Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: 183, P. 106741 - 106741
Published: Sept. 6, 2024
Language: Английский
Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: 183, P. 106741 - 106741
Published: Sept. 6, 2024
Language: Английский
Fuel, Journal Year: 2024, Volume and Issue: 379, P. 132893 - 132893
Published: Sept. 4, 2024
Language: Английский
Citations
3Environmental Chemistry Letters, Journal Year: 2024, Volume and Issue: 22(4), P. 1741 - 1758
Published: May 2, 2024
Language: Английский
Citations
2Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: 181, P. 106643 - 106643
Published: July 22, 2024
Understanding the mechanisms governing coal pyrolysis reactions, particularly in relation to macromolecular structure, is crucial for improving energy efficiency and facilitating transition of into a clean source. This study employs cutting-edge techniques, such as High-Resolution Transmission Electron Microscopy (HRTEM) Thermogravimetric Analysis coupled with Fourier Transform Infrared Spectroscopy Mass Spectrometry (TG–FTIR–MS), analyze lignite its residual solid samples subjected across range temperatures from 300 °C 1100 °C. The variational characteristics structure during are examined. Utilizing molecular dynamics simulations, we evolution mechanism carbon organic matter process. results show that can be divided three distinct phases: activation (30–300 °C), (300–650 condensation (650–1200 °C). During these phases, undergoes complex transformations, including folding, twisting, shedding small side chains, breaking ultimately leading directional arrangement structural fragments. units initially undergo decomposition, followed by growth alignment certain direction. spatial distribution aromatic evolves local ordering complete disordering, culminating larger-scale, three-dimensional ordering. order bond within is: oxygen-containing functional groups (such C–O COOH) > aliphatic (N–C C–C) (CC). By uncovering reaction intermediates pathways involved pyrolysis, this research provides comprehensive quantitative description These insights offer invaluable theoretical support industrial-scale coal, paving way more efficient sustainable utilization resource.
Language: Английский
Citations
2Materials Today Communications, Journal Year: 2024, Volume and Issue: 39, P. 108982 - 108982
Published: April 21, 2024
Language: Английский
Citations
2Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: 183, P. 106741 - 106741
Published: Sept. 6, 2024
Language: Английский
Citations
2