With
the
rapid
advancement
of
artificial
intelligence,
smart
sensing
technologies,
and
batteries
with
high
power
density,
thermal
management
has
become
a
critical
issue
for
electronic
devices.
Phase
change
materials
(PCMs)
offer
promising
applications
in
management.
However,
it
is
significant
challenge
to
fabricate
PCMs
conductivity
(TC)
electromagnetic
interference
shielding
effectiveness
(EMI
SE)
while
maintaining
leakage-free
performance.
This
work
reports
solid–solid
phase
composites
TC
EMI
SE
enabled
by
covalent
functionalization
quasi-hyperbolic
framework.
The
material
(OP)
synthesized
via
nucleophilic
ring-opening
reaction
epoxy
groups,
where
octadecanol
(OD)
grafted
onto
side
chains
polyethylene-co-methyl
acrylate-co-glycidyl
methacrylate
(PEMAGMA).
Subsequently,
filled
into
electrochemically
expanded
graphite
(EEG)
framework
through
vacuum
filtration,
which
EEG
produced
using
an
electrochemical
expansion
method
SE.
obtained
OP/EEG
exhibited
excellent
properties,
including
very
low
leakage
(0.6%),
latent
heat
(86.45
J/g),
ultrahigh
(22.6
W/(m·K)),
superior
(110.28
dB).
shows
great
potential
improving
transfer
efficiency
interface
(TIMs)
practical
applications,
demonstrating
outlook
field
With
the
rapid
advancement
of
artificial
intelligence,
smart
sensing
technologies,
and
batteries
with
high
power
density,
thermal
management
has
become
a
critical
issue
for
electronic
devices.
Phase
change
materials
(PCMs)
offer
promising
applications
in
management.
However,
it
is
significant
challenge
to
fabricate
PCMs
conductivity
(TC)
electromagnetic
interference
shielding
effectiveness
(EMI
SE)
while
maintaining
leakage-free
performance.
This
work
reports
solid–solid
phase
composites
TC
EMI
SE
enabled
by
covalent
functionalization
quasi-hyperbolic
framework.
The
material
(OP)
synthesized
via
nucleophilic
ring-opening
reaction
epoxy
groups,
where
octadecanol
(OD)
grafted
onto
side
chains
polyethylene-co-methyl
acrylate-co-glycidyl
methacrylate
(PEMAGMA).
Subsequently,
filled
into
electrochemically
expanded
graphite
(EEG)
framework
through
vacuum
filtration,
which
EEG
produced
using
an
electrochemical
expansion
method
SE.
obtained
OP/EEG
exhibited
excellent
properties,
including
very
low
leakage
(0.6%),
latent
heat
(86.45
J/g),
ultrahigh
(22.6
W/(m·K)),
superior
(110.28
dB).
shows
great
potential
improving
transfer
efficiency
interface
(TIMs)
practical
applications,
demonstrating
outlook
field