Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: 505, P. 159240 - 159240
Published: Jan. 5, 2025
Language: Английский
Citations
1Energy Reports, Journal Year: 2025, Volume and Issue: 13, P. 3351 - 3368
Published: March 13, 2025
Language: Английский
Citations
1ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 5412 - 5425
Published: March 18, 2025
Language: Английский
Citations
1Catalysts, Journal Year: 2025, Volume and Issue: 15(4), P. 301 - 301
Published: March 23, 2025
This study reports the synthesis, characterization, and catalytic performance of a series catalysts Ru supported on CeO2-Y2O3 composites (Ru/CeYX; X = 0, 33, 66, 100 wt.% Y2O3) for CO2 hydrogenation. Supported material modification (Y2O3-CeO2), by Y2O3 incorporation, allowed change in selectivity from methane to RWGS hydrogenation reaction. is correlated with variation physicochemical properties caused addition. X-ray diffraction (XRD) analysis confirmed formation crystalline fluorite-phase CeO2 α-Y2O3. High-resolution transmission electron microscopy (HR-TEM) energy-dispersive spectroscopy (EDS) elemental mapping revealed homogeneous nanocomposite. As content increased, specific surface area, measured BET, showed decreasing trend 106.3 51.7 m2 g−1. photoelectron (XPS) Ce3d indicated similar Ce3+/Ce4+ ratio across all CeO2-containing materials, while O1s spectra reduction oxygen vacancies increasing content, which attributed decreased area upon composite formation. Catalytically, addition influenced both conversion selectivity. lowest observed Ru/CeY100. Regarding selectivity, was dominant product Ru/CeY0 (pure CeO2), CO main Ru/CeY33, Ru/CeY66, Ru/CeY100, indicating shift towards reverse water–gas (RWGS) The highest reaction rate Ru/CeY33 catalyst under tested conditions. differences are active sites due decrease vacancies, important adsorption. In order verify species catalytically RWGS, samples were characterized FTIR
Language: Английский
Citations
1Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 361, P. 124555 - 124555
Published: Aug. 31, 2024
Language: Английский
Citations
5Results in Surfaces and Interfaces, Journal Year: 2024, Volume and Issue: unknown, P. 100321 - 100321
Published: Oct. 1, 2024
Language: Английский
Citations
4Journal of Catalysis, Journal Year: 2025, Volume and Issue: 443, P. 115994 - 115994
Published: Jan. 31, 2025
Language: Английский
Citations
0Nanoscale, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
A highly dispersed NiCo alloy catalyst derived from bimetallic-organic framework nanosheets was synthesized for efficient photothermal catalysis CO2 hydrogenation to methane. The bimetal achieves a CH4 production rate of 55.60 mmol g-1 h-1 with only 18.82% decline in performance after 86 hours under atmospheric pressure at selected 290 °C and continuous flow reaction. In situ diffuse reflectance infrared Fourier transform spectroscopy (in DRIFTS) reveals the synergistic complementary roles light heat catalysis. thermochemical process drives reverse water-gas shift reaction form *CO intermediate, key intermediate formation CH4, irradiation-generating strong near field surface plasma resonance bimetals promotes subsequent step *CHO, rate-determining into CH4. Meanwhile, density functional theory (DFT) calculations suggest that bimetallic can also lower energy barrier hydrogenation, facilitating *CHO.
Language: Английский
Citations
0Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 45, P. 102648 - 102648
Published: March 17, 2025
Language: Английский
Citations
0Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 19, 2025
Abstract Currently, thermal catalysis is the predominant method for achieving reverse water–gas shift (RWGS) reaction reduction of carbon dioxide (CO 2 ) to monoxide (CO), which a crucial intermediate in synthesis other high value‐added chemicals via Fischer–Tropsch synthesis. To extend applicability CO RR) CO, researchers have explored RR that utilizes external fields addition fields. This review commences by providing an overview research background pertinent and then primary mechanisms potential pathways associated with process are summarized. Furthermore, impact various fields, including traditional light photothermal coupling solar thermochemical laser electric photoelectric electromagnetic plasma on investigated. Finally, summary future perspectives as influenced presented. It anticipated this will provide valuable insights focused preparation high‐value‐added through enhanced
Language: Английский
Citations
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