Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 109, P. 115208 - 115208
Published: Dec. 31, 2024
Language: Английский
Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 109, P. 115208 - 115208
Published: Dec. 31, 2024
Language: Английский
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 9, 2025
Dendritic zinc (Zn) electrodeposition presents a significant obstacle to the large-scale development of rechargeable zinc-ion batteries. To mitigate this challenge, various interfacial strategies have been employed. However, these approaches often involve incorporation foreign materials onto Zn anode surface, resulting in increased material costs and processing complexities, not mention compromised interface endurability due structural compositional heterogeneity. Realizing that Cu atoms typically exist as trace impurities commercial Zn, novel approach is demonstrated leverages create Cu-rich surface for effective modulation electrodeposition. By simply heating commercially available foil with naturally oxidized only internal are thermally activated become diffusible, their diffusion also navigated toward via oxygen attraction. The effectively regulates electrodeposition, comparable conventional strategies, yet exhibits superior cycling durability. 3D situ microscopy confirms enables dendrite-free, compact, (101)-oriented contrasting traditional (002)-oriented dendrite-suppression mechanism. transforming impurity within into work demonstrates straightforward, cost-effective efficient method controlling
Language: Английский
Citations
2Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 10, 2025
Abstract Aqueous zinc (Zn) batteries hold significant promise as large‐scale energy storage solutions aimed at mitigating the intermittency of renewable energy. Nevertheless, Zn anode is plagued by a series adverse reactions, hindering development toward practical applications. Herein, concept polyetheramine nematic spatial effects that reshape inner and outer Helmholtz planes to stabilize introduced. Theoretical calculations characterizations confirm reshaped exhibit water/suflate‐repulsive homogeneous 2+ transport interface, enabling highly stable for energetic batteries. Consequently, anode‐free half‐cells under achieve cycling over 390 h an areal capacity 50 mAh cm −2 1500 10 . The constructed Zn‐V 2 O 5 Zn‐MnO cycle performance 1000 2000 cycles, respectively. Importantly, enlarged pouch cell with 300 demonstrates specific 176 g −1 after cycles. Moreover, displays successful integration photovoltaic panels along notable safety features. This superior electrical double‐layer regulation strategy offers valuable insights into
Language: Английский
Citations
1Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: March 1, 2025
Language: Английский
Citations
0Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: 718, P. 136931 - 136931
Published: April 14, 2025
Language: Английский
Citations
0Journal of Power Sources, Journal Year: 2025, Volume and Issue: 647, P. 237304 - 237304
Published: May 12, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 158035 - 158035
Published: Nov. 1, 2024
Citations
3Green Energy & Environment, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 1, 2024
Language: Английский
Citations
1Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 24, 2024
Abstract Zinc‐ion batteries possess operation safety, high energy density, production flexibility and affordability, making them attractive for scalable storage. While Zn anodes face significant challenges from rampant dendrite growth electrolyte‐related side‐reactions in a complex interfacial microenvironment. The growing resistance further degrades the battery performance. An integrated anode design is reported to regulate simultaneously 2+ flux through situ confinement of sieve, that is, 2D CuBDC metal–organic framework mesoporous carbonaceous host. with sub‐nanometer channels selected efficient dehydration directional transport, lowering nucleation barrier by zincophilic Cu(II) N sites. Conductive meso‐carbon reduces blocks side‐reactions. Resultantly, modified demonstrate improved cycling stability lower voltage polarization, supported operando optical microscopy ex analysis. This work provides feasible strategy improving aqueous new insights on designing advancing zinc batteries.
Language: Английский
Citations
0Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 109, P. 115208 - 115208
Published: Dec. 31, 2024
Language: Английский
Citations
0