Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157964 - 157964
Published: Nov. 1, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157964 - 157964
Published: Nov. 1, 2024
Language: Английский
Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132652 - 132652
Published: March 1, 2025
Language: Английский
Citations
1Journal of Water Process Engineering, Journal Year: 2025, Volume and Issue: 71, P. 107161 - 107161
Published: Feb. 12, 2025
Language: Английский
Citations
0Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: April 22, 2025
Abstract Efficient oxidation of biomass‐derived 5‐hydroxymethylfurfural (HMF) to 2,5‐furandicarboxylic acid (FDCA) under low temperature and atmospheric pressure using non‐noble metal catalysts is highly desirable yet challenging. This study employs a temperature‐controlled hydrothermal redox strategy synthesize series MnO 2 nanorods (MnO ‐R) investigates their catalytic performance in HMF ambient oxygen pressure. Results demonstrate that increasing the not only sequentially forms β, α/β, α phases , but also continuously enriches vacancy Lewis acid. The higher‐defect α‐MnO ‐R, exhibiting lower Mn─O coordination number, displays 96.7% FDCA yield an initial productivity up 365.5 µmol g cat −1 h which are 1.5 times 2.7 higher than β‐MnO respectively. DFT calculations spectroscopic experiments reveal high‐temperature drives phase transition intensifies reactions, leading Mn numbers, result stronger adsorption energy toward C─O bond, faster superoxide radical generation, bond oxidation. ‐R exhibits good recyclability excellent substrate universality various aromatic aldehydes/alcohols. work provides new perspective on designing efficient oxide catalysts, focusing coordination/defect reconstruction cations, thus deepening understanding how modulate these centers enhance efficiency.
Language: Английский
Citations
0Water Research, Journal Year: 2024, Volume and Issue: 273, P. 123027 - 123027
Published: Dec. 21, 2024
Language: Английский
Citations
3Environmental Geochemistry and Health, Journal Year: 2024, Volume and Issue: 47(1)
Published: Dec. 18, 2024
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157964 - 157964
Published: Nov. 1, 2024
Language: Английский
Citations
0