Optics Letters,
Journal Year:
2024,
Volume and Issue:
49(21), P. 6065 - 6065
Published: Sept. 16, 2024
The
long
persistent
luminescence
(LPL)
phenomenon
in
the
water
environment
presents
us
with
a
broad
blueprint
to
struggle
for
new
generation
of
optical
materials.
However,
realization
water-resistant
LPL
remains
formidable
challenge
due
severe
quenching
triplet
excitons
inflowing
media.
Here,
an
electron
donor-acceptor
system
is
designed
based
on
B
Journal of Inorganic and Organometallic Polymers and Materials,
Journal Year:
2024,
Volume and Issue:
34(9), P. 3907 - 3930
Published: May 8, 2024
Abstract
Wastewater
treatment
is
designed
to
eradicate
toxic
pollutants
emanating
from
the
industrial
effluent
surface
and
underground
water.
The
efficiency
limitations
of
most
existing
water
techniques
such
as
coagulation/flocculation,
photocatalysis,
membrane
technologies
adsorption
in
remediation
have
been
established.
However,
success
reported
for
each
these
usually
associated
with
environmental
friendliness
products
applied.
MOFs-based
are
one
materials
serving
an
alternative
chemically
synthesized
products,
their
application
has
extensively
but
not
systematically
documented.
In
this
review,
authors
endeavoured
comprehensively
provide
insights
into
recent
product
synthesis
different
applications,
especially
treatment.
key
factors
influencing
MOFs,
including
choice
metal
ions,
organic
linkers,
conditions,
along
latest
developments
scalable
cost-effective
fabrication
discussed.
routes,
limitation
performances
adsorbent,
photocatalyst
additives
removal
elaborated.
prospects
large-scale
production
real
applications
critically
reviewed
study.
Overall,
a
well-curated
MOFs
hereby
generated
best
resources
accessible
through
literature.
Molecules,
Journal Year:
2024,
Volume and Issue:
29(13), P. 2989 - 2989
Published: June 23, 2024
Long-afterglow
materials
have
a
broad
of
applications
in
optoelectronic
devices,
sensors,
medicine
and
other
fields
due
to
their
excellent
luminescent
properties.
The
host-guest
long-afterglow
MOFs
material
combines
the
advantages
multi-component
characteristics
stability
MOFs,
which
improves
its
luminous
performance
expands
This
review
introduces
classification,
synthesis
application
with
long
afterglow.
Due
rigid
frames
multi-channel
characteristics,
can
load
common
guest
including
rare
earth
metals,
organic
dyes,
carbon
dots,
etc.
methods
loading
into
include
solvothermal
synthesis,
post-encapsulation,
post-modification,
Those
wide
range
information
security
biological
imaging.
Macromolecules,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 13, 2025
With
the
rise
of
circular
economy,
self-healing
polymers
have
attracted
significant
attention
for
their
longer
lifespan
and
greater
recyclability
compared
with
traditional
thermoplastics
thermosetting
polymers.
However,
addressing
instability
units
to
develop
high-performance
materials
remains
a
challenge.
Herein,
we
report
series
superior
polyimine
derivatives,
biobased
polyacylhydrazones
(bio-PHys),
via
aldehyde-hydrazide
condensation.
The
coexistence
amide
bonds
imine
bonds,
which
provide
hydrogen
bonding
dynamics,
imparts
remarkable
mechanical
properties
(tensile
strength
103
MPa,
elongation
at
break
180%)
bio-PHys,
along
notable
capabilities
under
glass
transition
temperature
(Tg).
Bio-PHys
also
exhibits
potential
scalable
production,
excellent
processability,
photoluminescence
characteristics.
We
explored
its
application
in
adhesive-free
laminated
substrates
thoroughly
investigated
aggregation-induced
emission
acylhydrazone
group.
Furthermore,
utilized
bio-PHys
create
recyclable
smart
paper
anticounterfeiting
dynamic
information
storage.
This
work
presents
novel
approach
developing
Angewandte Chemie International Edition,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 12, 2025
Metal-organic
frameworks
(MOFs)
have
been
proven
promising
ultralong
room
temperature
phosphorescence
(RTP)
materials
for
anti-counterfeit
due
to
their
unique
optical
properties.
However,
it
remains
a
major
challenge
achieve
the
desired
phosphorescent
properties
limited
regulatory
methods
and
indistinct
mechanism.
Herein,
coordination
solvent
second
metal
ion
co-strategy
is
firstly
proposed
prepare
seven
robust
heterometallic-organic
(HMOFs)
with
two
configurations:
ZnMg/Ca-sol
[sol
=
H2O,
dimethylformamide
(DMF),
dimethylacetamide
(DMA),
formyldiethylamine
(DEF)]
ZnSr/Ba-H2O,
exhibiting
different
RTP.
The
tunable
lifetimes
within
14.5-195.4
ms
are
achieved
gradually
by
altering
type
of
alkaline
earth
metals,
solvent,
hydrogen-bonding
in
HMOFs.
Significantly,
theoretical
calculations
reveal
that
promotion
spin-orbit
coupling
heavy
metals
rigid
constraint
on
skeleton
result
excellent
balance
between
high
quantum
yield
(ФP)
long
lifetime,
especially
ZnSr-H2O
(6.8%,
195.4
ms).
Depending
wide-range
tuning
RTP
great
stability,
HMOFs
successfully
applied
spatial-time
resolved
anti-counterfeiting
multi-level
information
encryption.
This
work
may
provide
new
approach
designing
target
while
resolving
contradiction
ФP
lifetime.
Angewandte Chemie,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 12, 2025
Abstract
Metal–organic
frameworks
(MOFs)
have
been
proven
promising
ultralong
room
temperature
phosphorescence
(RTP)
materials
for
anticounterfeit
due
to
their
unique
optical
properties.
However,
it
remains
a
major
challenge
achieve
the
desired
phosphorescent
properties
limited
regulatory
methods
and
indistinct
mechanism.
Herein,
coordination
solvent
second
metal
ion
costrategy
is
firstly
proposed
prepare
seven
robust
heterometallic–organic
(HMOFs)
with
two
configurations,
ZnMg/Ca‐sol
[sol
=
H
2
O,
dimethylformamide
(DMF),
dimethylacetamide
(DMA),
formyldiethylamine
(DEF)]
ZnSr/Ba‐H
O
,
exhibiting
different
RTP.
The
tunable
lifetimes
within
14.5–195.4
ms
are
achieved
gradually
by
altering
type
of
alkaline
earth
metals,
solvent,
hydrogen‐bonding
in
HMOFs.
Significantly,
theoretical
calculations
reveal
that
promotion
spin–orbit
coupling
heavy
metals
rigid
constraint
on
skeleton
result
excellent
balance
between
high
quantum
yield
(
Ф
P
)
long
lifetime,
especially
ZnSr‐H
(6.8%,
195.4
ms).
Depending
wide‐range
tuning
RTP
great
stability,
HMOFs
successfully
applied
spatial‐time
resolved
anticounterfeiting
multilevel
information
encryption.
This
work
may
provide
new
approach
designing
target
while
resolving
contradiction
lifetime.
Abstract
The
persistent
luminescence
(PersL)
induced
by
X‐rays
in
fluoride
materials
has
garnered
widespread
application
within
the
field
of
optoelectronics.
However,
complexity
trap
systems
multi‐component
impeded
further
exploration
into
PersL
properties.
Here,
a
compound
consisting
solely
and
lanthanide
ions
is
focused
on,
which
simplifies
revelation
mechanism
under
X‐ray
excitation.
Experimental
theoretical
results
reveal
that
phenomenon
primarily
attributed
to
migration
recovery
processes
interstitial
lattice.
Depending
on
localization
ions,
corresponding
Frenkel
defects
can
be
classified
two
distinct
types:
those
are
readily
self‐recoverable
near
matrix
less
likely
self‐recover
dopant
ions.
anomalous
phenomena
observed
at
temperatures
do
not
correspond
thermoluminescence
spectra
substantiate
existence
these
dynamic
traps.
Furthermore,
leveraging
material's
superior
properties,
scintillator
film
prepared
utilized
for
imaging
static
displays.
These
findings
provide
refined
understanding
related
defects,
laying
solid
foundation
continued
development
technology.