Molecular Catalysis, Journal Year: 2024, Volume and Issue: 568, P. 114505 - 114505
Published: Sept. 5, 2024
Language: Английский
Molecular Catalysis, Journal Year: 2024, Volume and Issue: 568, P. 114505 - 114505
Published: Sept. 5, 2024
Language: Английский
Materials Today Energy, Journal Year: 2025, Volume and Issue: unknown, P. 101796 - 101796
Published: Jan. 1, 2025
Language: Английский
Citations
3Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161949 - 161949
Published: March 1, 2025
Language: Английский
Citations
1Small, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 28, 2024
Abstract Metal–organic frameworks (MOFs) are excellent precursors for preparing transition metal and nitrogen co‐doped carbon catalysts, which have been widely utilized in the field of electrocatalysis since their initial development. However, original MOFs derived catalysts greatly limited development application due to disadvantages such as atom aggregation, structural collapse, narrow pore channels. Recently, surfactants‐assisted attracted much attention from researchers advantages hierarchical porous structure, increased specific surface area, many exposed active sites. This review mainly focuses on synthesis methods comprehensively introduces action surfactants materials structure‐activity relationship between oxygen reduction reaction, evolution hydrogen reaction performance. Apparently, aims this not only introduce status but also contribute rational design fuel cells, metal–air electrolysis water toward production.
Language: Английский
Citations
6Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124615 - 124615
Published: Sept. 1, 2024
Language: Английский
Citations
5Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 679, P. 75 - 89
Published: Sept. 28, 2024
Language: Английский
Citations
5Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 27, 2024
Abstract Bifunctional catalysts for the oxygen reduction reaction (ORR) and evolution (OER) are essential components of rechargeable zinc‐air batteries. In this study, we synthesized a Pr 0.5 Ba Mn 0.8 Co 0.1 Ru O 2.5+δ (PBMCRO) perovskite composite with in situ exsolved CoRu nanoparticles Co–N–C, functioning as an efficient bifunctional electrocatalyst The exsolution from oxide was facilitated by reducing action 2‐methylimidazole (2‐MIM). Concurrently, Co–N–C used to decorate PBMCRO, forming novel electrode Co–N–C–PBMCRO. incorporation introduces significant number electrochemically active vacancies matrix, enhancing ORR OER performance. Additionally, synergistically improves electrochemical activity while preserving structural stability oxide. prepared Co–N–C–PBMCRO catalyst demonstrates significantly enhanced performance compared undecorated pristine MnO 3−δ (PBMO). battery achieve peak power density approximately 90 mW/cm 2 exhibit remarkable cycling 788 h. This study presents effective strategy enhance catalytic perovskite‐based air electrodes metal‐air
Language: Английский
Citations
5International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 73, P. 590 - 597
Published: June 12, 2024
Language: Английский
Citations
4Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1004, P. 175860 - 175860
Published: Aug. 4, 2024
Language: Английский
Citations
3Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 497, P. 154483 - 154483
Published: Aug. 5, 2024
Language: Английский
Citations
3Small, Journal Year: 2024, Volume and Issue: 20(46)
Published: Aug. 8, 2024
Abstract Metal‐air secondary batteries with ultrahigh specific energies have received vast attention and are considered new promising energy storage. The slow redox reactions between oxygen‐water molecules lead to low efficiency (55–71%) limited applications. Herein, it is proposed that the MIL‐68(In)‐derived porous carbon nanotube supports CoNiFeP heteroconjugated alloy catalyst an overboiling point electrolyte achieve oxidation rate of water molecules. Structural characterization density functional theory calculations reveal greatly reduces free process, further accelerates dissociation O─H hydrogen bonds, release O 2 molecules, achieving extra‐low overpotential 110 mV@10 mA cm −2 far lower than commercial Ir/C catalysts 192 mV at 125 °C state‐of‐the‐art. Furthermore, assembled rechargeable zinc‐air begins break through 85 °C, jumps 100 reaches 88.1% ultralow decay 0.0068% after 150 cycles superior those reported metal‐air batteries. This work provides a joint‐design strategy reexamines battery operating temperature construct higher for fuel cells.
Language: Английский
Citations
3