Improving zinc anode reversibility and stability through adsorption modulation on crystal surfaces with trace green multifunctional organic molecules DOI

Xiaohan Jin,

Yaru Li, Ying Yang

et al.

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 109, P. 115208 - 115208

Published: Dec. 31, 2024

Language: Английский

“Pumping” Trace Cu Impurity out of Zn Foil for Sustainable Aqueous Battery Interface DOI Open Access
Rui Zhong,

Shengbo Wang,

Kun He

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 9, 2025

Dendritic zinc (Zn) electrodeposition presents a significant obstacle to the large-scale development of rechargeable zinc-ion batteries. To mitigate this challenge, various interfacial strategies have been employed. However, these approaches often involve incorporation foreign materials onto Zn anode surface, resulting in increased material costs and processing complexities, not mention compromised interface endurability due structural compositional heterogeneity. Realizing that Cu atoms typically exist as trace impurities commercial Zn, novel approach is demonstrated leverages create Cu-rich surface for effective modulation electrodeposition. By simply heating commercially available foil with naturally oxidized only internal are thermally activated become diffusible, their diffusion also navigated toward via oxygen attraction. The effectively regulates electrodeposition, comparable conventional strategies, yet exhibits superior cycling durability. 3D situ microscopy confirms enables dendrite-free, compact, (101)-oriented contrasting traditional (002)-oriented dendrite-suppression mechanism. transforming impurity within into work demonstrates straightforward, cost-effective efficient method controlling

Language: Английский

Citations

2

Polyetheramine Nematic Spatial Effects Reshape the Inner/Outer Helmholtz Planes for Energetic Zinc Batteries DOI Open Access

Xinhua Zheng,

Bibo Han,

Jifei Sun

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 10, 2025

Abstract Aqueous zinc (Zn) batteries hold significant promise as large‐scale energy storage solutions aimed at mitigating the intermittency of renewable energy. Nevertheless, Zn anode is plagued by a series adverse reactions, hindering development toward practical applications. Herein, concept polyetheramine nematic spatial effects that reshape inner and outer Helmholtz planes to stabilize introduced. Theoretical calculations characterizations confirm reshaped exhibit water/suflate‐repulsive homogeneous 2+ transport interface, enabling highly stable for energetic batteries. Consequently, anode‐free half‐cells under achieve cycling over 390 h an areal capacity 50 mAh cm −2 1500 10 . The constructed Zn‐V 2 O 5 Zn‐MnO cycle performance 1000 2000 cycles, respectively. Importantly, enlarged pouch cell with 300 demonstrates specific 176 g −1 after cycles. Moreover, displays successful integration photovoltaic panels along notable safety features. This superior electrical double‐layer regulation strategy offers valuable insights into

Language: Английский

Citations

1

Flexible Sn-Air batteries with multilevel microchannel corrosion-resistant anodes for stability and wide-temperature applications DOI
Junjie Wang, Ziyu Wang, Yuexi Chen

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 1, 2025

Language: Английский

Citations

0

Multifunctional Zn–complex as interfacial coating for constructing stable and dendrite-free Zn anodes DOI
Jingtao Wang, Lin Liu, Jiahui Lu

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: 718, P. 136931 - 136931

Published: April 14, 2025

Language: Английский

Citations

0

Wind-eroded landform-inspired organic salt protective coating for highly reversible zinc anodes DOI
Xingfu Yang,

Junnan Liu,

Xu Zeng

et al.

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 647, P. 237304 - 237304

Published: May 12, 2025

Language: Английский

Citations

0

Activated proton storage in molybdenum selenide via nanostructure molecular engineering DOI
Fei Long, Long Zhang,

Shuwen Yan

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 158035 - 158035

Published: Nov. 1, 2024

Citations

3

Interfacial regulation for zinc metal anode of aqueous zinc-ion battery DOI Creative Commons
Jing Zhu, Xumeng Ge, Peng Zhi

et al.

Green Energy & Environment, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 1, 2024

Language: Английский

Citations

1

An Ionic Sieve‐Integrated Conductive Interfacial Design to Simultaneously Regulate the Zn2+ Flux and Interfacial Resistance for Advancing Zinc‐Ion Batteries DOI
Haobo Wang, Yutong Wu,

Qihong Xie

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 24, 2024

Abstract Zinc‐ion batteries possess operation safety, high energy density, production flexibility and affordability, making them attractive for scalable storage. While Zn anodes face significant challenges from rampant dendrite growth electrolyte‐related side‐reactions in a complex interfacial microenvironment. The growing resistance further degrades the battery performance. An integrated anode design is reported to regulate simultaneously 2+ flux through situ confinement of sieve, that is, 2D CuBDC metal–organic framework mesoporous carbonaceous host. with sub‐nanometer channels selected efficient dehydration directional transport, lowering nucleation barrier by zincophilic Cu(II) N sites. Conductive meso‐carbon reduces blocks side‐reactions. Resultantly, modified demonstrate improved cycling stability lower voltage polarization, supported operando optical microscopy ex analysis. This work provides feasible strategy improving aqueous new insights on designing advancing zinc batteries.

Language: Английский

Citations

0

Improving zinc anode reversibility and stability through adsorption modulation on crystal surfaces with trace green multifunctional organic molecules DOI

Xiaohan Jin,

Yaru Li, Ying Yang

et al.

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 109, P. 115208 - 115208

Published: Dec. 31, 2024

Language: Английский

Citations

0