Improving the catalytic performance over ultrathin Pd/2D-CoAl-LDH nanosheet via modulating electronic metal-support interaction for CO esterification to dimethyl oxalate

Applied Catalysis A General, Journal Year: 2025, Volume and Issue: unknown, P. 120167 - 120167

Published: Feb. 1, 2025

Language: Английский

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Construction of Mesopores and Skeleton Si–Al Rearrangement to Design Pd-Based Catalysts for Dimethyl Carbonate Synthesis

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

Language: Английский

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Promoting Intermediate Stabilization and Coupling for Dimethyl Carbonate Electrosynthesis

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 31, 2025

Abstract The electrocatalytic coupling of methanol and CO to produce dimethyl carbonate (DMC) is an attractive strategy for converting C 1 resources into value‐added products, while the controlled adsorption two key intermediates, * OCH 3 , have not been demonstrated yet. Herein, a heterointerface engineering developed modulate intermediate facilitate C─O bond formation. By constructing Pd PdO heterostructure catalyst with abundant interfaces (designated as Pd/PdO‐r), 0 sites serve stabilize electrophilic 2+ can promote adsorption, thereby optimizing their spatial proximity reactivity. In addition, heterointerfaces allow lower reaction barrier, enabling efficient pathway DMC synthesis. Consequently, Pd/PdO‐r exhibited high Faradaic efficiency 86% yield rate 252 µmol h −1 mg cat in flow cells. work suggests effective approach design enhanced coupling, thus promoting formation valuable multicarbon products from resources.

Language: Английский

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In situ prepared ionic liquids containing moisture-resistant bismuth-based perovskite crystals enhance the photocatalytic water purification and H2 production of MOF

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 360, P. 130998 - 130998

Published: Dec. 9, 2024

Language: Английский

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