Techniques DOI Creative Commons
Sheng Xu,

Lihua Zhao,

Shukui Li

et al.

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This review provides insight into the TEM applications for studying layered oxides SIBs, and broadens their potential future advancements.

Language: Английский

Citations

1

Solid-Solution Reaction and Ultrasmall Volume Change in High-Entropy P2-type Layered Oxide Cathode for All-Climate Sodium-Ion Batteries DOI
Jiang Yang, Wenhui Li, Kun Luo

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(21), P. 8051 - 8060

Published: May 10, 2024

P2-type layered oxide materials have attracted considerable interest because of their high safety and low cost. However, suffer from complicated Na+/vacancy ordering undesirable phase transitions, resulting in staircase-like electrochemical curves accompanied by fast capacity fading poor rate performance. A cathode material with high-entropy cation configurations, Na0.85Li0.08Mg0.04Ni0.22Al(B)0.04Mn0.62O2 (HEO), is designed successfully synthesized this work. The presence various metal ions the transition layers imposes an influence on arrangement alkali layers, as evidenced change interlayer distance associated electrostatic repulsion. HEO exhibits a smooth process without obvious voltage plateaus within 2.0–4.3 V delivers reversible 115 mA h g–1. Structural characterizations indicate that undergoes complete solid–solution reaction transitions over whole range, which facilitates ultrasmall volume variation (0.6%) Na+ ion diffusion (10–9 cm2 s–1) process. therefore shows excellent performances performance (91 g–1 at current density 480 g–1) retention wide temperature range −45 to 55 °C (after 100 cycles, batteries show 80% °C, 87% room temperature, 92% °C). results described work demonstrate method inhibit profiles induced either or P–O useful strategy for enhancing all-climate sodium-ion batteries.

Language: Английский

Citations

8

High entropy induced lattice expansion in layered oxide cathode towards fast sodium storage DOI
Ziming Wang, Hao Chen,

Qi Zhao

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 71, P. 103617 - 103617

Published: July 1, 2024

Language: Английский

Citations

8

High-entropy materials for sodium-ion batteries DOI Creative Commons

Greeshma Caroline,

Neeraja Nair, Shantikumar V. Nair

et al.

Next Sustainability, Journal Year: 2024, Volume and Issue: 4, P. 100044 - 100044

Published: Jan. 1, 2024

The high-entropy concept is receiving attention as an advanced design strategy to functionalize material properties by tuning the disorderliness of system. High-entropy materials have garnered significant recognition in realm energy storage due their versatile and diverse properties. In recent times, there has been active exploration traditional positive electrodes sodium-ion batteries. Nevertheless, under profound sodiated conditions, these tend exhibit sluggish kinetics unfavourable phase transitions, leading capacity degradation subpar rate capability. concepts successfully tune configurational entropy adjusting stoichiometric balance active/inactive cations address drawbacks. developments research progress on for batteries are reviewed this article, with a focus advantages modulation improving electrochemical performances. aspects cathode well key challenges finally outlined realize practical

Language: Английский

Citations

7