The Long Persistent Luminescence Triggered by Photo-Induced Charge-Separation for Information Encryption in Liquid State DOI
Wenying Shi,

Liping Guan,

Yuntao He

et al.

Optics Letters, Journal Year: 2024, Volume and Issue: 49(21), P. 6065 - 6065

Published: Sept. 16, 2024

The long persistent luminescence (LPL) phenomenon in the water environment presents us with a broad blueprint to struggle for new generation of optical materials. However, realization water-resistant LPL remains formidable challenge due severe quenching triplet excitons inflowing media. Here, an electron donor-acceptor system is designed based on B

Language: Английский

Recent and Prospects of Synthesis and Application of Metal-Organic Frameworks (MOFs) in Water Treatment: A Review DOI Creative Commons
Sarah Constance Motshekga, Opeyemi A. Oyewo, Seshibe Makgato

et al.

Journal of Inorganic and Organometallic Polymers and Materials, Journal Year: 2024, Volume and Issue: 34(9), P. 3907 - 3930

Published: May 8, 2024

Abstract Wastewater treatment is designed to eradicate toxic pollutants emanating from the industrial effluent surface and underground water. The efficiency limitations of most existing water techniques such as coagulation/flocculation, photocatalysis, membrane technologies adsorption in remediation have been established. However, success reported for each these usually associated with environmental friendliness products applied. MOFs-based are one materials serving an alternative chemically synthesized products, their application has extensively but not systematically documented. In this review, authors endeavoured comprehensively provide insights into recent product synthesis different applications, especially treatment. key factors influencing MOFs, including choice metal ions, organic linkers, conditions, along latest developments scalable cost-effective fabrication discussed. routes, limitation performances adsorbent, photocatalyst additives removal elaborated. prospects large-scale production real applications critically reviewed study. Overall, a well-curated MOFs hereby generated best resources accessible through literature.

Language: Английский

Citations

18

Tuning triplet excitons and dynamic afterglow based on host-guest doping DOI

Yuchen Hong,

Yupeng Zhao, Lei Ma

et al.

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Journal Year: 2024, Volume and Issue: 324, P. 124955 - 124955

Published: Aug. 23, 2024

Language: Английский

Citations

7

Host–guest Metal–Organic Frameworks-Based Long-Afterglow Luminescence Materials DOI Creative Commons
Zhichen Zhang, Zhi‐Gang Gu, Jian Zhang

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(13), P. 2989 - 2989

Published: June 23, 2024

Long-afterglow materials have a broad of applications in optoelectronic devices, sensors, medicine and other fields due to their excellent luminescent properties. The host-guest long-afterglow MOFs material combines the advantages multi-component characteristics stability MOFs, which improves its luminous performance expands This review introduces classification, synthesis application with long afterglow. Due rigid frames multi-channel characteristics, can load common guest including rare earth metals, organic dyes, carbon dots, etc. methods loading into include solvothermal synthesis, post-encapsulation, post-modification, Those wide range information security biological imaging.

Language: Английский

Citations

4

Biobased Self-healable Photoluminescent Polyacylhydrazones Imparted by Supramolecular Interactions DOI

Mingze Xia,

Yi Cheng,

Jingzhao Shang

et al.

Macromolecules, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 13, 2025

With the rise of circular economy, self-healing polymers have attracted significant attention for their longer lifespan and greater recyclability compared with traditional thermoplastics thermosetting polymers. However, addressing instability units to develop high-performance materials remains a challenge. Herein, we report series superior polyimine derivatives, biobased polyacylhydrazones (bio-PHys), via aldehyde-hydrazide condensation. The coexistence amide bonds imine bonds, which provide hydrogen bonding dynamics, imparts remarkable mechanical properties (tensile strength 103 MPa, elongation at break 180%) bio-PHys, along notable capabilities under glass transition temperature (Tg). Bio-PHys also exhibits potential scalable production, excellent processability, photoluminescence characteristics. We explored its application in adhesive-free laminated substrates thoroughly investigated aggregation-induced emission acylhydrazone group. Furthermore, utilized bio-PHys create recyclable smart paper anticounterfeiting dynamic information storage. This work presents novel approach developing

Language: Английский

Citations

0

Li, Na, and Cs-based metal-organic frameworks for room temperature phosphorescence applications DOI
Jiaqi Ma, Rui Feng,

Yanyuan Jia

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 7, 2025

Language: Английский

Citations

0

Multicolor Long-Persistent Luminescence with High Phosphorescence Quantum Yield and Long Lifetime in Ultrahigh Elastic Fibers DOI
Xiaoyan Wang, Zheng Zhang, Shuangqiao Yang

et al.

ACS Materials Letters, Journal Year: 2025, Volume and Issue: unknown, P. 928 - 937

Published: Feb. 10, 2025

Language: Английский

Citations

0

Light driven CsPbI3 perovskite quantum dots core-shell transformation for Snapchat type anti-counterfeiting and encryption in 4D codes DOI
Yaxin Zhou, Liming Chen, Peng Zhang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160847 - 160847

Published: Feb. 1, 2025

Language: Английский

Citations

0

Engineering Solvent‐Coordinated Heterometallic–Organic Frameworks for Wide‐Range Tuning of Ultralong Room Temperature Phosphorescence toward Time‐Resolved Anticounterfeiting DOI Open Access

Juanjuan Xue,

Zhenhong Qi, Dongpeng Yan

et al.

Angewandte Chemie International Edition, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Metal-organic frameworks (MOFs) have been proven promising ultralong room temperature phosphorescence (RTP) materials for anti-counterfeit due to their unique optical properties. However, it remains a major challenge achieve the desired phosphorescent properties limited regulatory methods and indistinct mechanism. Herein, coordination solvent second metal ion co-strategy is firstly proposed prepare seven robust heterometallic-organic (HMOFs) with two configurations: ZnMg/Ca-sol [sol = H2O, dimethylformamide (DMF), dimethylacetamide (DMA), formyldiethylamine (DEF)] ZnSr/Ba-H2O, exhibiting different RTP. The tunable lifetimes within 14.5-195.4 ms are achieved gradually by altering type of alkaline earth metals, solvent, hydrogen-bonding in HMOFs. Significantly, theoretical calculations reveal that promotion spin-orbit coupling heavy metals rigid constraint on skeleton result excellent balance between high quantum yield (ФP) long lifetime, especially ZnSr-H2O (6.8%, 195.4 ms). Depending wide-range tuning RTP great stability, HMOFs successfully applied spatial-time resolved anti-counterfeiting multi-level information encryption. This work may provide new approach designing target while resolving contradiction ФP lifetime.

Language: Английский

Citations

0

Engineering Solvent‐Coordinated Heterometallic–Organic Frameworks for Wide‐Range Tuning of Ultralong Room Temperature Phosphorescence toward Time‐Resolved Anticounterfeiting DOI Open Access

Juanjuan Xue,

Zhenhong Qi, Dongpeng Yan

et al.

Angewandte Chemie, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Abstract Metal–organic frameworks (MOFs) have been proven promising ultralong room temperature phosphorescence (RTP) materials for anticounterfeit due to their unique optical properties. However, it remains a major challenge achieve the desired phosphorescent properties limited regulatory methods and indistinct mechanism. Herein, coordination solvent second metal ion costrategy is firstly proposed prepare seven robust heterometallic–organic (HMOFs) with two configurations, ZnMg/Ca‐sol [sol = H 2 O, dimethylformamide (DMF), dimethylacetamide (DMA), formyldiethylamine (DEF)] ZnSr/Ba‐H O , exhibiting different RTP. The tunable lifetimes within 14.5–195.4 ms are achieved gradually by altering type of alkaline earth metals, solvent, hydrogen‐bonding in HMOFs. Significantly, theoretical calculations reveal that promotion spin–orbit coupling heavy metals rigid constraint on skeleton result excellent balance between high quantum yield ( Ф P ) long lifetime, especially ZnSr‐H (6.8%, 195.4 ms). Depending wide‐range tuning RTP great stability, HMOFs successfully applied spatial‐time resolved anticounterfeiting multilevel information encryption. This work may provide new approach designing target while resolving contradiction lifetime.

Language: Английский

Citations

0

Unveiling the Dynamics of Frenkel Defects in Fluoride Materials for X‐Ray‐Induced Persistent Luminescence and Advanced Imaging Applications DOI Open Access
Ming‐Xing Li, Wenwu You,

Shuanglai Liu

et al.

Laser & Photonics Review, Journal Year: 2025, Volume and Issue: unknown

Published: March 11, 2025

Abstract The persistent luminescence (PersL) induced by X‐rays in fluoride materials has garnered widespread application within the field of optoelectronics. However, complexity trap systems multi‐component impeded further exploration into PersL properties. Here, a compound consisting solely and lanthanide ions is focused on, which simplifies revelation mechanism under X‐ray excitation. Experimental theoretical results reveal that phenomenon primarily attributed to migration recovery processes interstitial lattice. Depending on localization ions, corresponding Frenkel defects can be classified two distinct types: those are readily self‐recoverable near matrix less likely self‐recover dopant ions. anomalous phenomena observed at temperatures do not correspond thermoluminescence spectra substantiate existence these dynamic traps. Furthermore, leveraging material's superior properties, scintillator film prepared utilized for imaging static displays. These findings provide refined understanding related defects, laying solid foundation continued development technology.

Language: Английский

Citations

0