Food Control, Journal Year: 2024, Volume and Issue: unknown, P. 111045 - 111045
Published: Nov. 1, 2024
Language: Английский
Food Control, Journal Year: 2024, Volume and Issue: unknown, P. 111045 - 111045
Published: Nov. 1, 2024
Language: Английский
Analytical Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: March 9, 2025
It remains challenging to rationally design superior nanozymes and understand the underlying mechanism. Herein, a facile covalent coupling-modulated nitrogen defect is reported for significantly boosting peroxidase (POD)-like activity. Vanadium nitride (VN) nanoparticles are grown on graphene oxide (GO) via C–N bonding form VN/rGO nanocomposites by varying with VOx/GO ratio. The initial increasing GO amount enables formation of bond, dramatically POD-like Nevertheless, higher amount, defects decrease due forming mainly V2O3. defect-rich nanocomposite 20 wt % (VG-2) exhibits best catalytic efficiency (Vmax/Km = 0.0187 s–1), which 778-fold than that natural horseradish peroxidase. Theoretical calculations structure characterization reveal rich-N originate from VN binding onto rGO an rich-electron structure, impeding agglomeration, greatly reduces energy barrier rate-determining step reaction. Finally, coupling urate oxidase VG-2 as enzyme cascade, ultrasensitive selective colorimetric detection was developed uric acid (UA), one indicators kidney function or gout attacks, linear ranging 1–100 μM 0.1–2.5 mM limit 0.24 UA (S/N 3). proposed method applicable detecting in human serum samples satisfactorily. This work could inspire more effective insights into designing other robust through variety biochemical analysis biocatalysis applications.
Language: Английский
Citations
2Talanta, Journal Year: 2025, Volume and Issue: 287, P. 127644 - 127644
Published: Jan. 27, 2025
Language: Английский
Citations
1Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 112640 - 112640
Published: Jan. 1, 2025
Language: Английский
Citations
0Journal of Inorganic and Organometallic Polymers and Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 11, 2025
Language: Английский
Citations
0Microchimica Acta, Journal Year: 2025, Volume and Issue: 192(3)
Published: March 1, 2025
Language: Английский
Citations
0Analytical Methods, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
An electrochemical DNA biosensor was developed based on SEA, which can detect 1 fg uL −1 genomic within 65 min. The electrode surface modified with AuNPs to improve sensitivity and the accelerated by electric field.
Language: Английский
Citations
0Analytica Chimica Acta, Journal Year: 2025, Volume and Issue: 1355, P. 344015 - 344015
Published: April 6, 2025
Language: Английский
Citations
0Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113711 - 113711
Published: April 1, 2025
Language: Английский
Citations
0Talanta, Journal Year: 2025, Volume and Issue: unknown, P. 128201 - 128201
Published: April 1, 2025
Language: Английский
Citations
0Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113808 - 113808
Published: April 1, 2025
Language: Английский
Citations
0