Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 13(1), P. 115025 - 115025
Published: Dec. 4, 2024
Language: Английский
Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 13(1), P. 115025 - 115025
Published: Dec. 4, 2024
Language: Английский
Solar Energy, Journal Year: 2024, Volume and Issue: 275, P. 112640 - 112640
Published: May 25, 2024
Language: Английский
Citations
19Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159689 - 159689
Published: Jan. 1, 2025
Language: Английский
Citations
5Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Language: Английский
Citations
5Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 105921 - 105921
Published: Jan. 1, 2025
Language: Английский
Citations
2Journal of Electroanalytical Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 118963 - 118963
Published: Jan. 1, 2025
Language: Английский
Citations
1Small, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 5, 2025
Abstract Achieving synergistic oxidation and reduction represents a significant challenge in the field of photocatalysis. In this study, hydrothermal/in situ construction Bi atom clusters within 2 Sn O 7 /ZnIn S 4 (BSO/ZIS) heterostructures is reported. These exhibit self‐accelerating charge‐transfer mechanisms facilitated by internal electric fields bonding bridges, resulting highly efficient light absorption capabilities. X‐ray photoelectron spectroscopy (XPS) Kelvin probe force microscopy (KPFM), as well theoretical calculations, indicate that canonical induction promotion electrons holes lowers activation energy CHO* generation, allowing simultaneous CO toluene over catalyst, enhances proton‐coupling electron‐transfer processes, unique reaction mechanism. The reactant, Bi‐Bi (B‐BSO/ZIS) heterostructure achieves rate to 726.3 µmol g −1 h (99.9% selectivity) benzaldehyde 2362.0 (98.0% selectivity), which increases activity 14.6 5.7 times compared pristine ZnIn . This study underscores significance modulating photocatalytic pathway through strategic selection metal reactants, contributing rational design photocatalysts for enhanced adsorption stabilization *H.
Language: Английский
Citations
1Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
S-scheme heterojunctions have become a hot topic in photocatalysis. Copper (Cu) compounds are versatile family of photocatalytic materials, including oxides (CuO, Cu2O), binary (CuBi2O4, CuFe2O4), sulfides (CuxS, (1 ≤ x 2)), selenides (CuSe), phosphides (Cu3P), metal organic frameworks (MOFs), etc. These materials characterized by narrow bandgaps, large absorption coefficients, and suitable band positions. To further increase the efficiency photoinduced charge separation, Cu-based widely integrated into exploited for hydrogen evolution reaction (HER), CO2 reduction, H2O2 generation, N2 fixation, pollutant degradation. This review comprehensively discusses recent progress heterojunctions, highlights their considerable potential targeted applications sustainable energy conversion, environmental remediation, beyond. The fundamentals transfer, design principles verification tools summarized. Then, describes categorized according to chemical composition, integration applications. In particular, implications transfer mechanism on promoting catalytic activity selected systems analyzed. Finally, current limitations outlooks provided motivate future studies developing novel advanced photocatalysts with high performance studying underlying mechanisms.
Language: Английский
Citations
1Journal of Cluster Science, Journal Year: 2025, Volume and Issue: 36(3)
Published: April 5, 2025
Language: Английский
Citations
1Journal of Materiomics, Journal Year: 2024, Volume and Issue: 11(3), P. 100934 - 100934
Published: Aug. 30, 2024
Language: Английский
Citations
8Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130319 - 130319
Published: Oct. 1, 2024
Language: Английский
Citations
7