Temperature and pH dual dependent conformational transition of polyacrylic acid modified by dehydroabietic alcohol DOI
Xiufang Zhu, W. Liu, Najla AlMasoud

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 8(1)

Published: Dec. 24, 2024

Language: Английский

Muscle‐Inspired Super‐Flexible Phase Change Materials with Programmable Deformation for Photothermal Actuation DOI Open Access

Xiaoye Geng,

Mulin Qin,

Zhenghui Shen

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 13, 2024

Abstract Phase change materials (PCMs) with remarkable latent heat storage/release capacity have demonstrated prominent advantages in energy conservation and efficient thermal management. Nevertheless, simultaneously achieving high storage capacity, excellent toughness, flexibility PCMs is a significant challenge for programmable deformations when used complex environmental scenarios. A flexible PCM reported deformation constructed through three‐dimensional (3D) dynamic cross‐linked network. This approach has culminated the development of homogeneously self‐supporting polyurethane‐based solid‐solid graphene enhancement, which exhibits exceptional properties (∆ H m = 105.3 J g −1 , ∆ c 105.0 ), toughness ( ε 1543%, σ 19.2 MPa), flexibility, shape memory behavior R r 90.3%). Notably, subjected to photothermal stimulation, it can lift objects weighing more than 2620 times their weight, presenting working density 1330 kJ −3 . PCM, possesses photothermal‐driven performance, opens new pathway artificial muscles or soft robots requirements management

Language: Английский

Citations

2

Somatosensory actuators based on light-responsive anisotropic hydrogel for storage encryption of information systems DOI

Mengtian Shang,

Shaoshuai Ma,

Jianfeng Ma

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 153895 - 153895

Published: July 11, 2024

Language: Английский

Citations

1

Preparation and Characterization of Low‐Voltage Responsive Nanocomposite Shape‐Changing Hydrogels/Carbon Nanofibers With Enhanced Mechanical Properties DOI Open Access
Jiale Li,

Qiang Ma,

Guohe Xu

et al.

Journal of Polymer Science, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 14, 2024

ABSTRACT High‐voltage responsiveness and poor mechanical properties hindered the practical applications of electro‐induced shape‐changing hydrogels (EISCHs). In previous work, were improved simply by increasing degree crosslinking, which resulted in reduced deformation capacity. Therefore, nanocomposite technique reinforcing nondeformable hydrogels' was introduced into EISCHs, resulting successful synthesis Poly (N‐isopropylacrylamide‐co‐5‐acrylamido‐1,10‐phenanthroline bis (1,10‐phenanthroline) iron (II))/hydrophilic‐treated hydroxylated carbon nanofibers (P(NIPAM‐Fe(phen) 3 )/HMWCNFs) hydrogel that exhibits outstanding properties, doesn't have its ability weakened possesses low‐voltage this work. The impact various hydrophilic‐treated (HMWCNFs) content on structure, swelling, mechanics investigated. As HMWCNFs increased (0.2%–1.0%), tensile compressive strengths increased, marking 6.67 times 2.91 rise over without HMWCNFs. P(NIPAM‐Fe(phen) /HMWCNFs) higher than at minimum response voltage 10 V. physical entanglements hydrogen bonding between polymer chains adhesion energy provided dissipation. HMWCNFs, as a conductive filler, facilitated electron transfer. swelled shrank due to transition 5‐acrylamido‐1,10‐phenanthroline (II) (Fe(phen) ) network (III) states under stimulation.

Language: Английский

Citations

1

Harnessing chemical functionality of xylan hemicellulose towards bio-based pH/magnetic dual-responsive nanocomposite hydrogel for drug delivery DOI Creative Commons
Qiwen Yong,

Guangliang Zhou,

Xiaomeng Yu

et al.

Research Square (Research Square), Journal Year: 2024, Volume and Issue: unknown

Published: March 11, 2024

Abstract This study reports for the first time an innovative pH/magnetic dual-responsive hemicellulose-based nanocomposite hydrogel with a nearly 100% bio-based and biodegradable compositions. We synthesized pure Fe 3 O 4 magnetic nanoparticles (Fe MNPs) using co-precipitation, then engineering xylan hemicellulose (XH), acrylic acid (AA), polyethylene glycol diacrylate (PEGDA), MNPs to synthesize @XH-Gel), through free radical graft polymerization on natural XH in-situ doping initiated by ammonium persulfate/tetramethylethylenediamine (APS/TMEDA) redox system. Fourier transform infrared spectroscopy (FTIR), nuclear resonance ( 1 H-NMR), X-ray diffractometry (XRD), scanning electron microscopy energy dispersive spectrometer (SEM-EDS), Brunauer-Emmett-Teller (BET), dynamic light scattering (DLS), swelling gravimetric analysis, vibrating sample magnetometer (VSM) were employed analyze hydrogel’s chemical structures, surface morphologies, pH-responsive behaviors, responsiveness characteristics. The results indicate that @XH-Gel exhibited excellent dual pH magnetism. Furthermore, emphasis was placed in-depth analysis of response mechanism drug release control. Finally, we utilized this cutting-edge investigate controlled-release behavior two model drugs, Acetylsalicylic Theophylline , within simulated gastrointestinal tract. demonstrated exceptional controlled attributes, positioning it as potential carrier targeted delivery, particularly conditions.

Language: Английский

Citations

0

Matrigel-Fibrinogen-Thrombin hydrogels with high bioactivity for the fabrication of self-propelled in vitro muscular tissues DOI
Zening Lin, Tao Jiang, Yun Yang

et al.

Applied Materials Today, Journal Year: 2024, Volume and Issue: 39, P. 102315 - 102315

Published: July 12, 2024

Language: Английский

Citations

0

A Ph-Responsive Carbon Dot Nanozyme Hydrogel Compound and its Application in Visual Assessment of Aquatic Product Freshness DOI

D. Liang,

Xincai Xiao,

Dan Zhao

et al.

Published: Jan. 1, 2024

Language: Английский

Citations

0

A review of advanced helical fibers: formation mechanism, preparation, properties, and applications DOI

Minmin Ding,

Xiuling Yang,

Yanbo Liu

et al.

Materials Horizons, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Preparation methods and applications of helical fibers.

Language: Английский

Citations

0

A pH-responsive Fe,Co,P-CDs hydrogel compound and its application in visual assessment of aquatic product freshness DOI
Dan Zhao,

D. Liang,

Huan Liu

et al.

Microchemical Journal, Journal Year: 2024, Volume and Issue: 208, P. 112413 - 112413

Published: Dec. 10, 2024

Language: Английский

Citations

0

Temperature and pH dual dependent conformational transition of polyacrylic acid modified by dehydroabietic alcohol DOI Creative Commons
Xiufang Zhu, W. Liu, Najla AlMasoud

et al.

Research Square (Research Square), Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 9, 2024

Abstract A rosin derivative, dehydroabietic alcohol (DHAA), was synthetized and employed to graft onto polyacrylic acid (PAA) via the Steglich esterification reaction, forming a block copolymer consisting of acrylic units monomer containing ester groups. The resulted grafted (DHAA-graft-PAA) demonstrated enhanced pH temperature sensitivities. number ratio reacted with DHAA un-reacted units, estimated by NMR results. number-average molecular weight DHAA-graft-PAA determined be 9290 an acid-base titration method. optimal decomposition measured using thermogravimetric analyzer approximately 289°C. structural characteristics DHAA-PAA were analyzed Fourier transform infrared spectroscopy, ultraviolet (UV) proton nuclear magnetic resonance spectroscopy (1HNMR). conformational transition under different values investigated. scattering intensity experiments showed that 7.96 critical value 5°C temperature. When below 7.96, degree carboxyl group ionization in polymer decreased, leading repulsion between groups chains causing chain contraction. dropped 5°C, conformation transitioned from extended state contracted state. This study demonstrates intelligent applications for novel sensitive polymer.

Language: Английский

Citations

0

Umbrella-rib-like multi-section three-jawed soft gripper by hybrid pneumatic and magnetic DOI
Zheng Zhang, Tianye Wang, Baisong Pan

et al.

Smart Materials and Structures, Journal Year: 2024, Volume and Issue: 34(1), P. 015057 - 015057

Published: Dec. 17, 2024

Abstract Dual-response can respond to multiple stimuli and overcome the limitations of a single response, especially in biomimetic applications where large deformations high stiffness are demand. This soft gripper fabricated with new multi-section design is novel dual-response actuator that combines silicone magnetic NdFeB particles, highlighting advantages hybrid pneumatic actuation achieve bending behavior efficient at low pressure. The position center section changed by adjusting internal Here, an umbrella-rib-like proposed, inspired process umbrella using deployable foldable mechanisms, joint designed for act like ribs such bend-folding location does not change much on robot different pressures. preparation this grippers provides proficiency wide application medical, industry so on.

Language: Английский

Citations

0