Ligand-Functionalized Organometallic Polyoxometalate as an Efficient Catalyst Precursor for Amide Hydrogenation DOI Creative Commons
Shun Hayashi, Koichi Momma, Kiyohiro Adachi

et al.

ACS Organic & Inorganic Au, Journal Year: 2024, Volume and Issue: 4(6), P. 705 - 711

Published: Nov. 19, 2024

Amide hydrogenation is an important process for producing amines, with the development of efficient heterogeneous catalysts relying on creation bimetallic active sites where two components interact synergistically. In this study, we develop a method preparing using ligand-functionalized organometallic polyoxometalates by synthesizing Rh-Mo polyoxometalate, [(RhCp

Language: Английский

Cooperative effects between NiMo alloy enable highly efficient for all-pH-value and alkaline seawater hydrogen evolution DOI

Lingxuan Meng,

Shuangyan Shang,

Suyi Liu

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 358, P. 124388 - 124388

Published: July 9, 2024

Language: Английский

Citations

11
Bimetallic nickel molybdenum nitride catalyst with low pressure and reduced hydrogen consumption for hydrogenation of dimethyl oxalate to ethanol: the impact of reduction temperature on catalytic performance DOI

Gong Jiang,

Hanqing Zhang, Weihan Shu

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(10), P. 5966 - 5976

Published: Jan. 1, 2024

The bimetallic nickel molybdenum nitride (Ni 3 Mo N) catalyst exhibits exceptional performance with a high EtOH yield (>97.5%) under low pressure (0.5 MPa) and minimal hydrogen consumption (H 2 /DMO (mol)) conditions.

Language: Английский

Citations

8
Eco-friendly and large-scale fabrication of NiMoN/Ni(OH)2/NF as highly efficient and stable alkaline hydrogen evolution reaction electrode DOI
Mengyao Xue,

Yuankang Bao,

Xun Xu

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 82, P. 655 - 661

Published: Aug. 3, 2024

Language: Английский

Citations

4
Unlocking algae biomass-derived amines, amides and nitriles: Mechanisms and (micro)kinetics during catalytic reactions DOI Creative Commons
Rok Pogorevc, Brigita Hočevar, Miha Grilc

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159527 - 159527

Published: Jan. 1, 2025

Language: Английский

Citations

0
Targeted Conversion of Biomass into Primary Diamines via Carbon Shell-Confined Cobalt Nanoparticles DOI
Yan Chen,

Siheng Yang,

Jingyu Wang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 30, 2025

Primary diamines are valuable yet challenging to synthesize due issues such as product and intermediate condensation catalyst poisoning. To address these problems, effective synthesis systems must be explored. Here, 2,5-bis(aminomethyl)furan (BAMF), a biomass-derived primary diamine, is chosen the model for constructing system. A series of carbon-shell confined Co nanoparticles (Co@CNT-x) fabricated BAMF. The Co@CNT-700 catalyst, with ca. 4 layers carbon shells, achieves an outstanding 96% isolated yield BAMF through reductive amination 2,5-diformylfuran dioxime. In this system, excess NH3 atmosphere necessary prevent reactions by competitive reactions, while shells protect from amine Control experiments indicate that dioxime primarily follows H2-assisted dehydration pathway form key imine intermediates, side products amides nitriles can also eventually converted into Co@CNT-700, leading its excellent selectivity. Notably, employing sequential three-step strategy, 87% achieved directly using biomass raw material. evaluate tolerance 9 other important aromatic, cycloalkyl, linear alkyl diamines, 1,4-cyclohexanediamine, obtained in high yields 87-99%.

Language: Английский

Citations

0
Ni-Mo Alloy Anchored on Carbon Nitride Coated Γ-Al2o3 for Hydrodeoxygenation of Lignin-Derived Phenols into Aviation Fuel-Range Cycloalkanes DOI
Zifan Wu, Lu Chen,

Yacong Deng

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0
Catalytic hydrodenitrogenation, hydrodeoxygenation and hydrogenation reactions of amides, amines, and nitriles over NiMoSX/Al2O3 catalysts: Mechanisms, kinetics and transport DOI Creative Commons

Matej Žula,

Vid Bačar,

Michal Mazur

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162112 - 162112

Published: March 1, 2025

Language: Английский

Citations

0
Unveiling the Roles of Pt and CeO2 during Solvent-Free Amide Hydrogenation Utilizing Operando Photoelectron Photoionization Coincidence Spectroscopy DOI Creative Commons
Xinbang Wu, Rosie J. Somerville, András Bödi

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: 15(8), P. 6216 - 6225

Published: April 2, 2025

The hydrogenation of amides to amines is an important reaction in the synthesis building blocks organic chemistry. However, solvent-free (requiring heterogeneous catalysts and high temperatures) challenging, with low selectivity obtained due further hydrogenolysis alcohol amine products. Such behavior was observed for a CeO2-supported Pt catalyst (Pt/CeO2). Although it known that support promotes adsorption amide on catalyst, facilitates hydrogenation, their individual roles conversion how they impact product remain unclear. Using operando photoelectron photoionization coincidence (PEPICO) spectroscopy, N-ethylpropionamide studied over both Pt/CeO2 CeO2. experiments reveal active below 150 °C produce selectivity. Lewis acidic (CeO2) also at higher temperatures, producing ethylamine propanal, while being vulnerable coking. nanoparticles mitigate coke formation, catalyze products above °C. This study provides insights bifunctional metal oxide--metal nanoparticle facilitate design superior catalysts.

Language: Английский

Citations

0
Hydrogenation of amides to amines by heterogeneous catalysis: A review DOI
Huiru Yang, Hermenegildo Garcı́a, Changwei Hu

et al.

Green Chemistry, Journal Year: 2023, Volume and Issue: 26(5), P. 2341 - 2364

Published: Dec. 16, 2023

A comprehensive summary of heterogeneous catalysts for the hydrogention various amides with differnent structural feactures to amines.

Language: Английский

Citations

7
Heterogeneous Catalytic Hydrogenation DOI
Bilal Nişancı, Bagher Eftekhari‐Sis, Maryam Zirak

et al.

Elsevier eBooks, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Language: Английский

Citations

1