Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Proceedings of the National Academy of Sciences, Journal Year: 2024, Volume and Issue: 121(11)
Published: March 5, 2024
Heterogeneous high-valent cobalt-oxo [≡Co(IV)=O] is a widely focused reactive species in oxidant activation; however, the relationship between catalyst interfacial defects and ≡Co(IV)=O formation remains poorly understood. Herein, photoexcited oxygen vacancies (OVs) were introduced into Co 3 O 4 (OV-Co ) by UV-induced modification method to facilitate chlorite (ClO 2 – activation. Density functional theory calculations indicate that OVs result low-coordinated atom, which can directionally anchor under oxygen-atom trapping effect. Chlorite first undergoes homolytic O–Cl cleavage transfers dissociated atom form with higher spin state. The rapidly extracts one electron from ClO chlorine dioxide ), accompanied returning lower As of effect, OV-Co /chlorite system achieved 3.5 times efficiency sulfamethoxazole degradation (~0.1331 min −1 than pristine system. Besides, refiled be easily restored re-exposure UV light, indicating sustainability trap. was further fabricated on polyacrylonitrile membrane for back-end water purification, achieving continuous flow pollutants low cobalt leakage. This work presents an enhancement strategy constructing OV as site heterogeneous advanced oxidation processes provides insight modulating via defect engineering.
Language: Английский
Citations
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Language: Английский
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Language: Английский
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0