Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159810 - 159810
Published: Jan. 1, 2025
Language: Английский
Citations
2International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 109, P. 224 - 233
Published: Feb. 11, 2025
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161855 - 161855
Published: March 1, 2025
Language: Английский
Citations
0ChemElectroChem, Journal Year: 2025, Volume and Issue: unknown
Published: March 20, 2025
Abstract Given the rising global energy demand and increasing emphasis on environmental protection, development of renewable conversion technologies to replace fossil fuels has emerged as a critical research priority. Among these technologies, seawater electrocatalysis garnered attention high‐efficiency environmentally friendly approach. This review summarizes recent advancements in for resource extraction, covering reaction mechanisms hydrogen production via electrolysis progress electrocatalytic materials. Specifically, we discuss materials based non‐precious metals, precious nonmetals, bifunctional electrocatalysts. Additionally, inorganic pollutants (e. g., hydrazine, sulfides) organic compounds urea, microplastics) is reviewed, emphasizing its significance marine utilization remediation. We also explore electrochemical strategies extracting valuable metal ions, such calcium, magnesium, uranium, lithium, abundant seawater. Although faces challenges terms cost technical scalability, technology interdisciplinary collaboration offer promising prospects commercialization with potential make substantial contributions sustainable development.
Language: Английский
Citations
0AIChE Journal, Journal Year: 2025, Volume and Issue: unknown
Published: April 4, 2025
Abstract Chiral compounds play a pivotal role in pharmaceutical chemistry, and the oxidation of chiral alcohols to corresponding carboxylic acids is crucial step. However, enantioselectivity susceptible degradation due sensitivity enol isomerization racemization. In this study, Ru/S‐Ni‐MOFs electrocatalysts with high specific surface area were synthesized. After undergoing electrochemical reconfiguration, which combined 4‐acetamido‐TEMPO (ACT) as co‐catalysts achieve efficient alcohols, reaching 99% at industrial‐grade current density 500 mA/cm 2 . Additionally, 100 g acid successfully synthesized yield 98% an large‐scale electrolyzer. situ experiments theoretical calculations demonstrated that S doping shifts center d‐band toward Fermi level, stabilizes ACTH inhibits dissociation OH, thereby enhancing electrocatalytic activity. This study presents synergistic strategy for practical electrosynthesis compounds.
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125375 - 125375
Published: April 1, 2025
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124991 - 124991
Published: Dec. 1, 2024
Language: Английский
Citations
2Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157275 - 157275
Published: Oct. 1, 2024
Language: Английский
Citations
1Small Methods, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 17, 2024
Here, integrated functional components into a hybrid heterostructure via highly stabilized network-like interconnected electronic nanoarchitecture of 1D N-doped holey-carbon nanotube (NHCNT) with 2D nickel─metal-organic framework (Ni─MOF) nanosheets are developed as high-performance electrocatalyst for overall water splitting. The NHCNT promoting electron transport pathways in electrocatalyst, and formation holes nanotubes further enables excellent diffusion ions the reaction rate. An combination 1D/2D structure NHCNT/Ni─MOF-4 exhibits oxygen evolution (η
Language: Английский
Citations
1Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 20, 2024
Abstract Electrochemical oxidization of crude ethylene glycol (EG) to fine chemicals driven by sustainable energy is an eco‐friendly solution the upcycling end‐of‐life polyethylene terephthalate (PET) wastes. Here, pseudo Ag x ‐Pt y Pd z core–shell electrocatalyst capable hybrid oxidation EG formate (FA) designed and synthesized. The trimetallic system consists nanowire ultrathin PtPd alloy skin with defects, such as holes grooves. defects expose core surroundings convert 0 2+ active species at appropriate potential (> 1.2 V vs RHE). Thus, reaction realized on electrocatalyst, where catalyzes through conventional Faradaic electrode process owing inherent activities Pt Pd, while serves auxiliar oxidant oxidize EG/intermediates (non‐Faradaic reaction). Such a strategy reinforces removal adsorbates refresh sites timely. Eventually, ultrahigh specific activity (24.45 A mg −1 ) long‐term stability 3000 h current density ≥ 400 mA cm −2 are delivered system. finding ‐enhanced alcohol reactions introduces new paradigm for designing high‐performance electrocatalysts environmental applications.
Language: Английский
Citations
1